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Investigation of morphology and dielectric properties of PVDF composite films reinforced with MWCNT@PDA core–shell nanorods

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Abstract

This paper chooses to use polyvinylidene fluoride (PVDF) as the matrix, multiwalled carbon nanotubes (MWCNT) modified by polydopamine (PDA) as fillers, to prepare the MWCNT@PDA/PVDF composite films with excellent energy storage characteristics. The films were prepared by solution tape casting MWCNT@PDA/PVDF and MWCNT/PVDF composite films. The microstructures and properties of the composite films, especially the dielectric property, were investigated and the effect of MWCNT@PDA was analyzed. Results indicated that with the increase of filler content, the dispersion effect of filler in matrix becomes worse, and the energy storage modulus and dielectric constant increase gradually. When the content of MWCNT@PDA is 2.0 wt%, the dielectric constant of the MWCNT@PDA/PVDF composite film reaches 10.5 at 100 Hz, and the dielectric loss is 0.023. The addition of MWCNT@PDA is beneficial to increase the energy storage density of the composite membrane. When the content of MWCNT@PDA is 1.5 wt%, the energy storage density is 0.62 J/cm3, which is 2.7 times that of the pure membrane.

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References

  1. X.H. Hao, J. Adv. Dielectr. 3, 1330001 (2013)

    Article  Google Scholar 

  2. T. Kousksou, P. Bruel, A. Jamil, T. El Rhafiki, Y. Zeraouli, Sol. Energy Mater. Sol. Cells 120, 59–80 (2014)

    Article  CAS  Google Scholar 

  3. B.J. Chu, X.Z. Zhou, K.L. Ren, B. Neese, M.R. Lin, Q. Wang, F. Bauer, Q.M. Zhang, Science 313, 334–336 (2006)

    Article  CAS  Google Scholar 

  4. P.W. Zhu, L. Weng, X.R. Zhang, X.M. Wang, L.Z. Guan, L.Z. Liu, J. Mater. Sci. 55, 7665–7679 (2020)

    Article  CAS  Google Scholar 

  5. A. Azizi, M.R. Gadinski, Q. Li, M.A. AlSaud, J. Wang, Y. Wang, B. Wang, F.H. Liu, L.Q. Chen, N. Alem, Q. Wang, Adv Mater 29, 1701864 (2017)

    Article  Google Scholar 

  6. Y. Yang, H.L. Sun, D. Yin, Z.H. Lu, J.H. Wei, R. Xiong, J. Shi, Z.Y. Wang, Z.Y. Liu, Q.Q. Lei, Journal of Materials Chemistry A 3, 4916–4921 (2015)

    Article  CAS  Google Scholar 

  7. Q. Wang, L. Zhu, J. Polym. Sci., Part B: Polym. Phys. 49, 1421–1429 (2011)

    Article  CAS  Google Scholar 

  8. Z. Wang, T. Wang, M.R. Fang, C. Wang, Y.J. Xiao, Y.P. Pu, Compos. Sci. Technol. 146, 139–146 (2017)

    Article  CAS  Google Scholar 

  9. K.C. Li, H. Wang, F. Xiang, W.H. Liu, H.B. Yang, Appl. Phys. Lett. 95, 202904 (2009)

    Article  Google Scholar 

  10. J.J. Li, J. Claude, L.E. Norena-Franco, S.I. Seok, Q. Wang, Chem. Mater. 20, 6304–6306 (2008)

    Article  CAS  Google Scholar 

  11. W.M. Xia, Z. Xu, F. Wen, Z.C. Zhang, Ceram. Int. 38, 1071–1075 (2012)

    Article  CAS  Google Scholar 

  12. X.L. Dou, X.L. Liu, Y. Zhang, H. Feng, J.F. Chen, S. Du, Appl. Phys. Lett. 95, 132904 (2009)

    Article  Google Scholar 

  13. E.Q. Huang, J. Zhao, J.W. Zha, L. Zhang, R.J. Liao, Z.M. Dang, J. Appl. Phys. 115, 194102 (2014)

    Article  Google Scholar 

  14. H.W. Lu, L.Z. Liu, J.Q. Lin, W.L. Yang, L. Weng, X.R. Zhang, G.R. Chen, W. Huang, J. Appl. Polym. Sci. 134, 45362 (2017)

    Article  Google Scholar 

  15. S.H. Wang, Y. Wan, B. Sun, L.Z. Liu, W.J. Xu, Nanoscale Res Lett 9, 522 (2014)

    Article  Google Scholar 

  16. B. Zhao, M. Hamidinejad, C.X. Zhao, R.S. Li, S. Wang, Y. Kazemi, C.B. Park, J. Mater. Chem. A 7, 133–140 (2019)

    Article  CAS  Google Scholar 

  17. X.M. He, Y.M. Chen, K. Zhu, S.X. Wang, H.W. Zhang, W. He, F. Xia, X.F. Jin, Y.S. Hu, X.H. Su, Polym. Compos. 39, E1920–E1927 (2018)

