Abstract
A modular, compact Raman spectrometer, based on a green laser pointer, an air cooled intensified charged coupled device and a x, y motorized translation stage was developed and applied for point detection. Its performance was tested for measurements of Raman spectra of liquids, trace amounts of explosives and individual particles, as well as for locating individual particles of interest and for chemical imaging of residues of latent human fingerprints. This system was found to be highly sensitive, identifying masses as low as ~1 ng in short times. The point and real-time detection capabilities of the spectrometer, together with the portability that it offers, make it a potential candidate for replacing existing Raman microscopes and for field applications.
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U. Willer, W. Schade, Anal. Bioanal. Chem. 395, 275 (2009)
S. Wallin, A. Pettersson, H. Östmark, A. Hobro, Anal. Bioanal. Chem. 395, 259 (2009)
D.S. Moore, Rev. Sci. Instrum. 75, 2499 (2004)
D.S. Moore, R.J. Scharff, Anal. Bioanal. Chem. 393, 1571 (2009)
M. Nambayah, T.I. Quickenden, Talanta 63, 461 (2004)
J.I. Steinfeld, J. Wormhoudt, Annu. Rev. Phys. Chem. 49, 203 (1998)
A. Fainberg, Science 225, 1531 (1992)
J.B. Simeonsson, R.C. Sausa, Trends Anal. Chem. 17, 542 (1998)
J.B. Simeonsson, R.C. Sausa, Appl. Spectrosc. Rev. 31, 1 (1996)
N. Daugey, J. Shu, I. Bar, S. Rosenwaks, Appl. Spectrosc. 53, 57 (1999)
J. Shu, I. Bar, S. Rosenwaks, Appl. Opt. 38, 4705 (1999)
ibid, Appl. Phys. B, 70, 621 (2000)
ibid, Appl. Phys. B, 71, 665 (2000)
T. Arusi-Parpar, D. Heflinger, R. Lavi, Appl. Opt. 40, 6677 (2001)
D. Heflinger, T. Arusi-Parpar, Y. Ron, R. Lavi, Opt. Comm. 204, 327 (2002)
G.P. Smith, B. Krancevic, D.L. Huestis, H. Oser, Appl. Phys. B 94, 127 (2009)
B. Wen, H. Eilers, Appl. Phys. B 106, 473 (2012)
F. Fuchs, S. Hugger, M. Kinzer, R. Aidam, W. Bronne, R. Losch, Q. Yang, K. Degreif, F. Schnürer, Opt. Eng. 49, 111127 (2010)
C.K.N. Patel, J. Laser Appl. 21, 224 (2009)
ibid, Eur. Phys. J. Spec. Top. 153, 1 (2008)
M.B. Pushkarsky, I.G. Dunayevskiy, M. Prasanna, A.G. Tsekoun, R. Go, C.K.N. Patel, Proc. Natl. Acad. Sci. 103, 19630 (2006)
A.A. Kosterev, Y.A. Bakhirkin, R.F. Curl, F.K. Tittel, Opt. Lett. 27, 1902 (2002)
A.A. Kosterev, F.K. Tittel, D.V. Serebryakov, A.L. Malinovsky, I.V. Morozov, Rev. Sci. Instrum. 76, 043105 (2005)
D.L. Huestis, G.P. Smith, H. Oser, Proc. SPIE-Int. Soc. Opt. Eng. 7679, 76790G (2010)
A. Portnov, S. Rosenwaks, I. Bar, J. Luminesc. 102, 408 (2003)
ibid, Appl. Opt. 42, 2835 (2003)
J.L. Gottfried, F.C. De Lucia, C.A. Munson, A.W. Miziolek, Anal. Bioanal. Chem. 395, 283 (2009)
J. Moros, J.A. Lorenzo, P. Lucena, L.M. Tobaria, J.J. Laserna, Anal. Chem. 82, 1389 (2010)
C. López-Moreno, S. Palanco, J.J. Laserna, F.C. De Lucia, A.W. Miziolek Jr, J. Rose, R.A. Walters, A. Whitehouse, J. Anal. At. Spectrom. 21, 55 (2006)
R. Noll, C. Fricke-Begemann in Stand-off Detection of Surface Contaminations with Explosive Residues Using Laser-Spectroscopic Methods, ed. by H. Schubert and A. Rimski-Korsakov. Stand-off Detection of suicide Bombers and Mobile Subjects, (Springer, Dordrecht, 2006), p. 89
C. Bohling, K. Hohmann, D. Scheel, C. Bauer, W. Schippers, J. Burgmeier, U. Willer, G. Holl, W. Schade, Spectrochim. Acta B 62, 1519 (2007)
V.I. Babushok, F.C. DeLucia Jr, P.J. Dagdigian, J.L. Gottfried, C.A. Munson, M.J. Nusca, A.W. Miziolek, Spectrochim. Acta B 62, 1321 (2007)
Y. Dikmelik, C. McEnnis, J.B. Spicer, Opt. Express 16, 5332 (2008)
