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Solvent-free coupling of aldehyde, alkyne, and amine over a versatile catalyst: Ag-functionalized mesoporous S, P-doped g-C3N4

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Abstract

In the present study, we introduce mesoporous g-C3N4/Ag co-doped with P and S which was designed and acquired by using mesoporous silica (SBA-15) as a hard templating agent and thiourea and chitosan phosphate as the dopants. The prepared catalyst was completely identified by FT-IR (Fourier-transform infrared spectroscopy), XRD (X-ray powder diffraction), FE-SEM (field-emission scanning electron microscopy), EDX (energy-dispersive spectroscopy), TEM (transmission electron microscopy), and Raman spectroscopy. The efficiency of the synthesized catalyst was evaluated toward the three-component coupling reaction, frequently named as A3 coupling. The higher activity of the prepared catalyst is because of the synergistic effects of phosphorus and sulfur co-doped together with Ag deposition. The desired products were achieved by an environmentally safe catalyst under the optimized conditions in high yields and short reaction time ranges.

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Acknowledgment

We are grateful to the Semnan University Research Council for the financial support of this research.

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  1. Department of Chemistry, Semnan University, Semnan, Iran

    Azra Bagherzade & Firouzeh Nemati

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  1. Azra Bagherzade
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Bagherzade, A., Nemati, F. Solvent-free coupling of aldehyde, alkyne, and amine over a versatile catalyst: Ag-functionalized mesoporous S, P-doped g-C3N4. Res Chem Intermed 47, 2917–2933 (2021). https://doi.org/10.1007/s11164-021-04453-3

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