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The first electrochemical sensor for determination of mangiferin based on an ionic liquid–graphene nanosheets paste electrode

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Abstract

A novel carbon paste electrode modified with graphene nanosheets and an ionic liquid (n-hexyl-3-methylimidazolium hexafluoro phosphate) was fabricated and used for the electrochemical study of mangiferin for the first time. This modified electrode offers a considerable improvement in voltammetric sensitivity toward mangiferin, compared to the bare electrode. Square wave voltammetry (SWV) exhibits a linear dynamic range from 5.0 × 10−8 to 2.0 × 10−4 M and a detection limit of 20.0 nM for mangiferin. Finally, the proposed method was successfully applied to the determination of mangiferin in real samples such as serum and urine.

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Authors and Affiliations

  1. Department of Chemistry, Shahid Bahonar University of Kerman, P.O. Box 76175-133, Kerman, Iran

    Somayeh Tajik & Mohammad Ali Taher

  2. Young Researchers Society, Shahid Bahonar University of Kerman, P.O. Box 76175-133, Kerman, Iran

    Somayeh Tajik

  3. Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran

    Hadi Beitollahi

Authors
  1. Somayeh Tajik
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  2. Mohammad Ali Taher
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  3. Hadi Beitollahi
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Correspondence to Somayeh Tajik.

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Tajik, S., Taher, M.A. & Beitollahi, H. The first electrochemical sensor for determination of mangiferin based on an ionic liquid–graphene nanosheets paste electrode. Ionics 20, 1155–1161 (2014). https://doi.org/10.1007/s11581-013-1063-2

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  • DOI: https://doi.org/10.1007/s11581-013-1063-2

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