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Research progress in the heat resistance, toughening and filling modification of PLA

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Abstract

Due to its high strength, high modulus, excellent clarity, good biodegradability and biocompatibility, poly(lactic acid) (PLA), a bio-based thermoplastic polyester, has evolved into a competitive commodity material with potential to replace conventional petrochemical-based polymers. However, the wide applications of PLA have been hampered by its native drawbacks, such as low heat distortion temperature (HDT), inherent brittleness and relatively high cost. In recent years, researchers have devoted to breaking above-mentioned bottleneck and attempted to extend the application of PLA. This review will summarize recent work about the modification of PLA, especially focusing on enhancing HDT, toughening and reducing cost.

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References

  1. Jenck JF, Agterberg F, Droescher MJ. Green Chem, 2004, 6: 544–556

    Article  CAS  Google Scholar 

  2. Liu HZ, Zhang JW. J Polym Sci Pol Phys, 2011, 49: 1051–1083

    Article  CAS  Google Scholar 

  3. Rasal RM, Hirt DE. Macromol Biosci, 2009, 9: 989–996

    Article  CAS  Google Scholar 

  4. Ray SS, Okamoto M. Macromol Rapid Commun, 2003, 24: 815–840

    Article  CAS  Google Scholar 

  5. Zhu KJ, Lin XZ, Yang SL. J Appl Polym Sci, 1990, 39: 1–9

    Article  CAS  Google Scholar 

  6. Schugens C, Grandfils C, Jerome R, Teyssie P, Delree P, Martin D, Malgrange B, Moonen G. J Biomed Mater Res, 1995,29: 1349–1362

