Skip to main content
Log in

Fabrication of Step-and-Flash Imprint Lithography (S-FIL) templates using XeF2 enhanced focused ion-beam etching

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The fabrication of Step-and-Flash Imprint Lithography (S-FIL) templates with line widths of 50 nm is described in this work. The structures have been patterned using a Ga+ focused ion beam (FIB) in a quartz template. FIB milling is generally accompanied with re-deposition effects, which represent a hindrance to densely patterned nanostructures required in most NIL applications. To reduce these re-deposition effects, in this research, xenon difluoride (XeF2) enhanced FIB etching was applied that also increases the material removal rates in comparison to pure kinetic ion sputtering. To optimise the process when using XeF2 gas the following ion scanning parameters have been examined: ion dose, beam current, dwell time and beam overlap (step size). It has been found that the assisting gases at very low doses do not bring significant etching enhancements whilst the sputtering rates have increased at high doses. Using the XeF2 gas-assisted etching, FIB structuring has been used to fabricate <100 nm structures onto quartz S-FIL templates. The presence of XeF2 considerably enhances the etching rate of quartz without any significant negative effects on the spatial resolution of the FIB lithographic process and reduces the template processing time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S.Y. Chou, P.R. Krauss, P.J. Renstrom, Imprint of sub-25 nm vias and trenches in polymers. Appl. Phys. Lett. 67, 3114 (1995)

    Article  ADS  Google Scholar 

  2. T. Bailey, B.J. Choi, M. Colburn, M. Meissl, S. Shaya, J.G. Ekerdt, S.V. Sreenivasan, C.G. Willson, Step and flash imprint lithography: template surface treatment and defect analysis. J. Vac. Sci. Technol. B 18, 3572 (2000)

    Article  Google Scholar 

  3. T.C. Bailey, S.C. Johnson, S.V. Sreenivasan, J.G. Ekerdt, C.G. Willson, D.J. Resnick, Step and Flash Imprint Lithography: an efficient nanoscale printing technology. J. Photopolym. Sci. Technol. 15(3), 481–486 (2002)

    Article  Google Scholar 

  4. M.D. Austin, W. Zhang, H. Ge, D. Wasserman, S.A. Lyon, S.Y. Chou, 6 nm half-pitch lines and 0.04 μm2 static random access memory patterns by nanoimprint lithography. Nanotechnology 16, 1058–1061 (2005)

    Article  ADS  Google Scholar 

  5. B. Wu, A. Kumar, Extreme ultraviolet lithography: a review. J. Vac. Sci. Technol. B 25, 1743 (2007)

    Article  Google Scholar 

  6. L.J. Guo, Recent progress in nanoimprint technology and its applications. J. Phys. D: Appl. Phys. 37, R123–R141 (2004)

    Article  ADS  Google Scholar 

  7. D.J. Resnick, W.J. Dauksher, D. Mancini, K.J. Nordquist, E. Ainley, K. Gehoski, J.H. Baker, T.C. Bailey, B.J. Choi, S. Johnson, S.V. Sreenivasan, J.G. Ekerdt, C.G. Willson, High resolution templates for step and flash imprint lithography. J. Microlithogr. Microfab., Microsyst. 1, 284 (2002)

    Article  Google Scholar 

  8. J. Kettle, R.T. Hoyle, R.M. Perks, S. Dimov, Overcoming material challenges for replication of “motheye lenses” using step and flash imprint lithography for optoelectronic applications. J. Vac. Sci. Technol. B 26, 1794 (2008)

    Article  Google Scholar 

  9. A. Lugstein, B. Basnar, J. Smoliner, E. Bertagnolli, FIB processing of silicon in the nanoscale regime. Appl. Phys. A: Mater. Sci. Process. 76, 545–548 (2003)

    Article  ADS  Google Scholar 

  10. M.-K. Lee, K.-K. Kuo, Gas-assisted focused ion beam etching of indium–tin oxide film. Jpn. J. Appl. Phys. 47, 347–350 (2008)

    Article  ADS  Google Scholar 

  11. L.R. Harriott, Focused-ion-beam-induced gas etching. Jpn. J. Appl. Phys. 33, 7094 (1994)

    Article  ADS  Google Scholar 

  12. I. Chyr, A.J. Steckl, GaN focused ion beam micromachining with gas-assisted etching. J. Vac. Sci. Technol. B 19(6), 2457–2460 (2001)

    Article  Google Scholar 

  13. T. Dai, X. Kang, B. Zhang, J. Xu, K. Bao, C. Xiong, Z. Gan, Study and formation of 2D microstrcutures of sapphire by FIB milling. Microelectron. Eng. 85, 640–645 (2008)

    Article  Google Scholar 

  14. J. Kettle, R.T. Hoyle, S. Dimov, R.M. Perks, Fabrication of complex 3D structures using Step-and-Flash Imprint Lithography (S-FIL). Microelectron. Eng. 85(5–6), 853–855 (2007) 2008

    Google Scholar 

  15. W. Li, S. Dimov, G. Lalev, Focused-ion-beam direct structuring of fused silica for fabrication of nano-imprinting templates. Microelectron. Eng. 84(5–8), 829–832 (2007)

    Article  Google Scholar 

  16. H. Nakamura, H. Komano, M. Ogasawara, Focused ion beam assisted etching of quartz in XeF2 without transmittance reduction for phase shifting mask repair. Jpn. J. Appl. Phys. 31, 4465 (1992)

    Article  ADS  Google Scholar 

  17. A. Rota, S.F. Contri, G.C. Gazzadi, S. Cottafava, E. Gualtieri, S. Valeri, Focused ion beam induced swelling in MgO(0 0 1). Surf. Sci. 600(18), 3718–3722 (2006)

    Article  ADS  Google Scholar 

  18. Y.Q. Fu, N.K.A. Bryan, O.N. Shing, Investigation of submicron linewidth direct deposition for high-density IC chip modification by focused ion beam. Int. J. Adv. Manuf. Technol. 17(11), 835–839 (2001)

    Article  Google Scholar 

  19. M.-K. Lee, K.-K. Kuo, Gas-Assisted Etching of sapphire using Focused Ion Beam. Jpn. J. Appl. Phys. 45(4A), 2447–2450 (2006)

    Article  ADS  Google Scholar 

  20. D.J. Resnick, S.V. Sreenivasan, C. Grant Willson, Step and flash imprint lithography. Mater. Today 8(2), 34–42 (2005)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. Kettle.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kettle, J., Hoyle, R.T. & Dimov, S. Fabrication of Step-and-Flash Imprint Lithography (S-FIL) templates using XeF2 enhanced focused ion-beam etching. Appl. Phys. A 96, 819–825 (2009). https://doi.org/10.1007/s00339-009-5319-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-009-5319-7

PACS

Navigation