Abstract
From year to year, mankind is struggling with an increasing climate crisis. Constant climate change is related to human activities. The global dependence on non-renewable fossil fuels to meet our current energy needs cannot be sustained longer in the face of depleting fuel reserves. Particular attention should be paid to biofuels produced from lignocellulosic biomass, which is a waste product from the forestry, paper and agricultural industries, or a product derived from energy crops, intended for biofuel purposes. A problem that arises when using lignocellulosic biomass is the limited availability of fermentable sugars due to its complicated structure. For this reason, various methods of pretreatment of the raw material are used. The aim of the pretreatment is to increase the availability of cellulose for hydrolytic enzymes and to separate the main fractions of the lignocellulosic material, mainly the lignin molecule. After pretreatment and hydrolysis, the monomeric sugars are further processed into ethanol through the fermentation process. The last stages in biotechnological lignocellulose conversion are the distillation and dehydration process to obtain pure biofuel. This work is a review of the literature on second-generation biofuels produced from lignocellulosic biomass. Issues ranging from various types of raw materials, methods of its pretreatment, enzymatic hydrolysis, fermentation with the participation of various microorganisms, to various methods of dehydration of the obtained bioethanol were discussed.
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References
Karimi S, Karri RR, Tavakkoli Yaraki M, Koduru JR (2021) Processes and separation technologies for the production of fuel-grade bioethanol: a review. Environ Chem Lett 19:2873–2890. https://doi.org/10.1007/s10311-021-01208-9
Awoyale AA, Lokhat D (2021) Experimental determination of the effects of pretreatment on selected Nigerian lignocellulosic biomass in bioethanol production. Sci Rep 11:557. https://doi.org/10.1038/s41598-020-78105-8
Lamichhane G, Acharya A, Poudel DK, Aryal B, Gyawali N, Niraula P, Phuyal SR, Budhathoki P, Bk G, Parajuli N (2021) Recent advances in bioethanol production from lignocellulosic biomass. Int J Green Energy 18(7):731–744. https://doi.org/10.1080/15435075.2021.1880910
Baruah J, Nath BK, Sharma R, Kumar S, Deka RC, Baruah DC, Kalita E (2018) Recent trends in the pretreatment of lignocellulosic biomass for value-added products. Front Energy Res 6:141. https://doi.org/10.3389/fenrg.2018.00141
Yamashita Y, Sasaki Ch, Nakamura Y (2010) Effective enzyme saccharification and ethanol production from Japanese cedar using various pretreatment methods. J Biosci Bioeng 110(1):79–86. https://doi.org/10.1016/j.jbiosc.2009.12.009
Balat M (2011) Production of bioethanol from lignocellulosic materials via the biochemical pathway: a review. Energ Convers Manag 52:858–875. https://doi.org/10.1016/j.enconman.2010.08.013
Sarkar N, Gosh SK, Bannerjee S, Aikat K (2012) Bioethanol production from agricultural wastes: an overview. Renew Energy 37:19–27. https://doi.org/10.1016/j.renene.2011.06.045
Kim S, Dale BE (2004) Global potential bioethanol production from wasted crops and crop residues. Biomass Bioenerg 26:361–375. https://doi.org/10.1016/j.biombioe.2003.08.002
Baeyens J, Kang Q, Appels L, Dewil R, Lv Y, Tan T (2015) Challenges and opportunities in improving the production of bio-ethanol. Prog Energ Combust Sci 47:60–88. https://doi.org/10.1016/j.pecs.2014.10.003
Koh LP, Ghazoul J (2008) Biofuels, biodiversity, and people: understanding the conflicts and finding opportunities. Biol Conserv 141:2450–2460. https://doi.org/10.1016/j.biocon.2008.08.005
Rzelewska-Piekut M, Regel-Rosocka M (2020) Technology of large volume alcohols, carboxylic acids and esters. Phys Sci Rev 20190034.https://doi.org/10.1515/9783110656367-004
Pulyaeva VN, Kharitonova NA, Kharitonova EN (2020) Advantages and disadvantages of the production and using of liquid biofuels. 2020 IOP Conf Ser: Mater Sci Eng 976:012031
Cheng JJ, Timilsina GR (2011) Status and barriers of advanced biofuel technologies: a review. Renew Energy 36:3541–3549. https://doi.org/10.1016/j.renene.2011.04.031
Cotana F, Cavalaglio G, Gelosia M, Nicolini A, Coccia V, Petrozzi A (2014) Production of bioethanol in a second generation prototype from pine wood chips. Energy Procedia 45:42–51. https://doi.org/10.1016/j.egypro.2014.01.006
Das N, Jena PK, Padhi D, Mohanty MK, Sahoo G (2021) A comprehensive review of characterization, pretreatment and its applications on different lignocellulosic biomass for bioethanol production. Biomass Conv Bioref. https://doi.org/10.1007/s13399-021-01294-3
Sánchez ÓJ, Cardona CA (2008) Trends in biotechnological production of fuel ethanol from different feedstocks. Bioresour Technol 99:5270–5295. https://doi.org/10.1016/j.biortech.2007.11.013
Mood SH, Golfeshan AH, Tabatabaei M, Jouzani GS, Najafi GH, Gholami M, Ardjmand M (2013) Lignocellulosic biomass to bioethanol, a comprehensive review with a focus on pretreatment. Renew Sustain Energy Rev 27:77–93. https://doi.org/10.1016/j.rser.2013.06.033
Mussato SI, Fernandes M, Milagres AMF, Roberto I (2008) Effect of hemicellulose and lignin on enzymatic hydrolysis of cellulose from brewer’s spent grain. Enzyme Microb Technol 43(2):124–129. https://doi.org/10.1016/j.enzmictec.2007.11.006
Menon V, Rao M (2012) Trends in bioconversion of lignocellulose: biofuels, platform chemicals & biorefinery concept. Prog Energ Combust 38:522–550. https://doi.org/10.1016/j.pecs.2012.02.002
