Abstract
Recent developments and trends of sol-gel auto-combustion method for spinel ferrite nanomaterial synthesis are briefly discussed and critically analyzed. The analysis of various parameters of reaction which could be used for better understanding of synthesis process and control of microstructure and property of spinel ferrite nanopowder products was the main objective of this review article. Special attention was paid to variety of particle size and phase purity. For these purposes the correlation between complexant, oxygen balance and combustion process chemical additives, as well as heating mechanism and atmosphere, was established. These results are relevant from standpoints of both application and processing of ferrites.
Similar content being viewed by others
References
Chavan S M, Babrekar M K, More S S, et al. Structural and optical properties of nanocrystalline Ni-Zn ferrite thin films. Journal of Alloys and Compounds, 2010, 507(1): 21–25
Adam J D, Davis L E, Dionne G F, et al. Ferrite devices and materials. IEEE Transactions on Microwave Theory and Techniques, 2002, 50(3): 721–737
Kulikowski J. Soft magnetic ferrites — development or stagnation? Journal of Magnetism and Magnetic Materials, 1984, 41(1–3): 56–62
Harris V G, Geiler A, Chen Y, et al. Recent advances in processing and applications of microwave ferrites. Journal of Magnetism and Magnetic Materials, 2009, 321(14): 2035–2047
Qu Y, Yang H, Yang N, et al. The effect of reaction temperature on the particle size, structure and magnetic properties of coprecipitated CoFe2O4 nanoparticles. Materials Letters, 2006, 60(29–30): 3548–3552
Kasapoglu N, Birsoz B, Baykal A, et al. Synthesis and magnetic properties of octahedral ferrite NixCo1 − x Fe2O4 nanocrystals. Central European Journal of Chemistry, 2007, 5(2): 570–580
Cao S W, Zhu Y J, Cheng G F, et al. ZnFe2O4 nanoparticles: microwave-hydrothermal ionic liquid synthesis and photocatalytic property over phenol. Journal of Hazardous Materials, 2009, 171(1–3): 431–435
Liu Y-L, Liu Z-M, Yang Y, et al. Simple synthesis of MgFe2O4 nanoparticles as gas sensing materials. Sensors and Actuators B: Chemical, 2005, 107(2): 600–604
Ahmed T T, Rahman I Z, Rahman M A. Study on the properties of the copper substituted NiZn ferrites. Journal of Materials Processing Technology, 2004, 153–154: 797–803
Valenzuela R. Magnetic Ceramics. 1st ed. Melbourne: Cambridge University Press, 3–23
Mouallem-Bahout M, Bertrand S, Pena O. Synthesis and characterization of ZnxNi1 − x Fe2O4 spinels prepared by citrate precursor. Journal of Solid State Chemistry, 2005, 178(4): 1080–1086
Gul I H, Ahmed W, Maqsood A. Electrical and magnetic characterization of nanocrystalline Ni-Zn ferrite synthesis by coprecipitation route. Journal of Magnetism and Magnetic Materials, 2008, 320(3–4): 270–275
Zahi S, Hashim M, Daud A R. Synthesis, magnetic properties and microstructure of Ni-Zn ferrite by sol-gel technique. Journal of Magnetism and Magnetic Materials, 2007, 308(2): 177–182
Košak A, Makovec D, Žnidaršič A, et al. Preparation of MnZnferrite with microemulsion technique. Journal of the European Ceramic Society, 2004, 24(6): 959–962
Jiao X, Chen D, Hu Y. Hydrothermal synthesis of nanocrystalline Mx(Zn1 − x )Fe2O4 (M = Ni, Mn, Co; x = 0.40−0.60) powders. Materials Research Bulletin, 2002, 37(9): 1583–1588
Takayama A, Okuya M, Kaneko S. Spray pyrolysis deposition of NiZn ferrite thin films. Solid State Ionics, 2004, 172(1–4): 257–260
