Abstract
Nb–Ti–Si-based alloy powders were prepared by mechanical alloying (MA) of elemental particles. The evolutions of morphology, size, phase constituents, crystallite size, lattice strain, composition and internal microstructure, etc., of the alloy powders were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), laser particle size analyzer and transmission electron microscope (TEM) analyses. The alloy particles are gradually refined and their shapes become globular with the increase in milling time. The diffraction peaks of Nb solid solution (Nbss) phase shift toward lower 2θ angles during ball milling from 2 to 5 h, and after that Nbss diffraction peaks shift toward higher 2θ angles with the increase in milling time from 5 to 70 h, which is mainly attributed to the alteration of the lattice parameter of Nbss powders due to the solution of the alloying element atoms into Nb lattice to form Nbss. During ball milling process, the decrease in crystallite size and increase in lattice strain of Nbss powders lead to continuous broadening of their diffraction peaks. A typical lamellar microstructure is formed inside the powder particles after ball milling for 5 h and becomes more refined and homogenized with the increase in milling time. After 40-h-ball milling, the typical lamellar microstructure disappears and a very homogeneous microstructure is formed instead. This homogeneous microstructure is proved to be composed of only supersaturated Nbss phase.
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Bewlay BP, Jackson MR, Subramanian PR, Zhao JC. A review of very-high-temperature Nb-silicide-based composites. Metall Mater Trans A. 2003;34(10):2043.
Guo HS, Guo XP. Microstructure evolution and room temperature fracture toughness of an integrally directionally solidified Nb–Ti–Si based ultrahigh temperature alloy. Scr Mater. 2011;64(7):637.
Yeh CL, Chen WH. A comparative study on combustion synthesis of Nb–Si compounds. J Alloys Compd. 2006;425(1–2):216.
Geng J, Tsakiropoulos P, Shao GS. A study of the effects of Hf and Sn additions on the microstructure of Nbss/Nb5Si3 based in situ composites. Intermetallics. 2007;15(1):69.
Lu YY, Zhang J, Tian LX, Li YL, Ma CL. Microstructural evolution of unidirectionally solidified Nbss–Nb5Si3 eutectic alloy. Rare Met. 2011;30(S):335.
Kim WY, Tanaka H, Hanada S. Microstructure and high temperature strength at 1773 K of Nbss/Nb5Si3 composites alloyed with molybdenum. Intermetallics. 2002;10(6):625.
Zhang S, Guo XP. Effects of B addition on the microstructure and properties of Nb silicide based ultrahigh temperature alloys. Intermetallics. 2015;57:83.
Hong Z, Zhang H, Weng JF, Su LF, Li Z, Jia LN. Oxidation behavior of Nb–24Ti–18Si–2Al–2Hf–4Cr and Nb–24Ti–18Si–2Al–2Hf–8Cr hypereutectic alloys at 1250°C. Rare Met. 2015; doi:10.1007/s12598-015-0600-8.
Ahmadi E, Malekzadeh M, Sadrnezhaad SK. Preparation of nanostructured high-temperature TZM alloy by mechanical alloying and sintering. Int J Refract Met Hard Mater. 2011;29(1):141.
Guo SB, Kang QP, Liu J, Qu XH. Fabrication of Ti3AlC2 ceramic material by mechanical alloying. Rare Met. 2010;29(4):376.
Yi DQ, Li D, Li J, Zhou HM. Powder metallurgic process for preparing Nb–15Ti–11Al–10Si composites. Chin J Rare Met. 2007;31(4):472.
Wang XL, Zhang KF. Mechanical alloying, microstructure and properties of Nb–16Si alloy. J Alloys Compd. 2010;490(1–2):677.
Wang TT, Guo XP. Morphology and phase constituents of mechanical alloyed Nb–Ti–Si based ultrahigh temperature alloy powders. Rare Met. 2007;30(S):427.
