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Epoxy Nanocomposites with Metal-Containing Fillers: Synthesis, Structure, and Properties

  • Macromolecular Compounds and Polymeric Materials
  • Published:
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Abstract

Recent achievements in the field of the development of preparation methods and study of structure and properties of epoxy nanocomposites with metal-containing fillers are analyzed. The ex situ and in situ methods for preparing epoxy nanocomposites are discussed. Nanocomposites with such fillers as metals, oxides, salts, chalcogenides, quantum dots, and hybrid and multicomponent fillers are considered. The structure of epoxy nanocomposites is analyzed in detail; it is determined by the structure of the matrix, by the type and character of nanoparticle distribution in the volume, and by the thickness and structure of the interfacial layer. The influence of the dimensionality (zero-, one-, two-, or three-dimensional) of metal-containing filler nanoparticles on the structure of the formed epoxy matrix of the nanocomposites is discussed. The dependence of the mechanical properties of epoxy nanocomposites on the interfacial interaction and structure of the matrix is analyzed. The electrophysical, magnetic, thermal, and tribological properties of the epoxy nanocomposites are considered.

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Notes

  1. Concentrators of stresses are material constituents causing increased stresses in the regions of sharp changes in the material shape and also in zones of contact of material components.

  2. Digestive ripening, also termed size focusing or inverse Ostwald ripening, is the transition of atoms from coarse nanoparticles to finer particles; it is a convenient way to make the size distribution function narrower [33].

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Funding

The study was performed within the framework of the government assignment for the Institute of Problems of Chemical Physics, Russian Academy of Sciences (theme registry no. АААА-А19119032690060-9).

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  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    V. I. Irzhak

  2. Southern Federal University, 344090, Rostov-on-Don, Russia

    I. E. Uflyand

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Translated from Zhurnal Prikladnoi Khimii, No. 2, pp. 138–163, February, 2022 https://doi.org/10.31857/S0044461822020013

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Irzhak, V.I., Uflyand, I.E. Epoxy Nanocomposites with Metal-Containing Fillers: Synthesis, Structure, and Properties. Russ J Appl Chem 95, 167–190 (2022). https://doi.org/10.1134/S1070427222020021

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