Thakur S, Katyal S C, Singh M. Structural and magnetic properties of nano nickel-zinc ferrite synthesized by reverse micelle technique. Journal of Magnetism and Magnetic Materials, 2009, 321(1): 1–7
Sarangi P P, Vadera S R, Patra M K, et al. Synthesis and characterization of pure single phase Ni-Zn ferrite nanopowders by oxalate based precursor method. Powder Technology, 2010, 203(2): 348–353
Balaji S, Kalai Selvan K, John Berchmans L, et al. Combustion synthesis and characterization of Sn4+ substituted nanocrystalline NiFe2O4. Materials Science and Engineering B, 2005, 119(2): 119–124
Aruna S T, Mukasyan A S. Combustion synthesis and nanomaterials. Current Opinion in Solid State and Materials Science, 2008, 12(3–4): 44–50
Randhawa B S, Dosanjh H S, Kumar N. Synthesis of lithium ferrite by precursor and combustion methods: A comparative study. Journal of Radioanalytical and Nuclear Chemistry, 2007, 274(3): 581–591
Lee S-P, Chen Y-J, Ho C-M, et al. A study on synthesis and characterization of the core-shell materials of Mn1 − x ZnxFe2O4-polyaniline. Materials Science and Engineering B, 2007, 143(1–3): 1–6
Sutka A, Mezinskis G, Pludons A, et al. Characterization of solgel auto-combustion derived spinel ferrite nano-materials. Power Engineering, 2010, 56(3–4): 254–259
Sutka A, Gross K A, Mezinskis G, et al. The effect of heating conditions on the properties of nano- and microstructured Ni-Zn ferrite. Physica Scripta, 2011, 83(2): 025601 (6 pages)
Thant A A, Srimala S, Kaung P, et al. Low temperature synthesis of MgFe2O4 soft ferrite nanocrystallites. Journal of the Australian Ceramic Society, 2010, 46(1): 11–14
Nayak P K. Synthesis and characterization of cadmium ferrite. Materials Chemistry and Physics, 2008, 112(1): 24–26
Shobana M K, Rajendran V, Jeyasubramanian K, et al. Preparation and characterisation of NiCo ferrite nanoparticles. Materials Letters, 2007, 61(13): 2616–2619
Mallapur M M, Shaikh P A, Kambale R C, et al. Structural and electrical properties of nanocrystalline cobalt substituted nickel zinc ferrite. Journal of Alloys and Compounds, 2009, 479(1–2): 797–802
Yue Z, Zhou J, Li L, et al. Effect of copper on the electromagnetic properties of Mg-Zn-Cu ferrites prepared by sol-gel autocombustion method. Materials Science and Engineering B, 2001, 86(1): 64–69
Azadmanjiri J, Salehani H K, Barati M R, et al. Preparation and electromagnetic properties of Ni1 − x CuxFe2O4 nanoparticle ferrites by sol-gel auto-combustion method. Materials Letters, 2007, 61(1): 84–87
Yue Z, Zhou J, Li L, et al. Synthesis of nanocrystalline NiCuZn ferrite powders by sol-gel auto-combustion method. Journal of Magnetism and Magnetic Materials, 2000, 208(1–2): 55–60
Selvan R K, Augustin C O, Berchmans L J, et al. Combustion synthesis of CuFe2O4. Materials Research Bulletin, 2003, 38(1): 41–54
Guo L, Shen X, Meng X, et al. Effect of Sm3+ ions doping on structure and magnetic properties of nanocrystalline NiFe2O4 fibers. Journal of Alloys and Compounds, 2010, 490(1–2): 301–306
Gupta N, Verma A, Kashyap S C, et al. Dielectric behavior of spindeposited nanocrystalline nickel-zinc ferrite thin films processed by citrate-route. Solid State Communications, 2005, 134(10): 689–694
Azadmanjiri J. Structural and electromagnetic properties of Ni-Zn ferrites prepared by sol-gel combustion method. Materials Chemistry and Physics, 2008, 109(1): 109–112
