Reactivity of the Unsaturated Triosmium Cluster [Os3(CO)8{Ph2PCH2P(Ph)C6H4}(μ-H)] with Thiols S. M. Tareque AbedinKazi A. AzamEdward Rosenberg OriginalPaper Pages: 5 - 22
Iridium Cluster Chemistry: The Synthesis and the Solid State Structures of [HIr5(CO)12]2− and [HIr4(CO)10PPh3]− Roberto Della PergolaLuigi GarlaschelliDonatella Strumolo OriginalPaper Pages: 23 - 34
Reactions of the Cluster Anion [HRu3(CO)11)]− with Dicyclohexylphosphine: Synthesis and Molecular Structure of H2Ru3(CO)8(PCy2)2 and H2Ru3(CO)6(PCy2)2(HPCy2)2 Georg Süss-FinkIsabelle GodefroyHelen Stoeckli-Evans OriginalPaper Pages: 35 - 48
Tetraplatinum Cluster Complexes Brian T. SterenbergRavindranath RamachandranRichard J. Puddephatt OriginalPaper Pages: 49 - 59
Synthesis, Electrochemistry and Crystal Structure of the [Ni36Pt4(CO)45]6− and [Ni37Pt4(CO)46]6− Hexaanions Francesco DemartinFabrizia Fabrizi de BianiPiero Zanello OriginalPaper Pages: 61 - 74
Synthesis, Chemical Characterization, and Molecular Structure of Au8{Fe(CO)4}4(dppe)2 and Au6Cu2{Fe(CO)4}4(dppe)2 Vincenzo G. AlbanoCarlo CastellariStefano Zacchini OriginalPaper Pages: 75 - 87
Pentaruthenium-Based Borides Stabilized by Gold(I) Phosphine Units Catherine E. HousecroftDorn M. NixonArnold L. Rheingold OriginalPaper Pages: 89 - 98
The Reaction of Alkenes with Triangulo-Clusters [Pt3(μ-CO)3(PR3)3] Renzo RosGiacomo FacchinFerenc Lukacs OriginalPaper Pages: 99 - 112
Surface Mediated Organometallic Synthesis: Formation of [H5Os10(CO)24]− by Hydrogenation of Silica-Supported [Os(CO)3(OH)2]n as a Springboard for a High-Yield Synthesis of [H4Os10(CO)24]2− Starting from α-[Os(CO)3Cl2]2 and Working in Ethylene Glycol Solution Elena LucentiDominique RobertoElena Cariati OriginalPaper Pages: 113 - 122
Iron-Iridium Mixed-Metal Carbonyl Clusters: A Mössbauer Study of the Structure and of the Adsorption of [Fe2Ir2(CO)12]2− on MgO L. StievanoS. CalogeroF. E. Wagner OriginalPaper Pages: 123 - 137
The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes Sabrina BraitStefano DeabateEnrico Sappa OriginalPaper Pages: 139 - 173
Application of the Spherical Harmonic Model to the ν(CO) Vibrational Spectra of Some Fe(CO)4 and M(CO)5 (M=Cr, W) Transition Metal Cluster Carbonyl Species S. F. A. KettleE. BoccaleriG. Longoni OriginalPaper Pages: 175 - 186
Mixed Ruthenium–Iridium Carbonyl Cluster Complexes. Synthesis of the Anions [Ru3Ir2(CO)14]2− and [Ru3Ir2(CO)14H]− and Crystal Structures of Their [tetraphenylphosphonium]+ Salts Alessandro FumagalliMaria Carlotta MalatestaAngelo Sironi OriginalPaper Pages: 187 - 200
Ruthenium Cluster Chemistry with Ph2PC6H4-4-C≡CH Nigel T. LucasMarie P. CifuentesMark G. Humphrey OriginalPaper Pages: 201 - 221
Hydrido-Carbonyl Rhenium Clusters with a Square Geometry of the Metal Core. Synthesis and X-Ray Characterization of the Novel [Re4(μ-H)3(CO)16]− Anion Mirka BergamoTiziana BeringhelliAngelo Sironi OriginalPaper Pages: 223 - 242
Synthesis of Platinum-Triruthenium Clusters Using the Zero-Valent Platinum Reagent Pt(nb)3: X-Ray Crystal Structures of Ru3Pt(CO)11(P-iPr3)2, Ru3Pt(μ-H)(μ3-η3-MeCCHCMe)(CO)9(P-iPr3), Ru3Pt(μ3-η2-PhCCPh)(CO)10(P-iPr3), Ru3Pt(μ-H)(μ4-N)(CO)10(P-iPr3) and Ru3Pt(μ-H)(μ4-η2-NO)(CO)10(P-iPr3) David EllisLouis J. Farrugia OriginalPaper Pages: 243 - 257
Easy Access to Phosphido-Selenido Clusters. Reaction of [Ru3(CO)12] with Ph2(pyth)PSe {pyth=5-(2-Pyridyl)-2-Thienyl} and Crystal Structure of [Ru3(μ3-Se)(μ-PPh2)(μ-pyth)(CO)6{P(pyth)Ph2}] Daniele CauzziClaudia GraiffAntonio Tiripicchio OriginalPaper Pages: 259 - 271
Laser Desorption Ionization Versus Electrospray Ionization Mass Spectrometry: Applications in the Analysis of Cluster Anions Paul J. DysonAndrew K. HearleyPatrick R. R. Langridge-Smith OriginalPaper Pages: 273 - 283
Neutron Diffraction Analysis of H3Co2[C5H2(t-Bu)3]2, a Molecule with a Triply Hydrogen-Bridged Metal–Metal Bond: Some Comments on Structural Patterns in M(μ-H)nM Systems (n=1, 2, 3, 4) Manfred BortzRobert BauSax A. Mason OriginalPaper Pages: 285 - 291
A New Polymorph of the Heteronuclear Cluster Ru4Pt2(CO)18 Vincenzo AntonucciAntonino S. AricòFabio Marchetti OriginalPaper Pages: 293 - 301
New Mixed Metal Cluster Complexes Containing Platinum. The Synthesis and Structural Characterizations of PtFe4(CO)12(COD)(μ5-C) and PtFe4(CO)12(PMe2Ph)2(μ5-C) Richard D. AdamsBurjor CaptainWei Fu OriginalPaper Pages: 303 - 312
First-Known High-Nuclearity Copper–Nickel Carbonyl Cluster: [CuxNi35−x(CO)40]5− (with x=3 or 5) Containing an Unprecedented 35-Atom Three-Layer hcp Triangular Stacking Metal-Core Geometry Peter D. MlynekMasaki KawanoLawrence F. Dahl OriginalPaper Pages: 313 - 338
1- and 2-D NMR Studies on [Rh6C(CO)14(PPh3)]2− Javad S. Z. SabouncheiBrian T. HeatonIvan S. Podkorytov OriginalPaper Pages: 339 - 348
Synthesis and Structure of a Neutral Trimetallic Biicosahedral Cluster, (Ph3P)10Au11Ag12Pt2Cl7. A Comparative Study of Molecular and Crystal Structures of Vertex-Sharing Biicosahedral Mixed-Metal Nanoclusters Boon K. TeoHong Zhang OriginalPaper Pages: 349 - 383