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Colloidal, morphological, thermal, rheological, and film properties of waterborne hyperbranched alkyd–acrylic resins

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Abstract

Waterborne hyperbranched alkyd–acrylic resins (HAAR) are interesting materials that provide excellent properties yet require only low levels of solvent in formulations using them. However, they have been scarcely studied. Therefore, the goal of this work was to prepare and evaluate various properties of HAAR. These materials were obtained by miniemulsion polymerization from a hyperbranched alkyd resin (HAR), methyl methacrylate (MMA), butyl acrylate (BA), and acrylic acid (AA). The proportions of HAR:acrylic monomers were as follow: 50:50 (HAAR1), 40:60 (HAAR2), 30:70 (HAAR3), and 20:80 (HAAR4). The particle size increased with the content of HAR, but the colloidal stability, critical deformation, zeta potential, thermal stability, and hardness followed an opposite behavior. The order of colloidal stability of the HAAR miniemulsions was HAAR4 > HAAR3 > HAAR2 > HAAR1. The particle morphology of the HAAR was mainly core–shell, but acrylic and alkyd particles were also observed. In addition, all HAAR initially exhibited a reduction in complex viscosity (η*) with the increase in angular frequency. The thermal stability of the HAR was lower than that of the HAAR. The HAAR showed better resistance against a 0.10 M sodium hydroxide (NaOH) solution than HAR.

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Acknowledgments

We thank the Francisco de Paula Santander University (UFPS)-Cúcuta and the internship program of the UFPS for the realization of this study.

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Authors and Affiliations

  1. Grupo de Investigación en Materiales Poliméricos (GIMAPOL), Departamento de Química, Universidad Francisco de Paula Santander, Avenida Gran Colombia No. 12E-96 Barrio Colsag, Cúcuta, Colombia

    Edwin A. Murillo

  2. Laboratorio de Polímeros, Centro de Química, Instituto de Ciencias-Benemérita Universidad Autónoma de Puebla, Complejo de Ciencias, ICUAP, Edif. 103H, 22 Sur y San Claudio, CP 72570, Puebla, Mexico

    Judith Percino

  3. Grupo de Investigación en Ciencia de los Materiales, University of Antioquia, Calle 67 No. 53-108, Medellín, Colombia

    Betty L. López

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  1. Edwin A. Murillo
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  3. Betty L. López
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Correspondence to Edwin A. Murillo.

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Murillo, E.A., Percino, J. & López, B.L. Colloidal, morphological, thermal, rheological, and film properties of waterborne hyperbranched alkyd–acrylic resins. J Coat Technol Res 16, 1223–1232 (2019). https://doi.org/10.1007/s11998-019-00205-6

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  • DOI: https://doi.org/10.1007/s11998-019-00205-6

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