Keshwani DR, Cheng JJ (2009) Switchgrass for bioethanol and other value-added applications: a review. Bioresour Technol 100:1515–1523. https://doi.org/10.1016/j.biortech.2008.09.035
Agbor VB, Cicek N, Sparling R, Berlin A, Levin DB (2011) Biomass pretreatment: fundamentals toward application. Biotechnol Adv 29:675–685. https://doi.org/10.1016/j.biotechadv.2011.05.005
Cardona Alzate CA, Sánchez Toro OJ (2006) Energy consumption analysis of integrated flow sheets for production of fuel ethanol from lignocellulosic biomass. Energy 31:2447–2459. https://doi.org/10.1016/j.energy.2005.10.020
Roy R, Rahman MS, Raynie DE (2020) Recent advances of greener pretreatment technologies of lignocellulose. Curr Res Green Sustain Chem 3:100035. https://doi.org/10.1016/j.crgsc.2020.100035
Wi SG, Cho EJ, Lee DS, Lee SJ, Lee YJ, Bae H-J (2015) Lignocellulose conversion for biofuel: a new pretreatment greatly improves downstream biocatalytic hydrolysis of various lignocellulosic materials. Biotechnol Biofuels 8:228. https://doi.org/10.1186/s13068-015-0419-4
Bhatia SK, Jagtap SS, Bedekar AA, Bhatia RK, Patelf AK, Pant D, Banu JR, Raoc CV, Kim Y-G, Yang Y-H (2020) Recent developments in pretreatment technologies on lignocellulosic biomass: effect of key parameters, technological improvements, and challenges. Bioresour Technol 300:122724. https://doi.org/10.1016/j.biortech.2019.122724
Barakat A, Chuetor S, Monlau F, Solhy A, Rouau X (2014) Eco-friendly dry chemo-mechanical pretreatments of lignocellulosic biomass: impact on energy and yield of the enzymatic hydrolysis. Appl Energ 113:97–105. https://doi.org/10.1016/j.apenergy.2013.07.015
Zabed H, Sahu JN, Suely A, Boyce AN, Faruq G (2017) Bioethanol production from renewable sources: current perspectives and technological progress. Renew Sust Energ Rev 71:475–501. https://doi.org/10.1016/j.rser.2016.12.076
Zhang K, Lu X, Li Y, Jiang X, Liu L, Wang H (2019) New technologies provide more metabolic engineering strategies for bioethanol production in Zymomonas mobilis. Appl Microbiol Biotechnol 103(5):2087–2099. https://doi.org/10.1007/s00253-019-09620-6
Jagtap SS, Rao CV (2018) Production of d-arabitol from d-xylose by the oleaginous yeast Rhodosporidium toruloides IFO0880. Appl Microbiol Biotechnol 102:143–151. https://doi.org/10.1007/s00253-017-8581-1
Kumar R, Tabatabaei M, Karimi K, Sárvári Horváth I (2016) Recent updates on lignocellulosic biomassderived ethanol—a review. Biofuel Res J 3:347–356. https://doi.org/10.18331/BRJ2016.3.1.4
Taherzadeh MJ, Karimi K (2008) Pretreatment of lignocellulosic wastes to improve ethanol and biogas production: a review. Int J Mol Sci 9:1621–1651. https://doi.org/10.3390/ijms9091621
Anwar Z, Gulfraz M, Irshad M (2014) Agro-industrial lignocellulosic biomass a key to unlock the future bio-energy: a brief review. J Radiat Res Appl Sci 7:163–173. https://doi.org/10.1016/j.jrras.2014.02.003
Kumar AK, Sharma S (2017) Recent updates on different methods of pretreatment of lignocellulosic feedstocks: a review. Bioresour Bioprocess 4(1):7. https://doi.org/10.1186/s40643-017-0137-9
Hideno A, Inoue H, Tsukahara K, Fujimoto S, Minowa T, Inoue S, Endo T, Sawayama S (2009) Wet disk milling pretreatment without sulfuric acid for enzymatic hydrolysis of rice straw. Bioresour Technol 100(10):2706–2711. https://doi.org/10.1016/j.biortech.2008.12.057
Kumar P, Barrett DM, Delwiche MJ, Stroeve P (2009) Methods for pretreatment of lignocellulosic biomass for efficient hydrolysis and biofuel production. Ind Eng Chem Res 48(8):3713–3729. https://doi.org/10.1021/ie801542g
Alvira P, Tomás-Pejó E, Bellesteros M, Negro MJ (2010) Pretreatment technologies for an efficient bioethanol production process based on enzymatic hydrolysis: a review. Bioresour Technol 101:4851–4861. https://doi.org/10.1016/j.biortech.2009.11.093
Yachmenev V, Condon B, Klasson T, Lambert A (2009) Acceleration of the enzymatic hydrolysis of corn stover and sugar cane bagasse celluloses by low intensity uniform ultrasound. J Biobased Mater Bioenergy 3(1):25–31. https://doi.org/10.1166/jbmb.2009.1002
Zhu Z, Macquarrie DJ, Simister R, Gomez LD, McQueen-Mason SJ (2015) Microwave assisted chemical pretreatment of Miscanthus under different temperature regimes. Sustain Chem Process 3:15. https://doi.org/10.1186/s40508-015-0041-6
Irmak S, Meryemoglu B, Sandip A, Subbiah J, Mitchell RB, Sarath G (2018) Microwave pretreatment effects on switchgrass and miscanthus solubilization in subcritical water and hydrolysate utilization for hydrogen production. Biomass Bioenerg 108:48–54. https://doi.org/10.1016/j.biombioe.2017.10.039
Kumar R, Mago G, Balan V, Wyman CE (2009) Physical and chemical characterizations of corn stover and poplar solids resulting from leading pretreatment technologies. Bioresour Technol 100:3948–3962. https://doi.org/10.1016/j.biortech.2009.01.075
Chen H, Liu J, Chang X, Chen D, Xue Y, Liu P, Lin H, Han S (2017) A review on the pretreatment of lignocellulose for high-value chemicals. Fuel Process Techno 160:196–206. https://doi.org/10.1016/j.fuproc.2016.12.007
Kucharska K, Rybarczyk P, Hołowacz I, Łukajtis R, Glinka M, Kamiński M (2018) Pretreatment of lignocellulosic materials as substrates for fermentation processes. Molecules 23:2937. https://doi.org/10.3390/molecules23112937
