Abstract
When the Fe(CO)4 and M(CO)5 (M=Cr, W) groups are co-ordinated in C3v and C4v fashion, respectively, in transition metal carbonyl cluster species they contain two sets of non-symmetry related carbonyl groups. In the application of the spherical harmonic model (SHM) to the interpretation of the infrared spectra of these compounds it proves necessary first to treat these as for a normal, isolated, M(CO)4 or M(CO)5 group and then apply the SHM. This recognition gives insights into the general application of the SHM.
Similar content being viewed by others
REFERENCES
(a) D. J. Darensbourg, H. H. Nelson, III, and C. L. Hyde (1974). Inorg. Chem. 13, 2135. (b) R. D. Ernst and T. J. Marks (1978). Inorg. Chem. 17, 1477.
G. Doyle, K. A. Eriksen, and D. Van Engen (1985). J. Am. Chem. Soc. 107, 7914.
S. F. A. Kettle, E. Diana, R. Rossetti, and P. L. Stanghellini (1997). J. Am. Chem. Soc. 119, 8228.
S. F. A. Kettle (1998). Spectrochim. Acta 54A, 1639.
N. Rosch and G. Pacchioni, in G. Schmid (ed.), Clusters and Colloids: From Theory to Applications (VCH, Weinheim, 1994), pp. 5–88, and ref. therein.
S. F. A. Kettle, E. Diana, R. Rossetti, and P. L. Stanghellini (1998). Inorg. Chem. 37, 6502.
(a) V. G. Albano, L. Grossi, G. Longoni, M. Monari, S. Mulley, and A. Sironi (1992). J. Am. Chem. Soc. 114, 5708. (b) V. G. Albano, F. Calderoni, M. C. Iapalucci, G. Longoni, M. Monari, and P. Zanello (1995). J. Cluster Sci. 6, 107.
(a) S. F. A. Kettle, I. Paul, and P. Stamper (1970). Chem. Comm. 1724. (b) S. F. A. Kettle, I. Paul, and P. Stamper (1972). J. Chem. Soc. (Dalton) 2413. (c) S. F. A. Kettle, I. Paul, and P. Stamper (1973). Inorg. Chim. Acta 7, 11. (d) S. F. A. Kettle and N. Luknar (1978). J. Chem. Phys. 68, 2264.
B. Schmiemenz and G. Huttner (1993). Angew. Chem. Int. Ed. 32, 297.
P. Kircher, G. Huttner, K. Heinze, and G. Renner (1998). Angew. Chem. Int. Ed. 37, 1664.
P. Kircher, G. Huttner, L. Zsolnai, and A. Dreiss (1998). Angew. Chem. Int. Ed. 37, 1666.
S. Martinengo, A. Fumagalli, G. Ciani, and M. Moret (1988). J. Organomet. Chem. 347, 413.
(a) M. R. Churchill, J. C. Fettinger, K. H. Whitmire, and C. B. Lagrone (1986). J. Organomet. Chem. 303, 99. (b) S. Luo and K. H. Whitmire (1989). Inorg. Chem. 28, 1424.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kettle, S.F.A., Boccaleri, E., Diana, E. et al. Application of the Spherical Harmonic Model to the ν(CO) Vibrational Spectra of Some Fe(CO)4 and M(CO)5 (M=Cr, W) Transition Metal Cluster Carbonyl Species. Journal of Cluster Science 12, 175–186 (2001). https://doi.org/10.1023/A:1016679130458
Issue Date:
DOI: https://doi.org/10.1023/A:1016679130458