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CuI NPs immobilized on a ternary hybrid system of magnetic nanosilica, PAMAM dendrimer and trypsin, as an efficient catalyst for A3‑coupling reaction

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Abstract

Preparation of a nanocatalyst (Fe3O4@SiO2@DNHCS-Tr@CuI) containing PAMAM dendrimer and trypsin enzyme supported on magnetic nanosilica on which CuI NPs were immobilized was reported in this paper. This nanocatalyst was characterized using FT-IR, FE-SEM, EDX, elemental mapping, XRD, and ICP analyses. The catalytic activity of Fe3O4@SiO2@DNHCS-Tr@CuI was evaluated by A3-coupling reaction, which indicated a highly efficient activity for the synthesis of propargylamines in green conditions, with high yields, short reaction times and easy separation and recovery of the catalyst for further use.

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Acknowledgements

The authors acknowledge the Research Council of the University of Mazandaran.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculties of Chemistry, University of Mazandaran, 4741695447, Babolsar, Iran

    Sahar Peiman, Robabeh Baharfar & Rahman Hosseinzadeh

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  1. Sahar Peiman
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  2. Robabeh Baharfar
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  3. Rahman Hosseinzadeh
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Correspondence to Robabeh Baharfar.

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Peiman, S., Baharfar, R. & Hosseinzadeh, R. CuI NPs immobilized on a ternary hybrid system of magnetic nanosilica, PAMAM dendrimer and trypsin, as an efficient catalyst for A3‑coupling reaction. Res Chem Intermed 48, 1365–1382 (2022). https://doi.org/10.1007/s11164-021-04654-w

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