Abstract
Sustainable recovery of laminar LiCoO2 materials from spent mobile phone batteries by high-temperature calcination was studied. Graphite powders were removed from the anode when the copper thin foil was attacked. Spent LiCoO2 and aluminum thin foil on the cathode were separated by pulverization and sieving. Spent cathodic materials were calcined at 900 °C to remove impurities and recover the laminar structure of LiCoO2. The structure and morphology of the recovered active materials were studied by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray. The laminar structure of the recovered LiCoO2 was found to be a favorable feature for the Li+ intercalation/deintercalation. Electrochemical properties of the recovered LiCoO2 electrode during the galvanostatic charge/discharge processes were tested by cyclic voltammetry. The recovered LiCoO2 electrode shows a reversibility and a specific capacitance of 14.0 F/g (at 50 mV/s) indicating that it exhibits favorable properties for use as pseudocapacitor. It is found comparatively that the present process is a more environment-friendly and a lower-cost recycling method, and hence more feasible for industrial applications than the other reported processes.
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References
Badawy SM, Nayl AA, El Khashab RA, El-Khateeb MA (2014) Cobalt separation from waste mobile phone batteries using selective precipitation and chelating resin. J Mater Cycles Waste Manag 16:739–746
Jha MK, Kumari A, Jha AK, Kumar V et al (2013) Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone. Waste Manage 33:1890–1897
Li J, Shi P, Wang Z, Chen Y, Chang C (2009) A combined recovery process of metals in spent lithium-ion batteries. Chemosphere 77:1132–1136
Zhang T, He Y, Wang F, Ge L et al (2014) Chemical and process mineralogical characterizations of spent lithium-ion batteries: an approach by multi-analytical techniques. Waste Manage 34:1051–1058
Zhou X, He W, Li G, Zhang X (2010) Recycling of electrode materials from spent lithium-ion batteries. In: 4th international conference on bioinformatics and biomedical engineering (iCBBE), 18–20 June 2010, pp 1–4
Bankole OE, Gong C, Lei L (2013) Battery recycling technologies: recycling waste lithium ion batteries with the impact on the environment in-view. J Environ Ecol 4(1):14–28
Shu-guang Z, Wen-zhi H, Guang-ming L et al (2012) Recovery of Co and Li from spent lithium-ion batteries by combination method of acid leaching and chemical precipitation. Trans Nonferrous Met Soc China 22:2274–2281
Lu M, Zhang H, Wang B, Zheng X, Dai C (2013) The Re-synthesis of LiCoO2 from spent lithium ion batteries separated by vacuum-assisted heat-treating method. Int J Electrochem Sci 8:8201–8209
Li J, Zhao R, He X, Liu H (2009) Preparation of LiCoO2 cathode materials from spent lithium–ion batteries. Ionics 15:111–113
Zhang Z, He W, Li G et al (2014) Recovery of lithium cobalt oxide material from the cathode of spent lithium-ion batteries. ECS Electrochem Lett 3(6):A58–A61
Badawy SM (2016) Synthesis of high-quality graphene oxide from spent mobile phone batteries. Environ Progress Sustain Energy 35(5):1485–1491
Shaw S (2012) Increasing demand for high purity natural graphite in new applications. In: Natural & synthetic graphite: global industry markets & outlook, 8th edn.
