Skip to main content
Log in

Microemulsion-Based Vegetable Oil Detergency Using an Extended Surfactant

  • Original Article
  • Published:
Journal of Surfactants and Detergents

Abstract

This work examined the use of a single extended surfactant in the microemulsion-based detergency of vegetable oils. The results showed that good canola oil detergency (>80%) was achieved at 25 °C using a single extended surfactant (C14,15–8PO–SO4Na) at concentrations as low as 125 ppm, i.e., significantly lower than the surfactant concentration range of 500–2,500 ppm reported in other microemulsion-based detergency work. It was found that the maximum detergency (95%) was achieved in the type II microemulsion region. These results demonstrate that the microemulsion-based extended surfactant formulation is a promising approach for vegetable oil detergency at low temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Hillyer HW (1903) A study of soap solutions. J Am Chem Soc 25:511–532

    Article  CAS  Google Scholar 

  2. Adam NK, Stevenson DG (1953) Detergent action. Endeavour 12:25–32

    CAS  Google Scholar 

  3. Rosen MJ (2004) Surfactants and interfacial phenomena, 3rd edn. Wiley, New York

    Google Scholar 

  4. Showell MS (2006) Handbook of detergents part D: formulation. Taylor & Francis, Boca Raton

    Google Scholar 

  5. Miller C (2006) Detergency for engineering applications of surfactant solutions. In: Somasundaran P, Hubbard AT (eds) Encyclopedia of surface and colloid science. Taylor & Francis, Boca Raton, pp 1664–1669

  6. Solans C, Dominguez JG, Friberg SE (1985) Evaluation of textile detergency of microemulsions in systems of water nonionic surfactant and hydrocarbon at low temperature. J Dispers Sci Technol 6:523–537

    Article  CAS  Google Scholar 

  7. Raney KH, Benton WJ, Miller CA (1987) Optimum detergency conditions with nonionic surfactants: I ternary water surfactant-hydrocarbon systems. J Colloid Interface Sci 117:282–290

    Article  CAS  Google Scholar 

  8. Mori F, Lim JC, Raney OG, Elsik CM, Miller CA (1989) Phase behavior, dynamic contacting and detergency in systems containing triolein and nonionic surfactants. Colloids Surfaces 40:323–345

    Article  CAS  Google Scholar 

  9. Thompson L (1994) The role of oil detachment mechanism in determining optimum detergency conditions. J Colloid Interface Sci 163:61–73

    Article  CAS  Google Scholar 

  10. Tongcumpou C, Acosta EJ, Quencer LB, Joseph AF, Scamehorn JF, Sabatini DA, Chavadej S, Yanumet N (2003) Microemulsion formation and detergency of oily soils: I phase behavior and interfacial tension. J Surfactant Deterg 6:191–203

    Article  CAS  Google Scholar 

  11. Tongcumpou C, Acosta EJ, Quencer LB, Joseph AF, Scamehorn JF, Sabatini DA, Chavadej S, Yanumet N (2003) Microemulsion formation and detergency of oily soils: II detergency formation and performance. J Surfactant Deterg 6:205–213

    Article  CAS  Google Scholar 

  12. Tongcumpou C, Acosta EJ, Quencer LB, Joseph AF, Scamehorn JF, Sabatini DA, Chavadej S, Yanumet N (2005) Microemulsion formation and detergency of oily soils: III performance and mechanisms. J Surfactant Deterg 8:147–156

    Article  CAS  Google Scholar 

  13. Tongcumpou C, Acosta E, Scamehorn JF, Sabatini DA, Yanumet N, Chavadej S (2006) Enhanced triolein removal using microemulsions formulated with mixed surfactants. J Surfactant Deterg 9:181–189

    Article  CAS  Google Scholar 

  14. Tanthakit P, Chavadej S, Scamehorn JF, Sabatini DA, Tongcumpou C (2008) Microemulsion formation and detergency with oily soil: IV. Effect of rinse cycle design. J Surfactant Deterg 11:117–128

    Article  CAS  Google Scholar 

  15. Alander J, Warnheim T (1989) Model microemulsions containing vegetable oils part 1: nonionic surfactant systems. J Am Oil Chem Soc 66:1656–1660

    Article  CAS  Google Scholar 

  16. Alander J, Warnheim T (1989) Model microemulsions containing vegetable oils 2. Ionic surfactant systems. J Am Oil Chem Soc 66:1661–1665

    Article  CAS  Google Scholar 

  17. Miñana-Pérez M, Graciaa A, Lachaise J, Salager JL (1995) Solubilization of polar oils with extended surfactants. Colloids Surf A 100:217–224

