Skip to main content
SpringerLink
Log in

[MPy4(NCO)2]-2Py clathrates (M = M(II) = Mn, Fe, Co, Ni, Cu, Zn, Cd; Py = pyridine)

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The title compounds form an iso structural series and are isomorphic with other [MPy4X2]-2Py clathrates (XRD, KM4 diffractometer, cell parameters and space group Ccca from 17–80 reflections). In the clathrate [NiPy4(NCO)2]-2Py studied in detail (XRD, CAD-4 diffractom eter, λCuKα, Ω/2θ scan mode, θmax = 78‡, 990 strong reflections, 104 parameters, R = 0.053), the host molecule has 222 symmetry, and the twofold axes run along the coordination bonds. The transoctahedral environment of nickel consists of six nitrogen atoms of four pyridine and two isocyanate ligands. The coordination polyhedron is slightly distorted due to changes in the bond lengths. The molecule has a propeller conformation. The guest molecules lie in the cavities of the crystal structure in conformity with the van der Waals type of packing. The host complex [NiPy4(NCO)2] (XRD, CAD-4 diffractometer, 4615 strong reflections, 560 parameters, R-0.037) crystallizes in the triclinic crystal system (space group P1) with two independent asymmetric molecules in the unit cell. The molecular structure is analogous to that in the ciathrate phase, but the coordination angles are severely distorted; one of the molecules acquires a distorted propeller conformation, and the other, a centrosvmmetric conformation, which is less favorable. While being structurally identical, the [MPy4(NCO)2]-2Py clathrates differ heavily in the properties. The first four complexes dissociate to host complexes, and their thermal stability changes in the sequence Mn< Fe< Co< Ni; the Cu and Zn clathrates decompose in one step to dipyridine complexes with decomposition of host complexes. Decomposition of the Cd ciathrate follows one of these patterns depending on conditions. The results are compared with those for other known systems. Synthetic procedures are given.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. V. Soldatov and J. Lipkowski,Zh. Strukt. Khim.,36, 1070–1073 (1995).

    CAS  Google Scholar 

  2. D. V. Soldatov, Yu. A. Dyadin, J. Lipkowski, and A. G. Ogienko,Mendeleev Commun., 11–13 (1997).

  3. J. Lipkowski,Comp. Supr. Chenu.,6, 691–714 (1996).

    CAS  Google Scholar 

  4. S. Halut-Desportes,Acta Crystallogr.,B33, 599–601 (1977).

    CAS  Google Scholar 

  5. A. F. Waters and A. H. White,Aust. J. Chenu.,49, 35–46 (1966).

    Google Scholar 

  6. D. V. Soldatov and J. A. Ripmeester,Supramol. Chenu.,9, 175–181 (1998).

    Article  CAS  Google Scholar 

  7. M. Philoche-Levisalles and S. Halut-Desportes,C. R. Acad. Sci. Paris,C284, 183–185 (1977).

    Google Scholar 

  8. D. V. Soldatov and J. Lipkowski,Zh. Strukt. Khim.,39, 292–299 (1988).

    Google Scholar 

  9. A. J. Finney, M. A. Hitchman, C. L. Raston, et al.,Aust. J. Chenu.,34, 2095–2111 (1981).

    CAS  Google Scholar 

  10. D. V. Soldatov, J. Lipkowski, and E. V. Grachev,Zh. Strukt. Khinu.,36, 912–918 (1995).

    CAS  Google Scholar 

  11. M. Selkti, C.-C. Ling, and A. Navaza,J. Incl. Phenonu.,17, 127–135 (1994).

    Article  CAS  Google Scholar 

  12. D. V. Soldatov,ibid.,20, 191–193 (1995).

    Article  Google Scholar 

  13. P. B. Durand and E. M. Holt,Acta Crystallogr.,C51, 850–852 (1995).

    CAS  Google Scholar 

  14. P. Losier and M. J. Zaworotko,J. Chem. Crystallogr.,26, 277–280 (1996).

    Article  CAS  Google Scholar 

  15. M. Ito, T. Shibata, and Y. Saito,Acta Crystallogr.,C40, 2041–2043 (1984).

    CAS  Google Scholar 

  16. D. V. Soldatov, B. A. Kolesov, J. Lipkowski, and Yu. A. Dyadin,Zh. Strukt. Khim.,38, 976–987 (1977).

    Google Scholar 

  17. D. V. Soldatov and J. Lipkowski,Zh. Strukt. Khim.,36, 1074–1082 (1995).

    CAS  Google Scholar 

  18. G. Beurskens, C. F. Martens, R. J. M. Nolte, et al.,J. Chem. Crystallogr.,25, 425–427 (1995).

    Article  CAS  Google Scholar 

  19. D. V. Soldatov and J. Lipkowski,J. Incl. Phenom.,30, 99–109 (1998).

    Article  CAS  Google Scholar 

  20. P. Tomasik and Z. Ratajewicz, in:The Chemistry of Heterocyclic Compounds, Vol. 14, G. R. Newkome and L. Strekowski (eds.), Wiley, New York (1985), Part 6.