    Article  CAS  Google Scholar 

  7. Okada M. Prog Polym Sci, 2002, 27: 87–133

    Article  CAS  Google Scholar 

  8. Linnemann B, Harwoko MS, Gries T. Chem Fibers Int, 2003, 53: 426–433

    CAS  Google Scholar 

  9. Rasal RM, Janorkar AV, Hirt DE. Prog Polym Sci, 2010, 35: 338–356

    Article  CAS  Google Scholar 

  10. Xiong Z, Ma SQ, Fan LB, Tang ZB, Zhang RY, Na HN, Zhu J. Compos Sci Technol, 2014, 94: 16–22

    Article  CAS  Google Scholar 

  11. Xiong Z, Yang Y, Feng JX, Zhang XM, Zhang CZ, Tang ZB, Zhu J. Carbohyd Polym, 2013, 92: 810–816

    Article  CAS  Google Scholar 

  12. Saeidlou S, Huneault MA, Li HB, Park CB. Prog Polym Sci, 2012, 37: 1657–1677

    Article  CAS  Google Scholar 

  13. Xiong Z, Zhang LS, Ma SQ, Yang Y, Zhang CZ, Tang ZB, Zhu J. Carbohyd Polym, 2013, 94: 235–243

    Article  CAS  Google Scholar 

  14. Legras R, Mercier JP, Nield E. Nature, 1983, 304: 432–434

    Article  CAS  Google Scholar 

  15. Nam JY, Okamoto M, Okamoto H, Nakano M, Usuki A, Matsuda M. Polymer, 2006, 47: 1340–1347

    Article  CAS  Google Scholar 

  16. Harris AM, Lee EC. J Appl Polym Sci, 2008, 107: 2246–2255

    Article  CAS  Google Scholar 

  17. Kolstad JJ. J Appl Polym Sci, 1996, 62: 1079–1091

    Article  CAS  Google Scholar 

  18. Kawamoto N, Sakai A, Horikoshi T, Urushihara T, Tobita E. J Appl Polym Sci, 2007, 103: 198–203

    Article  CAS  Google Scholar 

  19. Schmidt SC, Hillmyer MA. J Polym Sci Pol Phys, 2001, 39: 300–313

    Article  CAS  Google Scholar 

  20. Urayama H, Kanamori T, Fukushima K, Kimura Y. Polymer, 2003, 44: 5635–5641

    Article  CAS  Google Scholar 

  21. Anderson KS, Hillmyer MA. Polymer, 2006, 47: 2030–2035

    Article  CAS  Google Scholar 

  22. Ke TY, Sun XZ. J Appl Polym Sci, 2003, 89: 1203–1210

    Article  CAS  Google Scholar 

  23. Shakoor A, Thomsa NL. Polym Eng Sci, 2014, 54: 64–70

    Article  CAS  Google Scholar 

  24. Petchwattana N, Covavisaruch S, Petthai S. Polym Bull, 2014, 71: 1947–1959

    Article  CAS  Google Scholar 

  25. Ogata N, Jimenez G, Kawai H, Ogihara T. J Polym Sci Pol Phys, 1997, 35: 389–396

    Article  CAS  Google Scholar 

  26. As’habi L, Jafari SH, Khonakdar HA. Thermochim Acta, 2013, 565: 102–113

    Article  Google Scholar 

  27. Nam JY, Ray SS, Okamoto M. Macromolecules, 2003, 36: 7126–7131

    Article  CAS  Google Scholar 

  28. Tang ZB, Zhang CZ, Liu XQ, Zhu J. J Appl Polym Sci, 2012, 125: 1108–1115

    Article  CAS  Google Scholar 

  29. Xing Q, Zhang XQ, Dong X, Liu GM, Wang DJ. Polymer, 2012, 53: 2306–2314

    Article  CAS  Google Scholar 

  30. Kawamoto N, Sakai A, Horikoshi T, Urushihara T, Tobita E. J Appl Polym Sci, 2007, 103: 198–203

    Article  CAS  Google Scholar 

  31. Kawamoto N, Sakai A, Horikoshi T, Urushihara T, Tobita E. J Appl Polym Sci, 2007, 103: 244–250

    Article  CAS  Google Scholar 

  32. Cai YH, Yan SF, Fan YQ, Yu ZY, Chen XS, Yin JB. Iran Polym J, 2012, 21: 435–444

    Article  CAS  Google Scholar 

  33. Cai YH, Yan SF, Yin JB, Fan YQ, Chen XS. J Appl Polym Sci, 2011, 121: 1408–1416

    Article  CAS  Google Scholar 

  34. Nakajima H, Takahashi M, Kimura Y. Macromol Mater Eng, 2010, 295: 460–468

    CAS  Google Scholar 

  35. Bai HW, Zhang WY, Deng H, Zhang Q, Fu QA. Macromolecules, 2011, 44: 1233–1237

    Article  CAS  Google Scholar 

  36. Song P, Wei ZY, Liang JC, Chen GY, Zhang WX. Polym Eng Sci, 2012, 52: 1058–1068

    Article  CAS  Google Scholar 

  37. Suryanegara L, Okumura H, Nakagaito AN, Yano H. Cellulose, 2011, 18: 689–698

    Article  CAS  Google Scholar 

  38. Wang SS, Han CY, Bian JJ, Han LJ, Wang XM. Polym Int, 2011, 60: 284–295

    Article  CAS  Google Scholar 

  39. Shi YY, Shao LN, Yang HJ, Huang T, Wang YH, Zhang N, Wang Y. Polym Advan Technol, 2013, 24: 42–50

