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Ni2(BDC)2(DABCO) metal–organic framework for cyclic carbonate synthesis from CO2 and epoxides (BDC = 1,4-benzendicarboxylic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane)

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Abstract

A Ni based metal organic framework Ni2(BDC)2(DABCO) has been synthesized by using Ni(II) ions and BDC (1,4-benzendicarboxylic acid) and DABCO (1,4-diazabicyclo[2.2.2]octane) ligands under solvothermal conditions. The prepared catalyst has been analyzed using various physicochemical techniques such as PXRD, FT-IR, ICP-OES, XPS, NH3-TPD, CO2-TPD, and BET. The heterogeneous catalytic performance of synthesized catalyst in the cycloaddition of CO2 and epoxides was investigated without using any solvent under mild reaction conditions. The influence of various reaction parameters like CO2 pressure, catalyst amount, time, and temperature, has been studied. Ni2(BDC)2(DABCO) was reused for five times without any considerable loss in the initial activity. Based on literature inferences and our previous studies, a plausible reaction mechanism for the cycloaddition reaction was also suggested.

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Acknowledgements

This work was supported by National Research Foundation of Korea (2016-R1D1A1B-03931325), and Korea Electric Power Corporation.

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Authors and Affiliations

  1. Division of Chemical and Biomolecular Engineering, Pusan National University, Busan, 609-735, Korea

    Hyeon-Jun Kim, Jintu Francis Kurisingal & Dae-Won Park

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  1. Hyeon-Jun Kim
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  2. Jintu Francis Kurisingal
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  3. Dae-Won Park
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Correspondence to Dae-Won Park.

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Kim, HJ., Kurisingal, J.F. & Park, DW. Ni2(BDC)2(DABCO) metal–organic framework for cyclic carbonate synthesis from CO2 and epoxides (BDC = 1,4-benzendicarboxylic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane). Reac Kinet Mech Cat 124, 335–346 (2018). https://doi.org/10.1007/s11144-018-1356-6

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