Vyas A, Rao KP, Prasad YVRK. Mechanical alloying characteristics and thermal stability of Ti–Al–Si and Ti–Al–Si–C powders. J Alloys Compd. 2009;475(1–2):252.
Naidoo M, Raethel J, Sigalas I, Herrmann M. Preparation of (Ti, Ta)–(C, N) by mechanical alloying. Int J Refract Met Hard Mater. 2012;35:178.
Riahi S, Rajabi M, Rabiee SM. Characterization of porous Ti-bioglass composite produced by mechanical milling and space holder sintering. Rare Met. 2015;34(9):638.
Li Z, Peng LM. Microstructural and mechanical characterization of Nb-based in situ composites from Nb–Si–Ti ternary system. Acta Mater. 2007;55(19):6573.
Gavrilov D, Vinogradov O, Shaw WJD. Simulation of mechanical alloying in a shaker ball mill with variable size particle. In: Proceedings of International Conference on Composite Materials. Cambridge; 1995. 11.
Takacs L, Pardavi-Horvath M. Nanocomposite formation in the Fe3O4–Zn system by reaction milling. J Appl Phys. 1994;75(10):5864.
Williamson GK, Hall WH. X-ray line broadening from filed aluminium and wolfram. Acta Mater. 1953;1(1):22.
Cullity BD, Stock SR. Elements of X-Ray Diffraction. Cohen M, editors. Englewood Cliffs, New Jersey: Prentice-Hall; 2001. 3.
Loginov PA, Levashov EA, Kurbatkina VV, Zaitsev AA, Sidorenko DA. Evolution of the microstructure of Cu–Fe–Co–Ni powder mixtures upon mechanical alloying. Powder Technol. 2015;276:166.
Klug HP, Alexander LE. X-Ray Diffraction Procedures: for Polycrystalline and Amorphous Materials. New York: Wiley; 1954. 6.
Kim HS, Madavali B, Eom TJ, Kim CM, Koo JM, Lee TH, Hong SJ. Effect of different mechanical milling processes on morphology and microstructural changes of nano and micron Al-powders. Arch Metall Mater. 2015;60(2):1235.
Schwarz RB. Microscopic model for mechanical alloying. Mater Sci Forum. 1998;269–272:665.
Slama C, Abdellaoui M. Microstructure characterization of nanocrystalline (Ti0.9W0.1)C prepared by mechanical alloying. Int J Refract Met Hard Mater. 2016;54:270.
Fecht HJ. Nanostructure formation by mechanical attrition. Nanostruct Mater. 1995;6(1–4):33.
Xun YW, Mohamed FA, Lavernia EJ. Synthesis of nanocrystalline Zn-22 pct Al using cryomilling. Metall Mater Trans A. 2004;35(2):573.
Nouri A, Chen XB, Li YC, Yamada Y, Hodgson PD, Wen C. Synthesis of Ti–Sn–Nb alloy by powder metallurgy. Mater Sci Eng A Struct. 2008;485(1–2):562.
Bahrami AH, Ghayour H, Sharafi S. Evolution of microstructural and magnetic properties of mechanically alloyed Fe80−x Ni20Si x nanostructured powders. Powder Technol. 2013;249:7.
Botcharova E, Heilmaier M, Freudenberger J, Drew G, Kudashow D, Martin U, Schultz L. Supersaturated solid solution of niobium in copper by mechanical alloying. J Alloys Compd. 2003;351(1–2):119.
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (Nos. 51371145, 51431003, U1435201), the Research Fund of the State Key Laboratory of Solidification Processing, China (No. 143-TZ-2016) and the Doctorate Foundation of Northwestern Polytechnical University (No. CX201229).
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Zhang, LJ., Guo, XP. Mechanical alloying behavior of Nb–Ti–Si-based alloy made from elemental powders by ball milling process. Rare Met. 36, 174–182 (2017). https://doi.org/10.1007/s12598-017-0881-1
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DOI: https://doi.org/10.1007/s12598-017-0881-1