Verardi A, Blasi A, De Bari I, Calabrò V (2016) Steam pretreatment of Saccharum Officinarum L. bagasse by adding of impregnating agents for advanced Bioethanol production. Ecotoxicol Environ Saf 134:293–300. https://doi.org/10.1016/j.ecoenv.2015.07.034
Qin L, Liu ZH, Li BZ, Dale BE, Yuan YJ (2012) Mass balance and transformation of corn stover by pretreatment with different dilute organic acids. Bioresour Technol 112:319–326. https://doi.org/10.1016/j.biortech.2012.02.134
da Costa SL, Chundawat SPS, Balan V, Dale BE (2009) ‘Cradle-to-grave’ assessment of existing lignocellulose pretreatment technologies. Curr Opin Biotechnol 20:339–347. https://doi.org/10.1016/j.copbio.2009.05.003
Binod P, Sindhu R, Singhania RR, Vikram S, Devi L, Nagalakshmi S, Kurien N, Sukumaran RK, Pandey A (2010) Bioethanol production from rice straw: an overview. Bioresour Technol 101:4767–4774. https://doi.org/10.1016/j.biortech.2009.10.079
Sun S, Sun S, Cao X, Sun R (2016) The role of pretreatment in improving the enzymatic hydrolysis of lignocellulosic materials. Bioresour Technol 199:49–58. https://doi.org/10.1016/j.biortech.2015.08.061
Nitsos C, Rova U, Christakopoulos P (2018) Organosolv fractionation of softwood biomass for biofuel and biorefinery applications. Energies 11:50. https://doi.org/10.3390/en11010050
Lewandowska M, Szymańska K, Kordala N, Dąbrowska A, Bednarski W, Juszczuk A (2016) Evaluation of Mucor indicus and Saccharomyces cerevisiae capability to ferment hydrolysates of rape straw and Miscanthus giganteus as affected by the pretreatment method. Bioresour Technol 212:262–270. https://doi.org/10.1016/j.biortech.2016.04.063
Behera BC, Sethi BK, Mishra RR, Dutta SK, Thatoi HN (2017) Microbial cellulases—diversity & biotechnology with reference to mangrowe environment: a review. J Genet Eng Biotechnol 15:197–210. https://doi.org/10.1016/j.jgeb.2016.12.001
Sun Y, Cheng J (2002) Hydrolysis of lignocellulosic materials for ethanol production: a review. Bioresour Technol 83:1–11. https://doi.org/10.1016/S0960-8524(01)00212-7
Suhara H, Kodama S, Kamei I, Maekawa N, Meguro S (2012) Screening of selective lignin-degrading basidiomycetes and biological pretreatment for enzymatic hydrolysis of bamboo culms. Int Biodeterior Biodegradation 75:176–180. https://doi.org/10.1016/j.ibiod.2012.05.042
Liang YS, Yuan XZ, Zeng GM, Hu CL, Zhong H, Huang DL, Tang L, Zhao JJ (2010) Biodelignification of rice straw by Phanerochaete chrysosporium in the presence of dirhamnolipid. Biodegradation 21:615–624. https://doi.org/10.1007/s10532-010-9329-0
Hendriks ATWM, Zeeman G (2009) Pretreatments to enhance the digestibility of lignocellulosic biomass. Bioresour Technol 100:10–18. https://doi.org/10.1016/j.biortech.2008.05.027
Brandon SK, Eiteman MA, Patel K, Richbourg MM, Miller DJ, Anderson WF, Peterson JD (2008) Hydrolysis of Tifton 85 bermudagrass in a pressurizea batch hot water reactor. J Chem Technol Biot 83(4):505–512. https://doi.org/10.1002/jctb.1824
Zhang N, Xu H, Yang J, Xie J-C, Wei M, Zhao J, Jiang JC (2020) Effects of liquid hot water combined with 1, 4-butanediol on chemical composition and structure of Moso Bamboo. Appl Biochem Biotechnol 190(4):1177–1186. https://doi.org/10.1007/s12010-019-03173-0
Maurya DP, Vats S, Rai S, Negi S (2013) Optimization of enzymatic saccharification of microwave pretreated sugarcane tops through response surface methodology for biofuel. Indian J Exp Biol 51(11):992–996
Merino-Pérez O, Martínez-Palou R, Labidi J, Luque R (2015) Microwave-assisted pretreatment of lignocellulosic biomass to produce biofuels and value-added products. In: Fang Z, Smith Jr, Richard L, Qi X (eds) Production of biofuels and chemicals with microwave. Biofuels Biorefin 3:197–224. https://doi.org/10.1007/978-94-017-9612-5_10
Puligundla P, Oh S-E, Mok C (2016) Microwave-assisted pretreatment technologies for the conversion of lignocellulosic biomass to sugars and ethanol: a review. Carbon Lett 17:1–10. https://doi.org/10.5714/CL.2016.17.1.001
Behera S, Arora R, Nandhagopal N, Kumar S (2014) Importance of chemical pretreatment for bioconversion of lignocellulosic biomass. Renew Sust Energ Rev 36:91–106. https://doi.org/10.1016/j.rser.2014.04.047
Parthiba O, Karthikeyan E, Trably S, Mehariya N, Bernet JWC, Carrere WH (2018) Pretreatment of food waste for methane and hydrogen recovery: a review. Bioresour Technol 249:1025–1039. https://doi.org/10.1016/j.biortech.2017.09.105
Van der Pol E, Bakker R, van Zeeland A, Garcia DS, Punt A, Eggink G (2015) Analysis of by-product formation and sugar monomerization in sugarcane bagasse pretreated at pilot plant scale: differences between autohydrolysis, alkaline and acid pretreatment. Bioresour Technol 181:114–123. https://doi.org/10.1016/j.biortech.2015.01.033
Kootstra A, Maarten J, Beeftink HH, Scott EL, Sanders JPM (2009) Comparison of dilute mineral and organic acid pretreatment for enzymatic hydrolysis of wheat straw. Biochem Eng J 46:126–131. https://doi.org/10.1016/j.bej.2009.04.020
Woo-Seok L, Jae-Won L (2013) Influence of pretreatment condition on the fermentable sugar production and enzymatic hydrolysis of dilute acid-pretreated mixed softwood. Bioresour Technol 140:306–311. https://doi.org/10.1016/j.biortech.2013.04.103
McIntoch S, Vancov T (2010) Enhanced enzyme saccharification of Sorghum bicolor straw using dilute alkali pretreatment. Bioresour Technol 101:6718–6727. https://doi.org/10.1016/j.biortech.2010.03.116
Cardona E, Rios J, Peña J, Rios L (2014) Effects of the pretreatment method on enzymatic hydrolysis and ethanol fermentability of the cellulosic fraction from elephant grass. Fuel 118:41–47. https://doi.org/10.1016/j.fuel.2013.10.055