    Google Scholar 

  21. C. D. Burbridge and D. M. L. Goodgame,Inorg. Chim. Acta,4, 231–234 (1970).

    Article  CAS  Google Scholar 

  22. A. M. Golub, G. V. Tsintsadze, and A. M. Mamulashvili,Ukr. Khim. Zh.,36, 1207–1210 (1970).

    CAS  Google Scholar 

  23. A. H. Norbury, E. A. Ryder, and R. F. Williams,J. Chem. Soc. A, 1439–1441 (1967).

  24. W. D. Schaeffer, W. S. Dorsey, D. A. Skinner, and C. G. Christian,J. Am. Chem. Soc.,79, 5870–5876 (1957).

    Article  CAS  Google Scholar 

  25. T. L. Davis and A. V. Logon,ibid.,50, 2493–2499 (1928).

    Article  CAS  Google Scholar 

  26. D. V. Soldatov, V. A. Logvinenko, and Yu. A. Dyadin,Zh. Neorg. Khim.,40, 324–328 (1995).

    CAS  Google Scholar 

  27. F. Paulik and J. Paulik,J. Therm. Anal.,5, 253–270 (1973).

    Article  CAS  Google Scholar 

  28. V. A. Logvinenko, J. Paulik, and F. Paulik,Quasiequilibrium Themwgravimetry in Modem Inorganic Chemistry [in Russian], Nauka, Novosibirsk (1989).

    Google Scholar 

  29. G. M. Sheldrick,Acta Crystallogr.,A46, 467–473 (1990).

    CAS  Google Scholar 

  30. G. M. Sheldrick,ibid.,A49 (Suppl.), C53 (1993).

    Google Scholar 

  31. J. Lipkowski,J. Mol. Struct.,75, 13–28 (1981).

    Article  CAS  Google Scholar 

  32. J. Lipkowski and D. V. Soldatov,J. Coord. Chem.,28, 265–269 (1993).

    Article  CAS  Google Scholar 

  33. L. Sotofte and S. E. Rasmussen,Acta Chem. Scand.,21, 2028–2040 (1967).

    Article  Google Scholar 

  34. H. Hartl and I. Brugam,Acta Crystallogr.,B36, 162–165 (1980).

    Google Scholar 

  35. F. Valach, P. Sivy, and B. Koren,ibid.,C40, 957–959 (1984).

    CAS  Google Scholar 

  36. A. I. Kitaigorodskii,Molecular Crystals [in Russian], Nauka, Moscow (1971).

    Google Scholar 

  37. D. V. Soldatov, E. V. Grachev, and J. Lipkowski,Zh. Strukt. Khim.,37, 765–773 (1996).

    Google Scholar 

  38. J. Lipkowski, in:Inclusion Compounds, Vol. 1, Academic Press, London (1984), pp. 59–103.

    Google Scholar 

  39. V. A. Logvinenko and D. V. Soldatov,Zh. Strukt. Khim.,39, 756–760 (1998).

    Google Scholar 

  40. H. Irving and R. J. P. Williams,J. Chem. Soc, 3192–3210 (1953).

  41. Yu. A. Dyadin and N. V. Kislykh,Mendeleev Commun., 134–136 (1991).

  42. Yu. A. Dyadin, D. V. Soldatov, V. A. Logvinenko, and J. Lipkowski,J. Coord. Chem.,37, 63–75 (1996).

    Article  CAS  Google Scholar 

  43. J. Lipkowski and S. Majchrzak,Rocz. Chem.,49, 1655–1660 (1977).

    Google Scholar 

  44. G. D. Andreetti, G. Bocelli, and P. Sgarabotto,Cryst. Struct. Chem.,1, 51–54 (1972).

    Google Scholar 

  45. E. A. Ukraintseva, Yu. A. Dyadin, N. V. Kislykh, et al.,J. Incl. Phenom.,23, 23–33 (1995).

    Article  CAS  Google Scholar 

  46. J. Lipkowski, N. V. Kislykh, Yu. A. Dyadin, and L. A. Sheludyakova,Zh. Strukt. Khim.,40, No. 5, 954–963 (1999).

    Google Scholar 

  47. J. Lipkowski, D. V. Soldatov, N. V. Kislykh, et al.,J. Incl. Phenom.,17, 305–316 (1994).

    Article  CAS  Google Scholar 

  48. Yu. A. Dyadin, N. V. Kislykh, G. N. Chekhova, et al.,Izv. Sib. Otd. Akad. Nauk SSSR, Sei: Khim. Nauk, No. 2, 58–63 (1986).

  49. Yu. A. Dyadin, N. V. Kislykh, G. N. Chekhova, et al.,J. Incl. Phenom.,2, 333–340 (1984).

    Article  CAS  Google Scholar 

  50. E. A. Ukraintseva, D. V. Soldatov, and Yu. A. Dyadin,10th International Symposium on Molecular Recognition and Inclusion. Collected Abstracts, Warsaw, Poland (1998), pp. 4–8.

  51. E. A. Ukraintseva, D. V. Soldatov, V. A. Logvinenko, and Yu. A. Dyadin,Mendeleev Commun., 102–104 (1997).

  52. E. A. Ukraintseva, D. V. Soldatov, and Yu. A. Dyadin,Zh. Neorg. Khim.,42, 283–286 (1997).

    CAS  Google Scholar 

  53. D. V. Soldatov, Yu. A. Dyadin, E. A. Ukraintseva, et al.,J. Incl. Phenom.,26, 269–280 (1996).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    D. V. Soldatov, V. A. Logvinenko, Yu. A. Dyadin, J. Lipkowski & K. Suwinska

  2. Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland

    D. V. Soldatov, V. A. Logvinenko, Yu. A. Dyadin, J. Lipkowski & K. Suwinska

Authors
  1. D. V. Soldatov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Logvinenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Dyadin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. Lipkowski
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. K. Suwinska
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromZhurnal Strukturnoi Khimii, Vol. 40, No. 5, pp. 935–953, September–October, 1999.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Soldatov, D.V., Logvinenko, V.A., Dyadin, Y.A. et al. [MPy4(NCO)2]-2Py clathrates (M = M(II) = Mn, Fe, Co, Ni, Cu, Zn, Cd; Py = pyridine). J Struct Chem 40, 757–771 (1999). https://doi.org/10.1007/BF02903451

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02903451

Keywords

Search

Navigation