de Biasi R S, Figueiredo A B S, Fernandes A A R, et al. Synthesis of cobalt ferrite nanoparticles using combustion waves. Solid State Communications, 2007, 144(1–2): 15–17
Shukla R, Ningthoujam R S, Umare S S, et al. Decrease of superparamagnetic fraction at room temperature in ultrafine CoFe2O4 particles by Ag doping. Hyperfine Interactions, 2008, 184(1–3): 217–225
Aphesteguy J C, Damiani A, DiGiovanni D, et al. Microwave-absorbing characteristics of epoxy resin composites containing nanoparticles of NiZn- and NiCuZn-ferrites. Physica B: Condensed Matter, 2009, 404(18): 2713–2716
Atif M, Nadeem M, Grossinger R, et al. Studies on the magnetic, magnetostrictive and electrical properties of sol-gel synthesized Zn doped nickel ferrite. Journal of Alloys and Compounds, 2011, 509(18): 5720–5724
Sutka A, Stingaciu M, Mezinskis G, et al. An alternative method to modify the sensitivity of p-type NiFe2O4 gas sensor. Journal of Materials Science, 2012, 47(6): 2856–2863
Doroftei C, Rezlescu E, Rezlescu N, et al. Microstructure and humidity sensitive properties of MgFe2O4 ferrite with Sn and Mo substitutions prepared by selfcombustion method. Journal of Optoelectronics and Advanced Materials, 2006, 8(3): 1012–1015
Costa A C F M, Lula R T, Kiminami R H G A, et al. Preparation of nanostructured NiFe2O4 catalysts by combustion reaction. Journal of Materials Science, 2006, 41(15): 4871–4875
Guo X, Qi Y, Li X, et al. Preparation, characteization and photocatlytic properties of nanometer zinc ferrite. Journal of University of Science and Technology Beijing, 2004, 11(5): 474–476
Airimioaei M, Ciomaga C E, Apostolescu N, et al. Synthesis and functional properties of the Ni1 − x MnxFe2O4 ferrites. Journal of Alloys and Compounds, 2011, 509(31): 8065–8072
Hwang C-C, Tsai J-S, Huang T-H, et al. Combustion synthesis of Ni-Zn ferrite powder — influence of oxygen balance value. Journal of Solid State Chemistry, 2005, 178(1): 382–389
Costa A C F M, Morelli M R, Kiminami R H G A. Combustion synthesis: Effect of urea on the reaction and characteristics of Ni-Zn ferrite powders. Journal of Materials Synthesis and Processing, 2001, 9(6): 347–352
Mangalaraja R V, Ananthakumar S, Manohar P, et al. Initial permeability studies of Ni-Zn ferrites prepared by flash combustion technique. Materials Science and Engineering A, 2003, 355(1–2): 320–324
Mangalaraja R V, Ananthakmar S, Manohar P, et al. Characterization of Mn0.8Zn0.2Fe2O4 synthesized by flash combustion technique. Materials Science and Engineering A, 2004, 367(1–2): 301–305
Sertkol M, KŌseoglu Y, Baykal A, et al. Synthesis and magnetic characterization of Zn0.7Ni0.3Fe2O4 nano particles via microwave-assisted combustion route. Journal of Magnetism and Magnetic Materials, 2010, 322(7): 866–871
Yu L, Cao S, Liu Y, et al. Thermal and structural analysis on the nanocrystalline NiCuZn ferrite synthesis in different atmospheres. Journal of Magnetism and Magnetic Materials, 2006, 301(1): 100–106
Wu K H, Ting T H, Li M C, et al. Sol-gel auto-combustion synthesis of SiO2-doped NiZn ferrite by using various fuels. Journal of Magnetism and Magnetic Materials, 2006, 298(1): 25–32
Hwang C-C, Tsai J-S, Huang T-H. Combustion synthesis of Ni-Zn ferrite by using glycine and metal nitrates — investigations of precursor homogeneity, product reproducibility, and reaction mechanism. Materials Chemistry and Physics, 2005, 93(2–3): 330–336
Costa A C F M, Morelli M R, Kiminami R H G A. Microstructure and magnetic properties of Ni1 − x ZnxFe2O4 synthesized by combustion reaction. Journal of Materials Science, 2007, 42(3): 779–783