    Article  CAS  Google Scholar 

  18. A. Eshraghian, M. Kamkar, M. Asgari, M. Arjmand, U. Sundararaj, Polym. Compos. 42, 1034–1048 (2021)

    Article  CAS  Google Scholar 

  19. W. Chueangchayaphan, P. Luangchuang, N. Chueangchayaphan, M.A. Sulaiman, Y. Nakaramontri, Chin. J. Polym. Sci. 39, 725–735 (2021)

    Article  CAS  Google Scholar 

  20. P. Wang, L. Yang, S. Gao, X.L. Chen, T. Cao, C. Wang, H. Liu, X.H. Hu, X.S. Wu, S.J. Feng, Advanced Composites and Hybrid Materials 4, 639–646 (2021)

    Article  CAS  Google Scholar 

  21. J.Y. Liang, Y.Z. Gu, Z.C. Zhang, S.K. Wang, M. Li, Z.G. Zhang, Nanotechnology 29, 035701 (2017)

    Article  Google Scholar 

  22. K. Silakaew, P. Thongbai, RSC Adv. 9, 23498–23507 (2019)

    Article  CAS  Google Scholar 

  23. Q.H. Deng, B.H. Chen, M.L. Bo, Y.F. Feng, Y.H. Huang, J.Q. Zhou, Journal of Materials Chemistry C 9, 1051–1061 (2021)

    Article  CAS  Google Scholar 

  24. X.Y. Huang, P.K. Jiang, Adv Mater 27, 546–554 (2015)

    Article  CAS  Google Scholar 

  25. J.M. Zhu, X.Y. Ji, M. Yin, S.Y. Guo, J.B. Shen, Compos. Sci. Technol. 144, 79–88 (2017)

    Article  CAS  Google Scholar 

  26. X.W. Cao, W.J. Zhao, X.J. Gong, D.L. Zhang, Q.J. Su, J.W. Zha, X.M. Yin, W. Wu, R.K.Y. Li, Compos. A Appl. Sci. Manuf. 148, 106486 (2021)

    Article  CAS  Google Scholar 

  27. M.J. Feng, C.H. Zhang, G.T. Zhou, T.D. Zhang, Y. Feng, Q.G. Chi, Q.Q. Lei, IEEE Access 8, 81542–81550 (2020)

    Article  Google Scholar 

  28. L.Z. Guan, L. Weng, X.R. Zhang, Z.J. Wu, Q. Li, L.Z. Liu, J. Mater. Sci. 55, 15238–15251 (2020)

    Article  CAS  Google Scholar 

  29. Y. Xuan, G.C. Jiang, Y.Y. Li, J.S. Wang, H.N. Geng, Colloids Surf., A 422, 50–60 (2013)

    Article  CAS  Google Scholar 

  30. L.Z. Guan, L. Weng, Q. Li, X.R. Zhang, Z.J. Wu, Y.Y. Ma, Mater. Des. 197, 109241 (2021)

    Article  CAS  Google Scholar 

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Acknowledgements

The authors are thankful for the financial supports from the National Natural Science Foundation of China (51677045, 51177030), the Natural Science Foundation of Heilongjiang Province (E201224), and Harbin Science and Technology Innovation Talent program (2016RAQXJ059).

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Authors and Affiliations

  1. School of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin, 150040, China

    Yating Yu, Hang Xu, Xiaoming Wang, Lizhu Guan, Xiaorui Zhang, Zijian Wu & Ling Weng

  2. Key Laboratory of Engineering Dielectric and Its Application, Harbin University of Science and Technology, Ministry of Education, Harbin, 150080, China

    Xiaorui Zhang, Zijian Wu & Ling Weng

Authors
  1. Yating Yu
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  2. Hang Xu
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  3. Xiaoming Wang
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  4. Lizhu Guan
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  5. Xiaorui Zhang
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  6. Zijian Wu
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  7. Ling Weng
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Contributions

YY and HX of this article contributed the same. YY performed experimental design and writing-review and editing. HX involved in analysis of experimental data. XW participated in data curation. LG and ZW involved in investigation. XZ provided the experimental analysis suggestion. LW performed resources and supervision.

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Correspondence to Ling Weng.

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The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Yu, Y., Xu, H., Wang, X. et al. Investigation of morphology and dielectric properties of PVDF composite films reinforced with MWCNT@PDA core–shell nanorods. J Mater Sci: Mater Electron 33, 6842–6855 (2022). https://doi.org/10.1007/s10854-022-07862-1

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  • DOI: https://doi.org/10.1007/s10854-022-07862-1

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