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Improving water resistance and mechanical properties of waterborne acrylic resin modified by octafluoropentyl methacrylate

  • Polymers & biopolymers
  • Published:
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Abstract

A new type of waterborne acrylic resin was prepared by the solution polymerization with octafluoroamyl methacrylate (OF-PMA), 2-butoxy ethanol, and acrylic monomers as raw materials and N, N-dimethyl ethanolamine as pH regulator. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy showed that the OF-PMA monomers were successfully grafted onto the resin. The effects of the addition mode and content of OF-PMA on the properties of waterborne acrylic resin were studied. The properties of waterborne acrylic polymer and its coating were tested by a thermogravimetric analyzer, an optical contact angle measuring instrument, and a tensile testing machine. The results showed that after the introduction of OF-PMA monomer into acrylic resin, the tensile strength of the resin was increased by 14.31 MPa. Moreover, the water resistance and heat resistance of resin coating were also improved obviously and the as-modified resin coating exhibited better fullness, adhesion of Gt0, and the hardness of 4H. The novel acrylic resin exhibits a potential application prospect in the fields of waterborne wood coatings.

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Acknowledgements

This work was supported by the Natural Science Foundation of Shandong Province (No. ZR2019BEE075), Scientific Research Foundation of SDUST for Recruited Talents (No. 2019RCJJ007), and Elite Program of SDUST (No. skr21-3-051). The authors acknowledge the financial support of Taif University Researchers Supporting Project number (TURSP-2020/14), Taif University, Taif, Saudi Arabia.

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Authors and Affiliations

  1. College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Jialin Bi, Zhangyin Yan, Fuhao Zhang, Qian Shao & Junxiang Wang

  2. Dalian University of Technology, Dalian, 116023, China

    Lei Hao

  3. Department of Food Science and Nutrition, College of Science, Taif University, P. O. Box 11099, 21944, Taif, Saudi Arabia

    Ashraf Y. Elnaggar & Islam H. El Azab

  4. Department of Chemistry, Turabah University College, Taif University, P.O.Box 11099, 21944, Taif, Saudi Arabia

    Salah M. El-Bahy

  5. Department of Chemistry, College of Science, Taif University, P.O. Box 11099, 21944, Taif, Saudi Arabia

    Gaber A. M. Mersal

  6. College of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan, 030024, China

    Salah M. El-Bahy & Mina Huang

  7. Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN, 37996, USA

    Mina Huang & Zhanhu Guo

  8. Integrated Composites Laboratory (ICL), Department of Mechanical and Construction Engineering, Northumbria University, Newcastle Upon Tyne, NE1 8ST, UK

    Zhangyin Yan & Zhanhu Guo

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  1. Jialin Bi
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  2. Zhangyin Yan
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Correspondence to Qian Shao, Junxiang Wang or Zhanhu Guo.

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Bi, J., Yan, Z., Hao, L. et al. Improving water resistance and mechanical properties of waterborne acrylic resin modified by octafluoropentyl methacrylate. J Mater Sci 58, 1452–1464 (2023). https://doi.org/10.1007/s10853-022-07956-5

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