Abstract
Electroanalytical performance of electrodeposited platinum nanoparticles (PtNPs), selenium nanoparticles (SeNPs), and tin oxide nanoparticles (SnO2NPs) on the surface of bare fluorine-doped tin oxide (BFTO) (PtNPs-SeNPs-SnO2NPs@BFTO) nanocomposite was used as an non-enzymatic electrochemical sensor towards detection of H2O2. The surface morphology and characterization of PtNPs-SeNPs-SnO2NPs@BFTO was studied by field emission scanning electron microscopy (FESEM) and EDS mapping. The Morphology of PtNPs-SeNPs-SnO2NPs@BFTO showed flower, spherical and irregular shapes by FESEM investigation. X-ray photoelectron spectroscopy was used to investigate the elemental composition of platinum, selenium, tin, oxygen, and fluorine on the PtNPs-SeNPs-SnO2NPs@BFTO surface. The synthesized PtNPs-SeNPs-SnO2NPs@BFTO electrochemical sensor was used for electro-catalytic detection of H2O2. The linear concentration range of the PtNPs-SeNPs-SnO2NPs@BFTO was 0.01 to 54 mM, with a high sensitivity of 104.8 mA mM−1 cm−2 and a low detection limit of 0.01 mM. The interference study of PtNPs-SeNPs-SnO2NPs@BFTO based sensors showed high selectivity towards H2O2 with interfering agents, including glucose (GU), ascorbic acid (AA), urea (UA), sucrose (SU), sodium chloride (SC), and sodium selenite (SS).
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Acknowledgements
We are grateful to the Materials Research Centre, MNIT Jaipur, for providing the research facility for the characterization of samples. We are also thankful to the Ministry of Education (MoE), Government of India for providing fellowship and Chemical Engineering Department, SVNIT, Surat, for providing research facilities.
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Nilesh S. Dumore: Formal analysis, Data curation, Investigation, Methodology, Writing- original draft. Mausumi Mukhopadhyay: Data curation, Conceptualization, Writing—review & editing, Supervision.
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Dumore, N.S., Mukhopadhyay, M. Electroanalytical Performance of Non-Enzymatical Electrochemical Sensor Based on PtNPs-SeNPs-SnO2NPs@BFTO Nanocomposites for the Detection of Hydrogen Peroxide. Electrocatalysis 14, 708–719 (2023). https://doi.org/10.1007/s12678-023-00828-9
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DOI: https://doi.org/10.1007/s12678-023-00828-9