George M, Mary John A, Nair S S, et al. Finite size effects on the structural and magnetic properties of sol-gel synthesized NiFe2O4 powders. Journal of Magnetism and Magnetic Materials, 2006, 302(1): 190–195
Mukasyan A S, Epstein P, Dinka P. Solution combustion synthesis of nanomaterials. Proceedings of the Combustion Institute, 2007, 31(2): 1789–1795
Patil J Y, Khandekar M S, Mulla I S, et al. Combustion synthesis of magnesium ferrite as liquid petroleum gas (LPG) sensor: Effect of sintering temperature. Current Applied Physics, 2012, 12(1): 319–324
Hwang C C, Wu T Y, Wan J, et al. Development of a novel combustion synthesis method for synthesizing of ceramic oxide powders. Materials Science and Engineering B, 2004, 111(1): 49–56
Wu K H, Ting T H, Yang C C, et al. Effect of complexant/fuel on the chemical and electromagnetic properties of SiO2-doped Ni-Zn ferrite. Materials Science and Engineering B, 2005, 123(3): 227–233
Hu P, Pan D, Wang X F, et al. Fuel additives and heat treatment effects on nanocrystalline zinc ferrite phase composition. Journal of Magnetism and Magnetic Materials, 2011, 323(5): 569–573
Costa A C F M, Silva V J, Xin C C, et al. Effect of urea and glycine fuels on the combustion reaction synthesis of Mn-Zn ferrites: Evaluation of morphology and magnetic properties. Journal of Alloys and Compounds, 2010, 495(2): 503–505
Verma S, Karande J, Patidar A, et al. Low-temperature synthesis of nanocrystalline powders of lithium ferrite by an autocombustion method using citric acid and glycine. Materials Letters, 2005, 59(21): 2630–2633
Costa A C F M, Vieira D A, Silva V J, et al. Synthesis of the Ni-Zn-Sm ferrites using microwaves energy. Journal of Alloys and Compounds, 2009, 483(1–2): 37–39
Salunkhe A B, Khot V M, Phadatare M R, et al. Combustion synthesis of cobalt ferrite nanoparticles — Influence of fuel to oxidizer ratio. Journal of Alloys and Compounds, 2012, 514: 91–96
Costa A C F M, Leite A M D, Ferreira H S, et al. Brown pigment of the nanopowder spinel ferrite prepared by combustion reaction. Journal of the European Ceramic Society, 2008, 28(10): 2033–2037
Kambale R C, Adhate N R, Chougule B K, et al. Magnetic and dielectric properties of mixed spinel Ni-Zn ferrites synthesized by citrate-nitrate combustion method. Journal of Alloys and Compounds, 2010, 491(1–2): 372–377
Qiu J, Liang L, Gu M. Nanocrystalline structure and magnetic properties of barium ferrite particles prepared via glycine as a fuel. Materials Science and Engineering A, 2005, 393(1–2): 361–365
Yue Z, Li L, Zhou J, et al. Preparation and characterization of NiCuZn ferrite nanocrystalline powders by auto-combustion of nitrate-citrate gels. Materials Science and Engineering B, 1999, 64(1): 68–72
Liu C, Zou B, Rondinone A J, et al. Chemical control of superparamagnetic properties of magnesium and cobalt spinel ferrite nanoparticles through atomic level magnetic couplings. Journal of the American Chemical Society, 2000, 122(26): 6263–6267
Azadmanjiri J, Seyyed Ebrahimi S A, Salehani H K. Magnetic properties of nanosize NiFe2O4 particles synthesized by sol-gel auto combustion method. Ceramics International, 2007, 33(8): 1623–1625
Xue H, Li Z, Wang X, et al. Facile synthesis of nanocrystalline zinc ferrite via self-propagating combustion method. Materials Letters, 2007, 61(2): 347–350