Bi S, Peng L, Chen K, Zhu Z (2016) Enhanced enzymatic saccharification of sugarcane bagasse pretreated by combining O2 and NaOH. Bioresour Technol 214:692–699. https://doi.org/10.1016/j.biortech.2016.05.041
Yoo CG, Pu Y, Ragauskas AJ (2017) Ionic liquids: promising green solvents for lignocellulosic biomass utilization. Cur Opin Green Sustain Chem 5:5–11. https://doi.org/10.1016/j.cogsc.2017.03.003
Serna LD, Alzate CO, Alzate CC (2016) Supercritical fluids as a green technology for the pretreatment of lignocellulosic biomass. Bioresour Technol 199:113–120. https://doi.org/10.1016/j.biortech.2015.09.078
Park J, Shin H, Yoo S, Zoppe JO, Park S (2015) Delignification of lignocellulosic biomass and its effect on subsequent enzymatic hydrolysis. BioRes 10(2):2732–2743. https://doi.org/10.15376/biores.10.2.2732-2743
Gunny AAN, Arbain D, Nashef EM, Jamal P (2015) Applicability evaluation of deep eutectic solvents–cellulase system for lignocellulose hydrolysis. Bioresour Technol 181:297–302. https://doi.org/10.1016/j.biortech.2015.01.057
Meng X, Parikh A, Seemala B, Kumar R, Pu Y, Christopher P, Wyman CE, Cai CM, Ragauskas AJ (2018) Chemical transformations of poplar lignin during cosolvent enhanced lignocellulosic fractionation process. ACS Sust Chem Eng 6:8711–8718. https://doi.org/10.1021/acssuschemeng.8b01028
Patinvoh RJ, Osadolor OA, Chandolias K, Sárvári Horváth I, Taherzadeh MJ (2017) Innovative pretreatment strategies for biogas production. Bioresour Technol 224:13–24. https://doi.org/10.1016/j.biortech.2016.11.083
Fockink DH, Morais AR, Ramos LP, Łukasik RM (2018) Insight into the high-pressure CO2 pre-treatment of sugarcane bagasse for a delivery of upgradable sugars. Energy 151:536–544. https://doi.org/10.1016/j.energy.2018.03.085
Zhao MJ, Xu QQ, Li GM, Zhang QZ, Zhou D, Yin JZ, Zhan HS (2019) Pretreatment of agricultural residues by supercritical CO2 at 50–80 °C to enhance enzymatic hydrolysis. J Energy Chem 31:39–45. https://doi.org/10.1016/j.jechem.2018.05.003
Escobar ELN, da Silva TA, Pirich CL, Corazza ML, Pereira Ramos L (2020) Supercritical fluids: a promising technique for biomass pretreatment and fractionation. Front Bioeng Biotechnol 8:252. https://doi.org/10.3389/fbioe.2020.00252
Liang J, Chen X, Wang L, Wei X, Wang H, Lu S, Li Y (2017) Subcritical carbon dioxide-water hydrolysis of sugarcane bagasse pith for reducing sugars production. Bioresour Technol 228:147–155. https://doi.org/10.1016/j.biortech.2016.12.080
Kumar AK, Sharma S (2017) Recent updates on different methods of pretreatment of lignocellulosic feedstocks: a review. Bioresour Bioprocess 4:7–17. https://doi.org/10.1186/s40643-017-0137-9
Prado JM, Lachos-Perez D, Forster-Carneiro T, Rostagno MA (2016) Sub- and supercritical water hydrolysis of agricultural and food industry residues for the production of fermentable sugars: a review. Food Bioprod Process 98:95–123. https://doi.org/10.1016/j.fbp.2015.11.004
Morais ARC, da Costa Lopes AM, Bogel-Łukasik R (2015) Carbon dioxide in biomass processing: contributions to the green biorefinery concept. Chem Rev 115:3–27. https://doi.org/10.5714/CL.2016.17.1.001
Weerachanchai P, Lee JM (2017) Recovery of lignin and ionic liquid by using organic solvents. J Ind Eng Chem 49:122–132. https://doi.org/10.1016/J.JIEC.2017.01.018
Marin-Batista JD, Mohedano AF, de la Rubia A (2021) Pretreatment of lignocellulosic biomass with 1-ethyl-3-methylimidazolium acetate for its eventual valorization by anaerobic digestion. Resources 10:118. https://doi.org/10.3390/resources10120118
Brandt A, Ray MJ, To TQ, Leak DJ, Murphy RJ, Welton T (2011) Ionic liquid pretreatment of lignocellulosic biomass with ionic liquid–water mixtures. Green Chem 13:2489–2499. https://doi.org/10.1039/c1gc15374a
Singh S (2018) Designing tailored microbial and enzymatic response in ionic liquids for lignocellulosic biorefineries. Biophys Rev 10:911–913. https://doi.org/10.1007/s12551-018-0418-3
Socha AM, Parthasarathi R, Shi J, Pattathil S, Whyte D, Bergeron M, George A, Tran K, Stavila V, Venkatachalam S, Hahn MG, Simmons BA, Singh S (2014) Efficient biomass pretreatment using ionic liquids derived from lignin and hemicellulose. Proc Nat Acad Sci 111:E3587–E3595. https://doi.org/10.1073/pnas.1405685111
Yan P, Xu Z, Zhang C, Liu X, Xu W, Zhang ZC (2015) Fractionation of lignin from eucalyptus bark using amine-sulfonate functionalized ionic liquids. Green Chem 17:4913–4920. https://doi.org/10.1039/C5GC01035G
Sun J, Shi J, Murthy Konda NVSN, Campos D, Liu D, Nemser S, Shamshina J, Dutta T, Berton P, Gurau G, Rogers RD, Simmons BA, Singh S (2017) Efficient dehydration and recovery of ionic liquid after lignocellulosic processing using pervaporation. Biotechnol Biofuels 10:154. https://doi.org/10.1186/s13068-017-0842-9
Moyer P, Kim K, Abdoulmoumine N, Chmely SC, Long BK, Carrier DJ, Labbé N (2018) Structural changes in lignocellulosic biomass during activation with ionic liquids comprising 3-methylimidazolium cations and carboxylate anions. Biotechnol Biofuels 11:265. https://doi.org/10.1186/s13068-018-1263-0
Capolupo L, Faraco V (2016) Green methods of lignocellulose pretreatment for biorefinery development. Appl Microbiol Biotechnol 100:9451–9467. https://doi.org/10.1007/s00253-016-7884-y
Zhao ZM, Meng X, Scheidemantle B, Pu Y, Liu ZH, Li BZ, Wyman CE, Cai CM, Ragauskas AJ (2022) Cosolvent enhanced lignocellulosic fractionation tailoring lignin chemistry and enhancing lignin bioconversion. Bioresour Technol 347:126367. https://doi.org/10.1016/j.biortech.2021.126367
