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Synthesis of New Class of Copper(II) Complex-Based FeNi3/KCC-1 for the N-Formylation of Amines Using Dihydrogen and Carbon Dioxide

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Abstract

This study investigated the potential application of an efficient, easily recoverable, and reusable copper(II)-based catalyst bearing polyvinyl alcohol (PVA) immobilized on FeNi3/KCC-1/APTPOSS [FeNi3/KCC-1/APTPOSS/TCT/PVA/Cu(II)] magnetic nano-particles (MNPs) for the N-formylation of amines via CO2 hydrogenation. FeNi3/KCC-1/TCT/PVA/Cu(II) MNPs were thoroughly characterized by transmission electron microscopy, field emission-scanning electron microscopy, vibrating sample magnetometry, thermo-gravimetric analysis, inductively coupled plasma-mass spectrometry (ICP-MS), and the Brunauer, Emmett, and Teller method. After the reaction, only minor changes to the morphology of the catalyst recycled by the ICP-MS were evidenced, thus corroborating its robustness.

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Authors and Affiliations

  1. Young Researchers and Elite Club, Neyshabur Branch, Islamic Azad University, P.O. Box 97175-613, Neyshabur, Iran

    Rahele Zhiani & Seyed Mohsen Sadeghzadeh

  2. Department of Chemistry, Bojnourd Branch, Islamic Azad University, Bojnourd, Iran

    Seyed Mahdi Saadati

  3. Department of Chemistry, Faculty of Science, University of Jiroft, Jiroft, 7867161167, Iran

    Mahboobeh Zahedifar

Authors
  1. Rahele Zhiani
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  2. Seyed Mahdi Saadati
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  3. Mahboobeh Zahedifar
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  4. Seyed Mohsen Sadeghzadeh
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Correspondence to Seyed Mohsen Sadeghzadeh.

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Zhiani, R., Saadati, S.M., Zahedifar, M. et al. Synthesis of New Class of Copper(II) Complex-Based FeNi3/KCC-1 for the N-Formylation of Amines Using Dihydrogen and Carbon Dioxide. Catal Lett 148, 2487–2500 (2018). https://doi.org/10.1007/s10562-018-2475-4

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  • DOI: https://doi.org/10.1007/s10562-018-2475-4

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