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Synthesis of Cyclic Carbonate from Carbon Dioxide and Epoxides Using Bicobalt Complexes Absorbed on DFNS

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Abstract

Herein, a 2D closely packed bicobalt complex supported by DFNS was first provided. The XPS and EDX pictures of the DFNS/(bicobalt complex) catalysts affirmed that bicobalt complex was well spread on the outer layer of DFNS. The CO2/propylene oxide coupling reactions, employing DFNS/(bicobalt complex) as catalysts were announced. In addition, the catalyst anatomical heterogeneity of DFNS/(bicobalt complex) was characterized by various techniques, including EDX, SEM, TGA, TEM, XPS, and FT-IR. No leaching of cobalt into the solution was observed. The catalytic power of our catalyst was compared with literature reported catalysts for the synthesis of cyclic carbonate. lower temperature, the minimum amount of catalyst, lower pressure of carbon dioxide and shorter reaction time were required for CO2 transformation, using DFNS/(bicobalt complex) NPs. Besides, hot filtration presented a throughout understanding of the catalyst’s heterogeneous nature. The easy and applied reusability of the catalyst was observed after the completion of the reaction.

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Authors and Affiliations

  1. Department of Medical Instrumentation Techniques, Bilad Alrafidain University College, Baghdad, Diyala, Iraq

    Ali Hassan

  2. Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, Iraq

    Khalida Abaid Samawi

  3. Integrated Chemical BioPhysics Research, Faculty of Science, Universiti Putra Malaysia, 43400 UPM, Serdang, Selangor, Malaysia

    Maadh Fawzi Nassar

  4. Department of Chemistry,, Faculty of Science, Universiti Putra Malaysia, 43400 UPM, Serdang, Selangor, Malaysia

    Maadh Fawzi Nassar

  5. Department of Police Equipment and Technologies, Policing Sciences and Social Studies Institute, Tehran, Iran

    Reza Haddad & Ali Roostaie

  6. Department of Chemistry, Faculty of Sciences, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

    Seyed Mohsen Sadeghzadeh

Authors
  1. Ali Hassan
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  2. Khalida Abaid Samawi
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  3. Maadh Fawzi Nassar
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  4. Reza Haddad
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  5. Ali Roostaie
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  6. Seyed Mohsen Sadeghzadeh
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Correspondence to Seyed Mohsen Sadeghzadeh.

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Hassan, A., Samawi, K.A., Nassar, M.F. et al. Synthesis of Cyclic Carbonate from Carbon Dioxide and Epoxides Using Bicobalt Complexes Absorbed on DFNS. Catal Lett 153, 2900–2909 (2023). https://doi.org/10.1007/s10562-022-04130-z

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  • DOI: https://doi.org/10.1007/s10562-022-04130-z

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