Liu J, Zhang W, Guo C, et al. Synthesis and magnetic properties of quasi-single domain M-type barium hexaferrite powders via sol-gel auto-combustion: Effects of pH and the ratio of citric acid to metal ions (CA/M). Journal of Alloys and Compounds, 2009, 479(1–2): 863–869
Waqas H, Qureshi A H. Influence of pH on nanosized Mn-Zn ferrite synthesized by sol-gel auto combustion process. Journal of Thermal Analysis and Calorimetry, 2009, 98(2): 355–360
Yue Z, Guo W, Zhou J, et al. Synthesis of nanocrystalline ferrites by sol-gel combustion process: the influence of pH value of solution. Journal of Magnetism and Magnetic Materials, 2004, 270(1–2): 216–223
Kapse V D, Ghosh S A, Raghuwanshi F C, et al. Nanocrystalline spinel Ni0.6Zn0.4Fe2O4: A novel material for H2S sensing. Materials Chemistry and Physics, 2009, 113(2–3): 638–644
Kadu A V, Jagtap S V, Chaudhari G N. Studies on the preparation and ethanol gas sensing properties of spinel Zn0.6Mn0.4Fe2O4 nanomaterials. Current Applied Physics, 2009, 9(6): 1246–1251
Vijaya Bhasker Reddy P, Ramesh B, Gopal Reddy C. Electrical conductivity and dielectric properties of zinc substituted lithium ferrites prepared by sol-gel method. Physica B: Condensed Matter, 2010, 405(7): 1852–1856
Sreeja V, Vijayanand S, Deka S, et al. Magnetic and Mössbauer spectroscopic studies of NiZn ferrite nanoparticles synthesized by a combustion method. Hyperfine Interactions, 2008, 183(1–3): 99–107
Deka S, Joy P A. Characterization of nanosized NiZn ferrite powders synthesized by an autocombustion method. Materials Chemistry and Physics, 2006, 100(1): 98–101
Vivekanandhan S, Venkateswarlu M, Satyanarayana N. Effect of ethylene glycol on polyacrylicacid based combustion process for the synthesis of nano-crystalline nickel ferrite (NiFe2O4). Materials Letters, 2004, 58(22–23): 2717–2720
Wu K H, Yu C H, Chang Y C, et al. Effect of pH on the formation and combustion process of sol-gel auto-combustion derived NiZn ferrite/SiO2 composites. Journal of Solid State Chemistry, 2004, 177(11): 4119–4125
Costa A C F M, Tortella E, Morelli M R, et al. Effect of heating conditions during combustion synthesis on the characteristics of Ni0.5Zn0.5Fe2O4 nanopowders. Journal of Materials Science, 2002, 37(17): 3569–3572
Toksha B G, Shirsath S E, Patange S M, et al. Structural investigations and magnetic properties of cobalt ferrite nanoparticles prepared by sol-gel auto combustion method. Solid State Communications, 2008, 147(11–12): 479–483
Xiang J, Shen X, Meng X. Preparation of Co-substituted MnZn ferrite fibers and their magnetic properties. Materials Chemistry and Physics, 2009, 114(1): 362–366
Zhang G, Li C, Cheng F, et al. ZnFe2O4 tubes: Synthesis and application to gas sensors with high sensitivity and low-energy consumption. Sensors and Actuators B: Chemical, 2007, 120(2): 403–410
Xiang J, Shen X, Song F, et al. One-dimensional NiCuZn ferrite nanostructures: Fabrication, structure, and magnetic properties. Journal of Solid State Chemistry, 2010, 183(6): 1239–1244
Zhang C-Y, Shen X-Q, Zhou J-X, et al. Preparation of spinel ferrite NiFe2O4 fibres by organic gel-thermal decomposition process. Journal of Sol-Gel Science and Technology, 2007, 42(1): 95–100
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sutka, A., Mezinskis, G. Sol-gel auto-combustion synthesis of spinel-type ferrite nanomaterials. Front. Mater. Sci. 6, 128–141 (2012). https://doi.org/10.1007/s11706-012-0167-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11706-012-0167-3