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Synthesis, spectroscopic characterization, and X-ray structure analysis of bis(2-amino-4-methylpyrimidin-1-ium) chloride tetrachloroantimonate(III) monohydrate [C5H8N3]2ClSbCl4·H2O

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Abstract

The synthesis, crystal structure, and characterization of a new organic–inorganic hybrid material with [C5H8N3]2ClSbCl4·H2O formula are described. The crystal structure refinement shows that this compound crystallizes in the monoclinic space group P21/m with the following unit cell dimensions: a = 5.6710(10) Å, b = 18.6279(2) Å, c = 9.0179(10) Å, β = 90.4480(10)°, V = 952.61(2) Å3, and Z = 2. The atomic arrangement of the title compound can be described by the three-dimensional network. The cohesion of compound entities is ensured by hydrogen bonding (N–H…Cl, OW–H…Cl, N–H…N, and C–H…Cl) and π–π interactions. The 13C CP-MAS-NMR spectrum shows five isotropic resonances, confirming the existence of five non-equivalent carbon atoms. This result is in good agreement with the X-ray single-crystal study. The infrared spectrum of this compound reported from 4,000 to 400 cm−1 confirmed the presence of the principal bands assigned to the internal modes of the organic cation.

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References

  1. Zhou Y, Qiao H (2007) Inorg Chem Commun 10:1318

    Article  CAS  Google Scholar 

  2. Khelifi M, Mkaouar I, Hlel F, Ben Salah A, Zouari R (2010) Ionics 16:709

  3. Wojtas M, Jakubas R, Ciunik Z, Medycki W (2004) J Solid State Chem 177:1575

    Article  CAS  Google Scholar 

  4. Bator G, Zeegers-Huyskens T, Jakubas R, Zaleski J (2001) J Mol Struct 570:6

    Article  Google Scholar 

  5. Kulicka B, Lis T, Kinzhybalo V, Jakubas R, Piecha A (2010) Polyhedron 29:2014

    Article  CAS  Google Scholar 

  6. Cantos G, Barbieri CL, Iacomini M, Gorin PA, Travassos LR (1993) Biochem J 289:155

    CAS  Google Scholar 

  7. Sing K, Sharma PK, Dubey SN, Tandon JP (1994) Indian J Chem 33A:266

    Google Scholar 

  8. Hu SZ, Lin WF (1989) Chin J Struct Chem 8:249

    CAS  Google Scholar 

  9. Köpf-Maier P, Klapötke T (1988) Inorg Chim Acta 152:49

    Article  Google Scholar 

  10. Rabie UM, Abou-El-Wafa MH, Mohamed RA (2007) J Mol Struct 87:6

    Article  Google Scholar 

  11. Rival Y, Grassy G, Taudou A, Ecalle R (1991) Eur J Med Chem 26:13

    Article  CAS  Google Scholar 

  12. Rahaman SA, Rajendra Pasad Y, Phani K, Bharath K (2009) Saudi Pharm J 17:255

  13. Quintero A, Pelcastre A, Solano JD (1999) J Pharm Pharmaceut Sci 2:108

    CAS  Google Scholar 

  14. El-Gazzar A-RBA, Hussein HAR, Hafez HNH (2007) Acta Pharm 5:395

    Google Scholar 

  15. Bujak M, Zaleski J (2003) J Mol Struct 647:121

    Article  CAS  Google Scholar 

  16. Weslati N, Chaabane I, Bulou A, Hlel F (2014) Phys B 441:42

    Article  CAS  Google Scholar 

  17. Li L, Wang G-X (2010) Acta Cryst E66:m1629

  18. Bujak M, Zaleski J (2003) J Mol Struct 647:121

    Article  CAS  Google Scholar 

  19. Thomas SP, Sunkari J (2013) Acta Cryst E69:o529

    Google Scholar 

  20. Yan X-C, Fan Y-H, Bi C-F, Zhang X, Zhang Z-Y (2013) Acta Cryst C69:61

    Google Scholar 

  21. Panneerselvam P, Muthiah PT, Francis S (2004) Acta Cryst E60:o747

    Google Scholar 

  22. Elboulali A, Toumi Akriche S, Al-Deyab S, Rzaigui M (2011) Acta Cryst E67:o1013

  23. Quesada A, Marchal A, Melguizo M, Low JN, Glidewell C (2004) Acta Cryst B60:76

    Article  CAS  Google Scholar 

  24. Low JN, Cannon D, Quesada A, Marchal A, Melguizo M, Nogueras M, Sanchez A, Glidewell C (2001) Acta Cryst C57:604

    CAS  Google Scholar 

  25. Janiak C (2000) J Chem Soc Dalton Trans 3885

  26. Nakamoto K (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th edn. John Wiley & Sons, New York, p 279

    Google Scholar 

  27. Bayrak C (1986) J Biol Chem 41:133

    Google Scholar 

  28. Sheldrick GM (2008) Acta Cryst A64:112

    Article  Google Scholar 

  29. Farrugia LJ (1999) J Appl Cryst 32:837

    Article  CAS  Google Scholar 

  30. Farrugia LJ (1997) J Appl Cryst 30:565

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Tunisian Ministry of H. E. Sc. R.

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, Zarzouna, 7021, Tunisie

    Zouhaier Aloui, Manel Essid, Sonia Abid, Mohamed Rzaigui & Chérif Ben Nasr

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  1. Zouhaier Aloui
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  2. Manel Essid
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  3. Sonia Abid
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  4. Mohamed Rzaigui
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  5. Chérif Ben Nasr
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Correspondence to Zouhaier Aloui.

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Aloui, Z., Essid, M., Abid, S. et al. Synthesis, spectroscopic characterization, and X-ray structure analysis of bis(2-amino-4-methylpyrimidin-1-ium) chloride tetrachloroantimonate(III) monohydrate [C5H8N3]2ClSbCl4·H2O. Monatsh Chem 146, 1465–1471 (2015). https://doi.org/10.1007/s00706-015-1422-y

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