Skip to main content
Log in

The role of stress distribution at the film/barrier interface in formation of copper silicides

  • Fabrication, Treatment, and Testing of Materials and Structures
  • Published:
Semiconductors Aims and scope Submit manuscript

Abstract

Silicide formation in thin Cu films subjected to thermal annealing has been investigated by atomic force microscopy, scanning electron microscopy, X-ray diffraction, and energy-dispersive X-ray spectroscopy. It is shown that the periodic stress distribution at the film/barrier interface under elevated temperatures can govern the character of copper silicide formation. The effect of barrier layer material and substrate orientation on the distribution density and shape of Cu3Si crystallites has been studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. B. Li, T. D. Sullivan, T. C. Lee, and D. Badami, Microelectron. Reliab. 44, 365 (2004).

    Article  Google Scholar 

  2. Y. K. Ko, J. H. Jang, S. Lee, H. J. Yang, W. H. Lee, P. J. Reucroft, and J. G. Lee, J. Mater. Sci. 38, 217 (2003).

    Article  Google Scholar 

  3. J. P. Chu, C. H. Lin, and Y. Y. Hsieh, J. Electron. Mater. 35, 76 (2006).

    Article  ADS  Google Scholar 

  4. S. Tsukimoto, T. Kabe, K. Ito, and M. Murakami, J. Electron. Mater. 36, 258 (2007).

    Article  ADS  Google Scholar 

  5. Y. Ezer, J. Härkönen, S. Arpiainen, V. Sokolov, P. Kuivalainen, J. Saarilahti, and J. Kaitila, Phys. Scripta T 79, 228 (1999).

    Article  ADS  Google Scholar 

  6. S. Y. Jang, S. M. Lee, and H. K. Baik, J. Mater. Sci.: Mater. Electron. 7, 271 (1996).

    Article  Google Scholar 

  7. J. S. Fang, T. P. Hsu, and G. S. Chen, J. Electron. Mater. 35, 15 (2006).

    Article  ADS  Google Scholar 

  8. Y. Shacham-Diamand, J. Electron. Mater. 30, 336 (2001).

    Article  ADS  Google Scholar 

  9. Thin Films: Interdiffusion and Reactions, Ed. by J. M. Poate, K. N. Tu, and J. W. Mayer (Wiley, New York, 1978; Mir, Moscow, 1982).

    Google Scholar 

  10. L. B. Freund and S. Suresh, Thin Film Materials: Stress, Defect Formation and Surface Evolution (Cambridge Univ., Cambridge, 2003).

    Google Scholar 

  11. X.-Y. Gong and D. R. Clarke, Oxid. Met. 50(5–6), 355 (1998).

    Article  Google Scholar 

  12. M. Y. He, A. G. Evans, and J. W. Hutchinson, Acta Mater. 48, 2593 (2000).

    Article  Google Scholar 

  13. J. O. Olowolafe, J. Li, and J. W. Mayer, J. Appl. Phys. 68, 6207 (1990).

    Article  ADS  Google Scholar 

  14. W. Schröter, V. Kevder, M. Seibt, H. Ewe, H. Hedemann, F. Riedel, and A. Sattler, Mater. Sci. Eng. B 72, 80 (2000).

    Article  Google Scholar 

  15. J. H. Zhao, M. Zhang, R. P. Liu, X. Y. Zhang, L. M. Cao, D. Y. Dai, H. Chen, and Y. F. Xu, J. Mater. Res. 14, 2888 (1990).

    Article  ADS  Google Scholar 

  16. S. Hong, S. Lee, Y. Ko, and J. Lee, Mater. Res. Soc. Symp. Proc. 766, 119 (2003).

    Google Scholar 

  17. D. Vale, G. Weber, and B. Gillot, Oxid. Met. 35(5–6), 415 (1991).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. V. Panin.

Additional information

Original Russian Text © A.V. Panin, A.R. Shugurov, I.V. Ivonin, Ye.V. Shesterikov, 2010, published in Fizika i Tekhnika Poluprovodnikov, 2010, Vol. 44, No. 1, pp. 118–125.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Panin, A.V., Shugurov, A.R., Ivonin, I.V. et al. The role of stress distribution at the film/barrier interface in formation of copper silicides. Semiconductors 44, 116–122 (2010). https://doi.org/10.1134/S1063782610010203

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063782610010203

Keywords

Navigation