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An overview on the processes and technologies for recycling cathodic active materials from spent lithium-ion batteries

  • SPECIAL FEATURE: REVIEW
  • The 7th International Conference on Waste Management and Technology (ICWMT) 2012
  • Published:
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Abstract

This paper aims to make an overview on the current status and new tendency for recycling cathodic active materials from spent lithium-ion batteries. Firstly, it introduces several kinds of pretreatment technologies, followed by the summary of all kinds of single recycling processes mainly focusing on organic acid leaching and synergistic extraction. Then, several examples of typical combined processes and industrial recycling processes are presented in detail. Meanwhile, the advantages, disadvantages and prospect of each single process, combined process, as well as industrial recycling processes, are discussed. Finally, based on a novel acidic organic solvent, the authors briefly introduce an environmental friendly process to directly recycle and resynthesize cathodic active material LiNi1/3Co1/3Mn1/3O2 from spent lithium-ion batteries. The preliminary experimental results demonstrated the advantages of low reaction temperature, high separation efficiency and organic solvent cycling and preventing secondary pollution to the environment. This process may be used for large-scale recycling of spent lithium-ion batteries after further study.

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Acknowledgments

This study was supported by the Chinese Academy of Sciences (No. 2011YDHZ-JSC02), Guangdong Province (No. 2011A032302001) and the China Postdoctoral Science Foundation (No. 2012M510553).

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Authors and Affiliations

  1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Research Centre for Process Pollution Control and Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, No. 1 Zhongguancun North Second Street, Beijing, 100190, China

    Xihua Zhang, Yongbing Xie, Xiao Lin, Haitao Li & Hongbin Cao

  2. University of Chinese Academy of Sciences, Beijing, China

    Xihua Zhang

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  1. Xihua Zhang
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  2. Yongbing Xie
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  3. Xiao Lin
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  4. Haitao Li
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Correspondence to Hongbin Cao.

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Zhang, X., Xie, Y., Lin, X. et al. An overview on the processes and technologies for recycling cathodic active materials from spent lithium-ion batteries. J Mater Cycles Waste Manag 15, 420–430 (2013). https://doi.org/10.1007/s10163-013-0140-y

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  • DOI: https://doi.org/10.1007/s10163-013-0140-y

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