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A review on applications of carbon nanotubes-based metal-sulfide composite anode materials (CNTs/MS) for sodium (Na)-ion batteries

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Abstract

Lithium-ion batteries (LIBs) have played a significant role in various applications, such as powering electronics and electric vehicles. However, due to the rising cost of lithium and its limited availability in the earth's crust arises, doubts whether the LIBs only have the capability to meet the increasing energy demand in the transportation sector in the future. Hence, researchers viewed sodium-ion batteries (SIBs) as a viable alternative to lithium-ion batteries (LIBs) for future energy storage applications due to the abundant availability of sodium resources, and their excellent electrochemical performance as comparable to that of LIBs. But, the commercialization of Na-ion batteries has been hindered by the degradation of conventional anode material performance and their unstable performance. To address these issues, Carbon Nanotubes (CNTs) based metal sulfide (MS) composites were recently employed as anode materials due to their low cost and higher gravimetric capacities. This review discusses the recent advancements in carbon nanotube-based metal sulfide anode materials, their various synthesis methods, morphological characteristics, and electrochemical properties. Finally, we also present strategies for increasing the electrochemical performance of future-generation SIBs.

Graphical abstract

Carbon nanotube-based anodes make sodium-ion batteries stronger.

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  1. Faculty of Integrated Technologies, Universiti Brunei Darussalam, Gadong, BE1410, Brunei

    Yathavan Subramanian, Anitha Dhanasekaran, Lukman Ahmed Omeiza, Veena Raj, Hayati Yassin, Shammya Afroze & Abul Kalam Azad

  2. Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor, Malaysia

    Mahendra Rao Somalu

  3. L.N. Gumilyov, Eurasian National University, Astana, 010008, Kazakhstan

    Shammya Afroze

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Yathavan Subramanian: conceptualization, writing (original draft preparation), writing (review and editing),

Anitha Dhanasekaran: writing (original draft preparation),

Lukman Ahmed Omeiza: writing (original draft preparation),

Veena R: Visualization,

Hayati Y: Visualization,

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Shammya Afroze: writing (review and editing),

Abul Kalam Azad: critical revision, supervision;

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Subramanian, Y., Dhanasekaran, A., Omeiza, L.A. et al. A review on applications of carbon nanotubes-based metal-sulfide composite anode materials (CNTs/MS) for sodium (Na)-ion batteries. emergent mater. 7, 357–385 (2024). https://doi.org/10.1007/s42247-023-00501-3

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  • DOI: https://doi.org/10.1007/s42247-023-00501-3

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