    Article  CAS  Google Scholar 

  40. Weng L, Xin Z. Chinese J Chem Eng, 2010, 18: 899–904

    Article  Google Scholar 

  41. Joo M, Auras R, Almenar E. Carbohyd Polym, 2011, 86: 1022–1030

    Article  CAS  Google Scholar 

  42. Qiu Z, Li Z. Ind Eng Chem Res, 2011, 50: 12299–12303

    Article  CAS  Google Scholar 

  43. Wang T, Yang Y, Zhang CZ, Tang ZB, Na HN, Zhu J. J Appl Polym Sci, 2013, 130: 1328–1336

    Article  CAS  Google Scholar 

  44. Qi ZF, Yang Y, Xiong Z, Deng J, Zhang RY, Zhu J. J Appl Polym Sci, 2015, 132: 42028

    Google Scholar 

  45. Ikada Y, Jamshidi K, Tsuji H, Hyon SH. Macromoleculecules, 1987, 20: 904–906

    Article  CAS  Google Scholar 

  46. Sun JR, Yu HY, Zhuang XL, Chen XS, Jing XB. J Phys Chem B, 2011, 115: 2864–2869

    Article  CAS  Google Scholar 

  47. Wei XF, Bao RY, Cao ZQ, Yang W, Xie BH, Yang MB. Macromoleculecules, 2014, 47: 1439–1448

    Article  CAS  Google Scholar 

  48. Brochu S, Prudhomme RE, Barakat I, Jerome R. Macromolecules, 1995, 28: 5230–5239

    Article  CAS  Google Scholar 

  49. Tsuji H, Takai H, Saha SK. Polymer, 2006, 47: 3826–3837

    Article  CAS  Google Scholar 

  50. Yamane H, Sasai K. Polymer, 2003, 44: 2569–2575

    Article  CAS  Google Scholar 

  51. Kang KS, Lee SI, Lee TJ, Narayan R, Shin BY. Korean J Chem Eng, 2008, 25: 599–608

    Article  CAS  Google Scholar 

  52. Cai J, Liu M, Wang L, Yao KH, Li S, Xiong HG. Carbohyd Polym, 2011, 86: 941–947

    Article  CAS  Google Scholar 

  53. Pei AH, Zhou Q, Berglund LA. Compos Sci Technol, 2010, 70: 815–821

    Article  CAS  Google Scholar 

  54. Frone AN, Berlioz S, Chailan JF, Panaitescu DM. Carbohyd Polym, 2013, 91: 377–384

    Article  CAS  Google Scholar 

  55. Fortnati E, Peltze M, Armentano I, Torre L, Jimenez A, Kenny JM. Carbohyd Polym, 2012, 90: 948–956

    Article  Google Scholar 

  56. Wang Y, Qin YY, Zhang YJ, Yuan MW, Li HL, Yuan ML. Int J Biol Macromol, 2014, 67: 58–63

    Article  CAS  Google Scholar 

  57. Sungsanit K, Kao N, Bhattacharya SN. Polym Eng Sci, 2012, 52: 108–116

    Article  CAS  Google Scholar 

  58. Hu Y, Hu YS, Topolkaraev V, Hiltner A, Baer E. Polymer, 2003, 44: 5681–5689

    Article  CAS  Google Scholar 

  59. Kulinski Z, Piorkowska E, Gadzinowska K, Stasiak M. Biomacromolecules, 2006, 7: 2128–2135

    Article  CAS  Google Scholar 

  60. Piorkowska E, Kulinski Z, Galeski A, Masirek R. Polymer, 2006, 47: 7178–7188

    Article  CAS  Google Scholar 

  61. Martino VP, Jimenez A, Ruseckaite RA. J Appl Polym Sci, 2009, 112: 2010–2018

    Article  CAS  Google Scholar 

  62. Vijayarajan S, Selke SEM, Matuana LM. Marcomol Mater Eng, 2014, 299: 622–630

    CAS  Google Scholar 

  63. Ali F, Chang YW, Kang SC, Yoon JY. Polym Bull, 2009, 62: 91–98

    Article  CAS  Google Scholar 

  64. Labrecque LV, Kumar RA, Dave V, Gross RA, Mccarthy SP. J Appl Polym Sci, 1997, 66: 1507–1513

    Article  CAS  Google Scholar 

  65. Ljungberg N, Wesslen B. J Appl Polym Sci, 2002, 86: 1227–1234

    Article  CAS  Google Scholar 

  66. Meng B, Deng JJ, Liu Q, Wu ZH, Yang W. Eur Polym J, 2012, 48: 127–135

    Article  CAS  Google Scholar 

  67. Yang SL, Wu ZH, Meng B, Yang W. J Polym Sci Polym Phys, 2009, 47: 1136–1145

    Article  CAS  Google Scholar 

  68. Burgos N, Tolaguera D, Fiori S, Jimenez A. J Polym Environ, 2014, 22: 227–235

    Article  CAS  Google Scholar 

  69. Yang Y, Xiong Z, Zhang LS, Tang ZB, Zhang RY, Zhu J. Mater Design, 2016, 91: 262–268

    Article  CAS  Google Scholar 

  70. Grijpma DW, Zondervan GJ, Pennings AJ. Polym Bull, 1991, 25: 327–333

    Article  CAS  Google Scholar 

  71. Theryo G, Jing F, Pitet LM, Hillmyer MA. Macromolecules, 2010, 43: 7394–7397

