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Natural Halloysite@Si(CH2)3NH2@Cu(acac)2 as an efficient nanocatalyst for the one-pot and three-component synthesis of propargylamines under solvent-free conditions

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Abstract

A novel heterogeneous catalyst, natural halloysite@Si(CH2)3NH2@Cu(acac)2, was designed and synthesized through the functionalization of the halloysite nano clay surface by 3-aminopropyltriethoxysilane followed by copper acetylacetonate. The catalyst was characterized using various techniques such as FTIR, SEM, EDS, BET, ICP, XRD, TEM, and TGA. The catalytic activity of natural halloysite@Si(CH2)3NH2@Cu(acac)2) was also evaluated for the synthesis of propargylamines using multicomponent A3-coupling reaction of various aldehydes, amines, and phenylacetylene.

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Acknowledgements

The authors gratefully acknowledge the Research Council of Ferdowsi University of Mashhad (3/51239).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, Iran

    Seyed Ali Mousavi-Mashhadi & Ali Shiri

  2. Institute of Organic Chemistry, Clausthal University of Technology, Leibnizstraße 6, 38678, Clausthal-Zellerfeld, Germany

    Kimia Hoseinzade

Authors
  1. Seyed Ali Mousavi-Mashhadi
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  2. Kimia Hoseinzade
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  3. Ali Shiri
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Contributions

SM designed and planned the catalyst, the experiments, and the final analysis. KH contributed with SM to perform the analyses of the results and work up progress and wrote the manuscript with consulting to SM and AS. AS supervised the finding results and provided critical feedback on the final paper.

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Correspondence to Ali Shiri.

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Mousavi-Mashhadi, S.A., Hoseinzade, K. & Shiri, A. Natural Halloysite@Si(CH2)3NH2@Cu(acac)2 as an efficient nanocatalyst for the one-pot and three-component synthesis of propargylamines under solvent-free conditions. Res Chem Intermed 50, 17–30 (2024). https://doi.org/10.1007/s11164-023-05181-6

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