M. Gaft, L. Nagli, Opt. Mater. 30, 1739 (2008)
S.K. Sharma, A.K. Misra, B. Sharma, Spectrochim. Acta A 61, 2404 (2005)
S.K. Sharma, A.K. Misra, P.G. Lucey, S.M. Angel, C.P. Mckay, Appl. Spectrosc. 60, 871 (2006)
J.C. Carter, S.M. Angel, M. Lawrence-Snyder, J. Scaffidi, R.E. Whipple, J.G. Reynolds, Appl. Spectrosc. 59, 769 (2005)
B. Zachhuber, C. Gasser, G. Ramer, EtH Chrysostom, B. Lendl, Appl. Spectrosc. 66, 875 (2012)
B. Zachhuber, C. Gasser, G. Ramer, B. Lendl, Anal. Chem. 83, 9438 (2011)
A.J. Hobro, B. Lendl, Trends Anal. Chem. 28, 1235 (2009)
A. Pettersson, I. Johansson, S. Wallin, M. Nordberg, H. Östmark, Propell. Explos. Pyrot. 34, 297 (2009)
J. Moros, J.A. Lorenzo, K. Novotný, J.J. Laserna, J. Raman Spectrosc. 44, 121 (2013)
E.L. Izake, B. Cletus, W. Olds, S. Sundarajoo, P.M. Fredericks, E. Jaatinen, Talanta 94, 342 (2012)
G.I. Petrov, V.V. Yakovlev, A.V. Sokolov, M.O. Scully, Opt. Express 13, 9537 (2005)
H. Li, D.A. Harris, B. Xu, P.J. Wrzesinski, V.V. Lozovoy, M. Dantus, Opt. Express 16, 5499 (2008)
A. Natan Katz, Y. Silberberg, S. Rosenwaks, Appl. Phys. Lett. 92, 171116 (2008)
A. Portnov, S. Rosenwaks, I. Bar, Appl. Phys. Lett. 93, 041115 (2008)
A. Portnov, I. Bar, S. Rosenwaks, Appl. Phys. B 98, 529 (2010)
A. Natan, J.M. Levitt, L. Graham, O. Katz, Y. Silberberg, Appl. Phys. Lett. 100, 051111 (2012)
G.L. Gresham, J.P. Davies, L.D. Goodrich, L.G. Blackwood, B.Y.H. Liu, D. Thimsem, S.H. Yoo, S.F. Hallowell, Proc. SPIE-Int. Soc. Opt. Eng. 2276, 34 (1994)
S. Inoue, Foundations of confocal scanned imaging in light microscopy, in Handbook of Biological Confocal Microscopy, ed. by J.B. Pawley (Springer, New York, 2006)
R.L. McCreery, in Photometric Standards for Raman Spectroscopy, ed. by J.M. Chalmers, P.R. Griffiths. Handbook of Vibrational Spectroscopy, (John Wiley and Sons Ltd. Chichester 2002)
Y. Mou, J.W. Rabalais, J. Forensic Sci. 54, 846 (2009)
R.L. McCreery, Raman Spectroscopy for Chemical Analysis (John Wiley and Sons Ltd, New York, 2000)
D.K. Williams, R.L. Schwartz, E.G. Bartick, Appl. Spectrosc. 58, 313 (2004)
C. Ricci, S. Bleay, S.G. Kazarian, Anal. Chem. 79, 5771 (2007)
M. Abdelhamid, F.J. Fortes, M.A. Harith, J.J. Laserna, J. Anal. At. Spectrom. 26, 1445 (2011)
J.S. Day, H.G.M. Edwards, S.A. Dobrowski, A.M. Voice, Spectrochim. Acta A 60, 563 (2004)
C. Cheng, T.E. Kirkbridge, D.N. Batchelder, R.J. Lacey, T.G. Sheldon, J. Forensic Sci. 40, 31 (1995)
A. Tripathi, E.D. Emmons, P.G. Wilcox, J.A. Guicheteau, D.K. Emge, S.D. Christesen, A.W. Fountain III, Appl. Spectrosc. 65, 611 (2011)
V. Pajcini, C.H. Munro, R.W. Bormett, R.E. Witkowski, S.A. Asher, Appl. Spectrosc. 51, 81 (1997)
W.R.C. Somerville, E.C. Le Ru, P.T. Northcote, P.G. Etchegoin, Am. J. Phys. 78, 671 (2010)
C. Mohr, C.L. Spencer, M. Hippler, J. Chem. Educ. 87, 326 (2010)
Acknowledgments
Financial support from NATO Science for Peace (SfP) Project 983789, the Technion—The Institute for Future Security Research, the James Franck Binational German-Israeli Program in Laser-Matter Interaction and the Israel Science Foundation founded by The Israel Academy of Science and Humanities is gratefully acknowledged.
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Malka, I., Petrushansky, A., Rosenwaks, S. et al. Detection of explosives and latent fingerprint residues utilizing laser pointer–based Raman spectroscopy. Appl. Phys. B 113, 511–518 (2013). https://doi.org/10.1007/s00340-013-5500-8
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DOI: https://doi.org/10.1007/s00340-013-5500-8