Zhang X, Xie Y, Lin X, Li H, Cao H (2013) An overview on the processes and technologies for recycling cathodic active materials from spent lithium-ion batteries. J Mater Cycles Waste Manag 15:420–430
Meshram P, Abhilash Pandey BD, Mankhand TR, Deveci H (2016) Acid baking of spent lithium ion batteries for selective recovery of major metals: a two-step process. J Ind Eng Chem 43:117–126
Paulino JF, Busnardo NG, Afonso JC (2008) Recovery of valuable elements from spent Li-batteries. J Hazard Mater 150:843–849
Chen X, Guo C, Ma H, Li J et al (2018) Organic reductants based leaching: a sustainable process for the recovery of valuable metals from spent lithium ion batteries. Waste Manage 75:459–468
Wang D, Zhang X, Chen H, Sun J (2018) Separation of Li and Co from the active mass of spent Li-ion batteries by selective sulfating roasting with sodium bisulfate and water leaching. Miner Eng 126:28–35
Chen X, Cao L, Kang D et al (2019) Recovery of valuable metals from mixed types of spent lithium ion batteries. Part II: selective extraction of lithium. Waste Manage 80:198–210
Nie H, Xu L, Song D et al (2015) LiCoO2: recycling from spent batteries and regeneration with solid state synthesis. Green Chem 17:1276–1280
Zhang Z, He W, Li G et al (2014) Ultrasound-assisted hydrothermal renovation of LiCoO2 from the cathode of spent lithium-ion batteries. Int J Electrochem Sci 9:3691–3700
Lu M, Zhang H, Wang B et al (2013) The Re-synthesis of LiCoO2 from spent lithium ion batteries separated by vacuum-assisted heat-treating method. Int J Electrochem Sci 8:8201–8209
Chen X, Luo C, Zhang J et al (2015) Sustainable recovery of metals from spent lithium-ion batteries: a green process. ACS Sustain Chem Eng 3(12):3104–3113
Jinhui L, Shengwen Z, Daoling X, Hao C (2009) Synthesis and electrochemical performances of LiCoO2 recycled from the incisors bound of Li-ion batteries. Rare Met 28(4):328–332
Chen X, Kang D, Cao L et al (2019) Separation and recovery of valuable metals from spent lithium ion batteries: simultaneous recovery of Li and Co in a single step. Sep Purif Technol 210:690–697
Zhou X, He W, Li G et al (2010) Recycling of electrode materials from spent lithium-ion batteries. In: 4th international conference on bioinformatics and biomedical engineering (iCBBE), pp 18–20
Vasilchina H, Aleksandrova A, Momchilov A et al (2005) Proceedings of the international workshop “portable and emergency energy sources—from materials to systems” pp 16–22, Primorsko, Bulgaria
Kwon NH (2013) The effect of carbon morphology on the LiCoO2 cathode of lithium ion batteries. Solid State Sci 2:59–65
Li L, RenJie C, XiaoXiao Z et al (2012) Preparation and electrochemical properties of re-synthesized LiCoO2 from spent lithium-ion batteries. Chin Sci Bull 57(32):4188–4194
Zhang Z, He W, Li G et al (2015) Renovation of LiCoO2 crystal structure from spent lithium ion batteries by ultrasonic hydrothermal reaction. Res Chem Intermed 41:3367–3373
Song D, Wang X, Nie H et al (2014) Heat treatment of LiCoO2 recovered from cathode scraps with solvent method. J Power Sources 249:137–141
Cao J, Hu G, Peng Z et al (2015) Polypyrrole-coated LiCoO2 nanocomposite with enhanced electrochemical properties at high voltage for lithium-ion batteries. J Power Sources 281:49–55
Kellerman DG, Karelina VV, Vadim S et al (2002) Investigation of thermal stability of LiCoO2 and Li1-xCoO2. Chem Sustain Dev 10:721–726
Antolini E, Ferretti M (1995) Synthesis and thermal stability of LiCoO2. J Solid State Chem 117:1–7
Habibi A, Jalaly M, Rahmanifard R, Ghorbanzadeh M et al (2018) The effect of calcination conditions on the crystal growth and battery performance of nanocrystalline Li(Ni1/3Co1/3Mn1/3)O2 as a cathode material for Li-ion batteries. New J Chem 42:19026–19033
Kong J, Zhou F, Wang C et al (2013) Effects of Li source and calcination temperature on the electrochemical properties of LiNi0.5Co0.2Mn0.3O2 lithium-ion cathode materials. J Alloy Compd 554:221–226
Zeng X, Li J, Singh N (2014) Recycling of spent lithium-ion battery: a critical review. Crit Rev Environ Sci Technol 44:1129–1165
Xu Y, Dong Y, Han X et al (2015) Application for simply recovered LiCoO2 material: as a high performance candidate for supercapacitor in aqueous system. ACS Sustain Chem Eng 3(10):2435–2442
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Badawy, S.M., Nayl, A.E.A. Recovery of Laminar LiCoO2 Materials from Spent Mobile Phone Batteries by High-Temperature Calcination. J. Sustain. Metall. 5, 474–481 (2019). https://doi.org/10.1007/s40831-019-00238-6
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DOI: https://doi.org/10.1007/s40831-019-00238-6