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Preconcentration of metal ions using microbacteria

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Abstract

This review (160 refs). covers the current state of the art of microbacteria-based sorbents for preconcentration of metal ions at trace levels. We highlight advantages and major challenges of the techniques and discuss future perspectives of both batch and column-based methods. Particular attention is paid to the preconcentration of metal ions using resin-immobilized microbacteria for solid phase extractions. We also discuss detection methods including UV–vis spectrophotometry, FAAS, ICP-OES and ICP-MS. Analytical figures of merit are compared, and examples are given for the application to a variety of samples including food, beverages, alloys, water, soil, and geological samples.

An graphical presentation of main experimental steps in solid phase extraction procedure for metal ions together with the summarization of affinity of metal ions to functional groups on the surface of bacteria by considering the classifications according to hard and soft acids and bases theory by Pearson

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Abbreviations

AHCANSA:

4-Amino-3-hydroxy-2–(2-chlorobenzene)-azo-1-naphthalene sulfonic acid

CMC:

Critical micelle concentration

CPE:

Cloud point extraction

CPI-MIP-OES:

Continuous powder introduction microwave induced plasma-optical emission spectrometry

DLLME:

Dispersive liquid-liquid microextraction

EDL:

Electrodeless discharge lamp

EPA:

Environmental protection agency

ET-AAS:

Electro thermal atomic absorption spectrometry

FAAS:

Flame atomic absorption spectrometry

GF-AAS:

Graphite furnace atomic absorption spectrometry

HCL:

Hollow cathode lamp

HSAB:

Hard and soft acids and bases

HG-AAS:

Hydride generation atomic absorption spectrometry

ICP-OES:

Inductively coupled plasma optical emission spectrometry

ICP-MS:

Inductively coupled plasma mass spectrometry

LOD:

Limit of detection

LOQ:

Limit of quantification

MWCNT:

Multiwalled carbon nanotubes

UV–VIS:

Ultraviolet visible spectrophotometry

PAN:

1-(2-Pyridylazo)-2-naphthol

PF:

Preconcentration factor

RSD:

Relative standard deviation

SPE:

Solid phase extraction

SPME:

Solid phase microextraction

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Authors and Affiliations

  1. Department of Biology, Faculty of Art and Science, Siirt University, 56100, Siirt, Turkey

    Sadin Özdemir & Veysi Okumuş

  2. Health Services Vocational High School, Medical Marketing and Promotion Programme, Mardin Artuklu University, 47200, Mardin, Turkey

    Abdurrahman Dündar

  3. Department of Chemistry, Faculty of Science, Dicle University, 21280, Diyarbakir, Turkey

    Ersin Kılınç

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  1. Sadin Özdemir
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  2. Veysi Okumuş
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  3. Abdurrahman Dündar
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  4. Ersin Kılınç
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Correspondence to Sadin Özdemir or Ersin Kılınç.

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Özdemir, S., Okumuş, V., Dündar, A. et al. Preconcentration of metal ions using microbacteria. Microchim Acta 180, 719–739 (2013). https://doi.org/10.1007/s00604-013-0991-x

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