Nguyen TY, Cai CM, Kumar R, Wyman CE (2015) Co-solvent pretreatment reduces costly enzyme requirements for high sugar and ethanol yields from lignocellulosic biomass. Chemsuschem 8(10):1716–1725. https://doi.org/10.1002/cssc.201403045
Mbous YP, Hayyan M, Hayyan A, Wong WF, Hashim MA, Looi CY (2017) Applications of deep eutectic solvents in biotechnology and bioengineering—promises and challenges. Biotechnol Adv 35(2):105–134. https://doi.org/10.1016/j.biotechadv.2016.11.006
Satlewal A, Agrawal R, Bhagia S, Sangoro J, Ragauskas AJ (2018) Natural deep eutectic solvents for lignocellulosic biomass pretreatment: recent developments, challenges and novel opportunities. Biotechnol Adv 36(8):2032–2050. https://doi.org/10.1016/j.biotechadv.2018.08.009
Kumar AK, Parikh BS, Pravakar M (2016) Natural deep eutectic solvent mediated pretreatment of rice straw: bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue. Environ Sci Pollut Res Int 23:9265–9275. https://doi.org/10.1007/s11356-015-4780-4
Wan C, Zhou Y, Li Y (2011) Liquid hot water and alkaline pretreatment of soybean straw for improving cellulose digestibility. Bioresour Technol 102:6254–6259. https://doi.org/10.1016/j.biortech.2011.02.075
Ninomiya K, Kohori A, Tatsumi M, Osawa K, Endo T, Kakuchi R, Ogino C, Takahashi SN, K, (2015) Ionic liquid/ultrasound pretreatment and in situ enzymatic saccharification of bagasse using biocompatible cholinium ionic liquid. Bioresour Technol 176:169–174. https://doi.org/10.1016/j.biortech.2014.11.038
Li D, Tan Y, Zhou Y, Pathak S, Sendjaja AY, Abdul Majid M, Chowdhury P, Ng WJ (2015) Comparative study of low-energy ultrasonic and alkaline treatment on biosludge from secondary industrial wastewater treatment. Environ Technol 36:2239–2248. https://doi.org/10.1080/09593330.2015.1025103
Ramadoss G, Muthukumar K (2014) Ultrasound assisted ammonia pretreatment of sugarcane bagasse for fermentable sugar production. Biochem Eng J 83:33–41. https://doi.org/10.1016/j.bej.2013.11.013
Parveen H, Tewari L, Pradhan D, Chaudhary P (2021) Combined pretreatment as an effective technology in breaking of phenolic polymer lignin from sustainable biomass: Bambusa balcooa. Preprints 2:2021050656. https://doi.org/10.20944/preprints202105.0656.v1
Dimos K, Paschos T, Louloudi A, Kalogiannis KG, Lappas AA, Papayannakos N, Kekos D, Mamma D (2019) Effect of various pretreatment methods on bioethanol production from cotton stalks. Fermentation 5(1):5. https://doi.org/10.3390/fermentation5010005
Kordala N, Lewandowska M, Bednarski W (2021) Effect of the method for the elimination of inhibitors present in Miscanthus giganteus hydrolysates on ethanol production effectiveness. Biomass Convers Bior. https://doi.org/10.1007/s13399-020-01255-2
Harmsen P, Huijgen W, Bermudez L, Bakker R (2010) Literature review of physical and chemical pretreatment processes for lignocellulosic biomass. Biosynergy Wageningen UR Food & Biobased Research
Zhou Z, Liu D, Zhao X (2021) Conversion of lignocellulose to biofuels and chemicals via sugar platform: an updated review on chemistry and mechanisms of acid hydrolysis of lignocellulose. Renew Sustain Energy Rev 146:111169. https://doi.org/10.1016/j.rser.2021.111169
El-Zawawy WK, Ibrahim MM, Abdel-Fattah YR, Soliman NA, Mahmoud MM (2011) Acid and enzyme hydrolysis to convert pretreated lignocellulosic materials into glucose for ethanol production. Carbohydr Polym 84:865–871. https://doi.org/10.1016/j.carbpol.2010.12.022
Zhang XZ, Zhang YHP (2013) Cellulases: characteristics, sources, production, and applications. In: Yang S-T (ed) Bioprocessing Technologies in Biorefinery for Sustainable Production of Fuels, Chemicals, and Polymers. Wiley, pp 131–146
Singhania RR, Sukumaran RK, Patel AK, Larroche C, Pandey A (2010) Advancement and comparative profiles in the production technologies using solid-state and submerged fermentation for microbial cellulases. Enzyme Microb Tech 46:541–549. https://doi.org/10.1016/j.enzmictec.2010.03.010
Gírio FM, Fonseca C, Carvalheiro F, Duarte LC, Marques S, Bogel-Łukasik R (2010) Hemicelluloses for fuel ethanol: a review. Bioresour Technol 101:4775–4800. https://doi.org/10.1016/j.biortech.2010.01.088
Dawood A, Ma K (2020) Applications of microbial β-mannanases. Front Bioeng Biotechnol 8:598630. https://doi.org/10.3389/fbioe.2020.598630
Palonen H (2004) Role of lignin in the enzymatic hydrolysis of lignocelluloses. VTT Publications, Espoo, pp 22–24
Juturu V, Wu JCh (2014) Microbial cellulases: engineering, production and applications. Renew Sust Energ Rev 33:188–203. https://doi.org/10.1016/j.rser.2014.01.077
Gusakov AV (2011) Alternatives to Trichoderma reesei in biofuel production. Trends Biotechnol 29(9):419–425. https://doi.org/10.1016/j.tibtech.2011.04.004
Ren H, Richard TL, Moore KJ (2007) The impact of enzyme characteristics on corn stover fiber degradation and acid production during ensiled storage. Appl Biochem Biotechnol 137–140(1–12):221–238. https://doi.org/10.1007/s12010-007-9054-2
Srivastava N, Srivastava M, Mishra PK, Gupta VK, Molina G, Rodriguez-Couto S, Manikanta A, Ramteke PW (2018) Applications of fungal cellulases in biofuel production: advances and limitations. Renew Sust Energ Rev 82:2379–2386. https://doi.org/10.1016/j.rser.2017.08.074
Quiroz-Castañeda RE, Folch-Mallol JL (2013) Hydrolysis of biomass mediated by cellulases for the production of sugars. In: Chandel A (ed) Sustainable degradation of lignocellulosic biomass—techniques, applications and commercialization. IntechOpen, pp 119–155