    Article  CAS  Google Scholar 

  72. Ho CH, Wang CH, Lin CL, Lee YD. Polymer, 2008, 49: 3902–3910

    Article  CAS  Google Scholar 

  73. Hashima K, Nishitsuji S, Inoue T. Polymer, 2010, 51: 3934–3939

    Article  CAS  Google Scholar 

  74. Qiu J, Liu F, Zhang JW, Na HN, Zhu J. Compos Sci Technol, 2016,128: 41–48

    Article  CAS  Google Scholar 

  75. Jiang L, Wolcott MP, Zhang JW. Biomacromolecules, 2006, 7: 199–207

    Article  Google Scholar 

  76. Semba T, Kitagawa K, Ishiaku US. J Appl Polym Sci, 2006, 101: 1816–1825

    Article  CAS  Google Scholar 

  77. Takayama T, Todo M. J Mater Sci, 2006, 41: 4989–4992

    Article  CAS  Google Scholar 

  78. Harada M, Ohya T, Lida K. J Appl Polym Sci, 2007, 106: 1813–1820

    Article  CAS  Google Scholar 

  79. Yu RL, Zhang LS, Feng YH, Zhang RY, Zhu J. Chinese J Polym Sci, 2014, 32: 1099–1110

    Article  CAS  Google Scholar 

  80. Zhang LS, Xiong Z, Shams SS, Yu RL, Huang JC, Zhang RY, Zhu J. Polymer, 2015, 64: 69–75

    Article  CAS  Google Scholar 

  81. Wang H, Sun XZ, Seib P. J Appl Polym Sci, 2001, 82: 1761–1767

    Article  CAS  Google Scholar 

  82. Dicker MPM, Duckworth PF, Baker AB, Francois G, Hazzard MK, Weaver PM. Compos Part A-Appl S, 2014, 56: 280–289

    Article  CAS  Google Scholar 

  83. Orue A, Jauregi A, Pena-Rodriguez C, Labidi J, Eceiza A, Arbelaiz A. Compos Part B-Eng, 2015, 73: 132–138

    Article  CAS  Google Scholar 

  84. Xu TQ, Tang ZB, Zhu J. J Appl Polym Sci, 2012, 125E: 622–627

    Article  Google Scholar 

  85. Sajna VP, Mohanty S, Nayak SK. Polym Advan Technol, 2016, 27: 515–524

    Article  Google Scholar 

  86. Dong Y, Ghataura A, Takagi H, Haroosh HJ, Nakagaito AN, Lau KT. Compos Part A-Appl S, 2014, 63: 76–84

    Article  CAS  Google Scholar 

  87. Song YA, Liu J, Chen SZ, Zheng YB, Ruan SL, Bin YZ. J Polym Environ, 2013, 21: 1117–1127

    Article  CAS  Google Scholar 

  88. Choi HY, Lee JS. Fiber Polym, 2012, 13: 217–223

    Article  CAS  Google Scholar 

  89. Alimuzzaman S, Gong RH, Akonda M. Polym Composite, 2014, 35: 2094–2102

    Article  CAS  Google Scholar 

  90. Taib RM, Ramarad S, Ishak ZAM, Todo M. Polym Composite, 2010, 31: 1213–1222

    CAS  Google Scholar 

  91. Oksman K, Skrifvars M, Selin JF. Compos Sci Technol, 2003, 63: 1317–1324

    Article  CAS  Google Scholar 

  92. Masirek R, Kulinski Z, Chionna D, Piorkowska E, Pracella M. J Appl Polym Sci, 2007, 105: 255–268

    Article  CAS  Google Scholar 

  93. Dai XY, Xiong Z, Na HN, Zhu J. Compos Sci Technol, 2014, 90: 9–15

    Article  CAS  Google Scholar 

  94. Dai XY, Xiong Z, Ma SQ, Li C, Wang JG, Na HN, Zhu J. Ind Eng Chem Res, 2015, 54: 3806–3812

    Article  CAS  Google Scholar 

  95. Zhang JF, Sun XZ. Biomacromolecules, 2004, 5: 1446–1451

    Article  CAS  Google Scholar 

  96. Wu CS. Macromol Biosci, 2005, 5: 352–361

    Article  CAS  Google Scholar 

  97. Shin BY, Han DH. Adv Compos Mater, 2013, 22: 411–423

    Article  CAS  Google Scholar 

  98. Xiong Z, Dai XY, Zhang RY, Tang ZB, Na HN, Zhu J. Ind Eng Chem Res, 2014, 53: 10653–10659

    Article  CAS  Google Scholar 

  99. Wang JW, Zhai WT, Zheng WG. J Polym Environ, 2012, 20: 528–539

    Article  CAS  Google Scholar 

  100. Xiong Z, Li C, Ma SQ, Feng JX, Yang Y, Zhang RY, Zhu J. Carbohyd Polym, 2013, 95: 77–84

    Article  CAS  Google Scholar 

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Correspondence to Ruoyu Zhang or Jin Zhu.

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Yang, Y., Zhang, L., Xiong, Z. et al. Research progress in the heat resistance, toughening and filling modification of PLA. Sci. China Chem. 59, 1355–1368 (2016). https://doi.org/10.1007/s11426-016-0222-7

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