    Article  Google Scholar 

  18. von Corswant C, Soderman O (1997) Microemulsions based on soybean phosphatidylcholine and triglycerides. Phase behavior and microstructure. Langmuir 13:5061–5070

    Article  Google Scholar 

  19. Huang L, Lips A, Co CC (2004) Microemulsification of triglyceride sebum and the role of interfacial structure on bicontinuous phase behavior. Langmuir 20:3559–3563

    Article  CAS  Google Scholar 

  20. Engelskirchen S, Elsner N, Sottmann T, Strey R (2007) Triacylglycerol microemulsions stabilized by alkyl ethoxylate surfactants—a basic study. Phase behavior, interfacial tension and microstructure. J Colloid Interface Sci 312:114–121

    Article  CAS  Google Scholar 

  21. Garrett PR, Carr D, Giles D, Pierre-Louis G, Staples E, Miller CA, Chen BH (2008) Solubilisation of triolein by microemulsions containing C12E4/hexadecane/water: equilibrium and dynamics. J Colloid Interface Sci 325:508–515

    Article  CAS  Google Scholar 

  22. Salager JL, Anton RE, Sabatini DA, Harwell JH, Acosta EJ, Tolosa LI (2005) Enhancing solubilization in microemulsions—state of the art and current trends. J Surfactant Deterg 8:3–21

    Article  CAS  Google Scholar 

  23. Witthayapanyanon A, Acosta EJ, Harwell JH, Sabatini DA (2006) Formulation of ultralow interfacial tension systems using extended surfactants. J Surfactant Deterg 9:331–339

    Article  CAS  Google Scholar 

  24. Do LD, Witthayapanyanon A, Harwell JH, Sabatini DA (2009) Environmentally friendly vegetable oil microemulsions using extended-surfactants and linkers. J Surfactant Deterg 12:91–99

    Article  CAS  Google Scholar 

  25. Smith GA, Hand KR (2008) Enhanced solubilization using extended chain surfactants. US Patent 7,467,633

  26. Aoudia M, Wade WH, Weerasooriya V (1995) Optimum microemulsions formulated with propoxylated Guerbet alcohol and propoxylated tridecyl alcohol sodium sulfates. J Dispers Sci Technol 16:115–135

    Article  CAS  Google Scholar 

  27. Phan TT (2009) Formation, characterization and application of triglyceride microemulsions using extended surfactants. PhD Dissertation, University of Oklahoma

  28. Witthayapanyanon A, Phan TT, Heitmann TC, Harwel JH, Sabatini DA (2010) Interfacial properties of extended-surfactant-based microemulsions and related macroemulsions. J Surfactant Deterg. doi:10.1007/s11743-009-1151-5

  29. Phan TT, Harwel JH, Sabatini DA (2010) Effects of triglyceride molecular structure on optimum formulation of surfactant-oil-water systems. J Surfactants Deterg. doi:10.1007/s11743-009-1155-1

  30. Velásquez J, Scorzza C, Vejar F, Forgiarini AM, Antón RE, Salager JL (2010) Effect of temperature and other variables on the optimum formulation of anionic extended surfactant-alkane-brine systems. J Surfactant Deterg 13:69–73

    Article  Google Scholar 

  31. Charoensaeng A, Sabatini DA, Khaodhiar S (2008) Styrene solubilization and adsolubilization on an aluminum oxide surface using linker molecules and extended surfactants. J Surfactant Deterg 11:61–71

    Article  CAS  Google Scholar 

  32. Charoensaeng A, Sabatini DA, Khaodhiar S (2009) Solubilization and adsolubilization of polar and nonpolar organic solutes by linker molecules and extended surfactants. J Surfactants Deterg 12:209–217

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to thank Geoff Russell and Victoria Stolarski, Sasol North America (Lake Charles, LA) for providing the extended surfactant samples. Funding for this work was provided by industrial sponsors of the Institute of Applied Surfactant Research at the University of Oklahoma: Akzo Nobel, Clorox, Conoco-Philips, Church and Dwight, Dow Chemical, Ecolab, Halliburton, Huntsman, Oxiteno, Procter & Gamble, Sasol North America, S.C. Johnson & Son, Shell Chemical; and by the Sun Oil Company Endowed Chair (David A. Sabatini).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to David A. Sabatini.

About this article

Cite this article

Phan, T.T., Witthayapanyanon, A., Harwell, J.H. et al. Microemulsion-Based Vegetable Oil Detergency Using an Extended Surfactant. J Surfact Deterg 13, 313–319 (2010). https://doi.org/10.1007/s11743-010-1184-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11743-010-1184-9

Keywords

Navigation