Baig KS (2020) Interaction of enzymes with lignocellulosic materials: causes, mechanism and influencing factors. Bioresour Bioprocess 7:21. https://doi.org/10.1186/s40643-020-00310-0
Abdul Fattah SS, Mohamed R, Jahim JM, Illias RM, Abu Bakar FD, Murad AMA (2016) Commercial cellulases and hemicellulase performance towards oil palm empty fruit bunch (OPEFB) hydrolysis. AIP Conf Proc 1784:020002. https://doi.org/10.1063/1.4966712
Zhang Y, Yang J, Luo L, Wang E, Wang R, Liu L, Liu J, Yuan H (2020) Low-cost cellulase-hemicellulase mixture secreted by Trichoderma harzianum EM0925 with complete saccharification efficacy of lignocellulose. Int J Mol Sci 21:371–389. https://doi.org/10.3390/ijms21020371
http://www.genencor.com/fileadmin/user_upload/genencor/documents/TRIO_ProductSheet_LowRes.pdf. Accessed 12 Sept 2021
https://www.novozymes.com/-/media/Project/Novozymes/Website/website/advance-your-business/05_L2_Bioenergy/Benefit-sheets/Cellic-CTec3-HS-application-sheet-NA.pdf. Accessed 12 Sept 2021
https://biosolutions.novozymes.com/en/bioenergy/products/biomass-conversion/cellic-ctec3-hs. Accessed 12 Sept 2021
Van Dyk JS, Pletschke BI (2012) A review of lignocellulose bioconversion using enzymatic hydrolysis and synergistic cooperation between enzymes—factors affecting enzymes, conversion and synergy. Biotechnol Adv 30:1458–1480. https://doi.org/10.1016/j.biotechadv.2012.03.002
Lee I, Yu JH (2020) The production of fermentable sugar and bioethanol from acacia wood by optimizing dilute sulfuric acid pretreatment and post treatment. Fuel 275:117943. https://doi.org/10.1016/j.fuel.2020.117943
Saekhow B, Chookamlang S, Na-u-dom A, Leksawasdi N, Sanguanchaipaiwong V (2020) Enzymatic hydrolysis of cassava stems for butanol production of isolated Clostridium sp. Energy Rep 6(1):196–201. https://doi.org/10.1016/j.egyr.2019.08.042
Martins MP, Ventorim RZ, Coura RR, Maitan-Alfenas GP, Alfenas RF, Guimaraes VM (2018) The β-xylosidase from Ceratocystis fimbriata RM35 improves the saccharification of sugarcane bagasse. Biocatal Agric Biotechnol 13:291–298. https://doi.org/10.1016/j.bcab.2018.01.009
García-Aparicio MP, Ballesteros M, Manzanares P, Ballesteros I, González A, Negro MJ (2007) Xylanase contribution to the efficiency of cellulose enzymatic hydrolysis of barley straw. In: Mielenz JR, Klasson KT, Adney WS, McMillan JD (eds) Applied Biochemistry and Biotecnology. ABAB Symposium. Humana Press. https://doi.org/10.1007/978-1-60327-181-331
Chen H, Wang L (2016) Technologies for biochemical conversion of biomass. 1st edition, ISBN: 9780128025949
Karnaouri A, Choroian K, Zouraris D, Karantonis A, Topakas E, Rova U, Christakopoulos P (2022) Lytic polysaccharide monooxygenases as powerful tools in enzymatically assisted preparation of nano-scaled cellulose from lignocellulose: a review. Bioresour Technol 345:126491. https://doi.org/10.1016/j.biortech.2021.126491
Ladevèze S, Haon M, Villares A, Cathala B, Grisel S, Herpoël-Gimbert I (2017) The yeast Geotrichum candidum encodes functional lytic polysaccharide monooxygenases. Biotechnol Biofuels 10:215. https://doi.org/10.1186/s13068-017-0903-0
Bernardi AV, Gerolamo LE, de Gouvêa PF, Yonamine DK, Pereira LMS, de Oliveira AHC (2020) LPMO AfAA9_B and cellobiohydrolase AfCel6A from A. fumigatus boost enzymatic saccharification activity of cellulase cocktail. Int J Mol Sci 22(1):276. https://doi.org/10.3390/ijms22010276
Liu G, Qu Y (2021) Integrated engineering of enzymes and microorganisms for improving the efficiency of industrial lignocellulose deconstruction. Eng Micriobiol 1:100005. https://doi.org/10.1016/j.engmic.2021.100005
Song B, Li BY, Wang XY, Shen W, Park SJ, Collings C, Feng AR, Smith SJ, Walton JD, Ding SY (2018) Real-time imaging reveals that lytic polysaccharide monooxygenase promotes cellulase activity by increasing cellulose accessibility. Biotechnol Biofuels 11:41. https://doi.org/10.1186/s13068-018-1023-1
Igarashi K, Uchihashi T, Koivula A, Wada M, Kimura S, Okamoto T, Penttila M, Ando T, Samejima M (2011) Traffic jams reduce hydrolytic efficiency of cellulase on cellulose surface. Science 333(6047):1279–1282. https://doi.org/10.1126/science.1208386
Talebnia F, Karakashev D, Angelidaki I (2010) Production of bioethanol from wheat straw: an overview on pretreatment, hydrolysis and fermentation. Bioresour Technol 101:4744–4753. https://doi.org/10.1016/j.biortech.2009.11.080
Karimi K, Zamani A (2013) Mucor indicus: Biology and industrial application perspectives: a review. Biotechnol Adv 31:466–481. https://doi.org/10.1016/j.biotechadv.2013.01.009
Karimi K, Brandberg T, Edebo L, Taherzadeh MJ (2005) Fed-batch cultivation of Mucor indicus in dilute-acid lignocellulosic hydrolyzate for ethanol production. Biotechnol Lett 27:1395–1400. https://doi.org/10.1007/s10529-005-0688-2
Sues A, Millati R, Edebo L, Taherzadeh MJ (2005) Ethanol production from hexoses, pentoses, and dilute-acid hydrolyzate by Mucor indicus. FEMS Yeast Res 5:669–676. https://doi.org/10.1016/j.femsyr.2004.10.013
Millati R, Wikandari R, Trihandayani ET, Cahyanto MN, Taherzadeh MJ, Niklasson C (2011) Ethanol from oil palm empty fruit bunch via dilute-acid hydrolysis and fermentation by Mucor indicus and Saccharomyces cerevisiae. Agric J 6(2):54–59. https://doi.org/10.3923/aj.2011.54.59
Asachi R, Karimi K (2013) Enhanced ethanol and chitosan production from wheat straw by Mucor indicus with minimal nutrient consumption. Process Biochem 48:1524–1531. https://doi.org/10.1016/j.procbio.2013.07.013
Zhao L, Zhang X, Tan T (2008) Influence of various glucose/xylose mixtures on ethanol production by Pachysolen tannophilus. Biomass Bioenerg 32:1156–1161. https://doi.org/10.1016/j.biombioe.2008.02.011
Zabed H, Sahu JN, Suely A, Boyce AN, Faruq G (2017) Bioethanol production from renewable sources: current perspectives and technological progress. Renew Sustain Energy Rev 71:475–501. https://doi.org/10.1016/j.rser.2016.12.076
Lee TY, Kim MD, Kim KY, Park K, Ryu YW, Seo JH (2000) A parametric study on ethanol production from xylose by Pichia stipitis. Biotechnol Bioprocess Eng 5:27–31. https://doi.org/10.1007/BF02932349
Converti A, Perego P, Dominguez JM, Silva SS (2001) Effect of temperature on the microaerophilic metabolism of Pachysolen tannophilus. Enzyme Microb Tech 28:339–345. https://doi.org/10.1016/s0141-0229(00)00330-6
Agbogbo FK, Coward-Kelly G (2008) Cellulosic ethanol production using the naturally occurring xylose-fermenting yeast, Pichia stipitis. Biotechnol Lett 30:1515–1524. https://doi.org/10.1007/s10529-008-9728-z
Dien BS, Cotta MA, Jeffries TW (2003) Bacteria engineered for fuel ethanol production: current status. Appl Microbiol Biotechnol 63:258–266. https://doi.org/10.1007/s00253-003-1444-y
Li X, Kim TH, Nghiem NP (2010) Bioethanol production from corn stover using aqueous ammonia pretreatment and two-phase simultaneous saccharification and fermentation (TPSSF). Bioresour Technol 101(15):5910–5916. https://doi.org/10.1016/j.biortech.2010.03.015
Kuhad RC, Gupta R, Khasa YP, Singh A, Zhang Y-HP (2011) Bioethanol production from pentose sugars: current status and future prospects. Renew Sust Energ Rev 15:4950–4962. https://doi.org/10.1016/j.rser.2011.07.058
Moysés DN, Reis VCB, Almeida JRM, Moraes LMP, Torres FAG (2016) Xylose Fermentation by Saccharomyces cerevisiae: challenges and prospects. Int J Mol Sci 17(3):1–18. https://doi.org/10.3390/ijms17030207
Qureshi N, Dien BS, Saha BC, Iten L, Liu S, Hughes SR (2015) Genetically engineered Escherichia coli FBR5 to use cellulosic sugars: production of ethanol from corn fiber hydrolysate employing commercial nutrient medium. Eur Chem Bull 4(3):130–134. https://doi.org/10.1002/btpr.1584
Abo BO, Gao M, Wang Y, Chuanfu W, Hongzhi M, Wang Q (2019) Lignocellulosic biomass for bioethanol: an overview on pretreatment, hydrolysis and fermentation processes. Rev Environ Health 34(1):57–68. https://doi.org/10.1515/reveh-2018-0054
Olofsson K, Bertilsson M, Lidén G (2008) A short review on SSF—an interesting process option for ethanol production from lignocellulosic feedstocks. Biotechnol Biofuels 1(7):1–14. https://doi.org/10.1186/1754-6834-1-7
Choudhary J, Singh S, Nain L (2016) Thermotolerant fermenting yeasts for simultaneous saccharification fermentation of lignocellulosic biomass. Electron J Biotechnol 21:82–92. https://doi.org/10.1016/j.ejbt.2016.02.007
Paulova L, Patakova P, Branska B, Rychtera M, Melzoch K (2015) Lignocellulosic ethanol: technology design and its impact on process efficiency. Biotechnol Adv 33:1091–1107. https://doi.org/10.1016/j.biotechadv.2014.12.002
Hans M, Kumar S, Chandel AK, Polikarpov I (2019) A review on bioprocessing of paddy straw to ethanol using simultaneous saccharification and fermentation. Process Biochem 85:125–134. https://doi.org/10.1016/j.procbio.2019.06.019
Yasuda M, Nagai H, Takeo K, Ishii Y, Ohta K (2014) Bio-ethanol production through simultaneous saccharification and co-fermentation (SSCF) of a low-moisture anhydrous ammonia (LMAA)-pretreated napier grass (Pennisetum Purpureum Schumach). Springerplus 3(1):333. https://doi.org/10.1186/2193-1801-3-333
Qin L, Zhao X, Wen-Chao L, Zhu JQ, Liu L, Bing-Zhi L, Yuan YJ (2018) Process analysis and optimization of simultaneous saccharification and co-fermentation of ethylenediamine-pretreated corn stover for ethanol production. Biotechnol Biofuels 11(1):118. https://doi.org/10.1186/s13068-018-1118-8
McIntosh S, Zhang Z, Palmer J, Wong HH, Doherty WOS, Vancov T (2016) Pilot-scale cellulosic ethanol production using eucalyptus biomass pre-treated by dilute acid and steam explosion. Biofuels Bioprod Biorefin 10(4):346–358. https://doi.org/10.1002/bbb.1651
Robak K, Balcerek M (2018) Review of second-generation bioethanol production from residual biomass. Food Technol Biotechnol 56(2):2. https://doi.org/10.17113/ftb.56.02.18.5428
Tokin R, Ipsen JØ, Westh P, Johansen KS (2020) The synergy between LPMOs and cellulases in enzymatic saccharification of cellulose is both enzyme- and substrate-dependent. Biotechnol Lett 42:1975–1984. https://doi.org/10.1007/s10529-020-02922-0
Quinlan RJ, Sweeney MD, Lo Leggio L, Otten H, Poulsen J-CN, Johansen KS, Krogh KBRM, Jørgensen CI, Tovborg M, Anthonsen A, Tryfona T, Walter CP, Dupree P, Xu F, Davies GJ, Walton PH (2011) Insights into the oxidative degradation of cellulose by a copper metalloenzyme that exploits biomass components. Proc Natl Acad Sci 108:15079–15084
Ishola MM, Jahandideh A, Haidarian B, Brandberg T, Taherzadeh MJ (2013) Simultaneous saccharification, filtration and fermentation (SSFF): a novel method for bioethanol production from lignocellulosic biomass. Bioresour Technol 133:68–73. https://doi.org/10.1016/j.biortech.2013.01.130
Hasunuma T, Kondo A (2012) Consolidated bioprocessing and simultaneous saccharification and fermentation of lignocellulose to ethanol with thermotolerant yeast strains. Process Biochem 47:1287–1294. https://doi.org/10.1016/j.procbio.2012.05.004
Olguin-Maciel E, Singh A, Chable-Villacis R, Tapia-Tussell R, Ruiz HA (2020) Consolidated bioprocessing, an innovative strategy towards sustainability for biofuels production from crop residues: an overview. Agronomy 10:1834. https://doi.org/10.3390/agronomy10111834
Xu Q, Singh A, Himmel ME (2009) Perspectives and new directions for the production of bioethanol using consolidated bioprocessing of lignocellulose. Curr Opin Biotechnol 20:364–371. https://doi.org/10.1016/j.copbio.2009.05.006
Liu ZH, Chen HZ (2016) Simultaneous saccharification and co-fermentation for improving the xylose utilization of steam exploded corn stover at high solid loading. Bioresour Technol 201:15–26. https://doi.org/10.1016/j.biortech.2015.11.023
Zhang M, Wang F, Su R, Qi W, He Z (2010) Ethanol production from high dry matter corncob using fed-batch simultaneous saccharification and fermentation after combined pretreatment. Bioresour Technol 101:4959–4964. https://doi.org/10.1016/j.biortech.2009.11.010
Kim TH, Choi CH, Oh KK (2013) Bioconversion of sawdust into ethanol using dilute sulfuric acid-assisted continuous twin screw-driven reactor pretreatment and fed-batch simultaneous saccharification and fermentation. Bioresour Technol 130:306–313. https://doi.org/10.1016/j.biortech.2012.11.125
Pruksathorn P, Vitidsant T (2009) Production of pure ethanol from azeotropic solution by pressure swing adsorption. Am J Eng Appl Sci 2(1):1–7. https://doi.org/10.1007/s11814-009-0184-9
Makertihartha IGBN, Dharmawijaya P, Wenten IG (2017) Recent advances on bioethanol dehydration using zeolite membrane. J Phys Conf Ser 877:012074. https://doi.org/10.1088/1742-6596/877/1/012074
Jeong J-S, Jeon H, Ko K-M, Chung B, Choi G-W (2012) Production of anhydrous ethanol using various PSA (pressure swing adsorption) processes in pilot plant. Renew Energy 42:41–45. https://doi.org/10.1016/j.renene.2011.09.027
Kupiec K, Rakoczy J, Komorowicz T, Larwa B (2014) Heat and mass transfer in adsorption-desorption cyclic process for ethanol dehydration. Chem Eng J 241:485–494. https://doi.org/10.1016/j.cej.2013.10.043
Rumbo-Morales JY, López-López G, Alvarado-Martínez VM, Sorcia-Vázquez FJ, Brizuela-Mendoza JA, Martínez-García M (2020) Parametric study and control of a pressure swing adsorption process to separate the water–ethanol mixture under disturbances. Sep Purif Technol 236:116214. https://doi.org/10.1016/j.seppur.2019.116214
Kupiec K, Kubala A (2006) Dehydration of ethanol used as a fuel additive. Environ Prot Eng 32(1):151–159
Rakoczy J, Kupiec K, Błąk A, Larwa T (2008) Dehydration of distillery spirit to obtain fuel bioethanol. Tech J Chem 1:115–124 (in polish)
Tajallipour M, Niu C, Dalai A (2013) Ethanol dehydration in a pressure swing adsorption process using canola meal. Energy Fuels 27(11):6655–6664. https://doi.org/10.1021/ef400897e
Yan B, Niu CH (2017) Pre-treating biosorbents for purification of bioethanol from aqueous solution. Int J Green Energy 14(3):245–252. https://doi.org/10.1080/15435075.2016.1254087
Tgarguifa A, Abderafi S, Bounahmidi T (2018) Energy efficiency improvement of a bioethanol distillery, by replacing a rectifying column with a pervaporation unit. Renew Energy 122:239–250. https://doi.org/10.1016/j.renene.2018.01.112
Amornraksa S, Subsaipin I, Simasatitkul L, Assabumrungrat S (2020) Systematic design of separation process for bioethanol production from corn stover. BMC Chem Eng 2:10. https://doi.org/10.1186/s42480-020-00033-1
Damayanti D, Supriyadi D, Amelia D, Saputri DR, Devi YLL, Auriyani WA, Wu HS (2021) Conversion of lignocellulose for bioethanol production, applied in bio-polyethylene terephthalate. Polymers 13:2886. https://doi.org/10.3390/polym13172886
Afonso C, Crespo J, Anastas P (2015) Green separation processes: fundamentals and applications, 1st edn. Wiley, Weinheim
Peng P, Lan Y, Liang L, Jia K (2021) Membranes for bioethanol production by pervaporation. Biotechnol Biofuels 14:10. https://doi.org/10.1186/s13068-020-01857-y
Wee SH, Tye CT, Bhatia S (2008) Membrane separation process—pervaporation through zeolite membrane. Sep Purif Technol 63:500–516. https://doi.org/10.1016/j.seppur.2008.07.010
Conde-Mejía C, Jiménez-Gutiérrez A (2020) Analysis of ethanol dehydration using membrane separation processes. Open Life Sci 15:122–132. https://doi.org/10.1515/biol-2020-0013
Samei M, Mohammadi T, Asadi AA (2013) Tubular composite PVA ceramic supported membrane for bio-ethanol production. Chem Eng Res Des 91:2703–2712. https://doi.org/10.1016/j.cherd.2013.03.008
Gao C, Zhang M, Ding J, Pan F, Jiang Z, Li Y, Zhao J (2014) Pervaporation dehydration of ethanol by hyaluronic acid/sodium alginate two-active-layer composite membranes. Carbohydr Polym 99:158–165. https://doi.org/10.1016/j.carbpol.2013.08.057
Meireles IT, Brazinha C, Crespo JG, Coelhoso IM (2013) A new microbial polysaccharide membrane for ethanol dehydration by pervaporation. J Membr Sci 425–426:227–234. https://doi.org/10.1016/j.memsci.2012.09.002
Raiser T (2012) Turning waste into energy. Sulzer Tech Rev 3:4–7
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Kordala, N., Walter, M., Brzozowski, B. et al. 2G-biofuel ethanol: an overview of crucial operations, advances and limitations. Biomass Conv. Bioref. 14, 2983–3006 (2024). https://doi.org/10.1007/s13399-022-02861-y
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DOI: https://doi.org/10.1007/s13399-022-02861-y