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Crystal and molecular structure of tetrapyridyl-copper(II)-bis-nitrato-bis-pyridine

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Abstract

The crystal and molecular structure of a pyridine complex of anhydrous copper(II)nitrate is described. The structure has been solved by vector search methods and refined by least-squares methods to R1=0.049 [I>2σ(I)]. The complex lies on a twofold axis parallel toa, and two solvent pyridine molecules lie on twofold axes parallel toc. The copper atom is coordinated by four pyridyl groups and two monodentate NO3 groups. Crystal data: C30H30N8O6Cu, orthorhombic, space group Pnna(52),a=14.446(7),b=12.154(5),c=16.881(4) Å,V=2964(2) Å3,Z=4.

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References

  1. Biagetti, R.V.; Bottjer, W.G.; Haendler, H.M.Inorg. Chem. 1966,5, 379.

    Google Scholar 

  2. Beurskens, P.T.; Beurskens, G.; Strumpel, M.; Nordman, C.E.Patterson and Pattersons, Glusker, J.P.; Patterson, B.K.; Rossi, M. Eds.; Oxford, Clarendon Press: Oxford, 1987; p 356.

    Google Scholar 

  3. Motherwell, W.D.S.PLUTO, A Program for Plotting Molecular and Crystal Structures; University Chemical Laboratory: Cambridge, England, 1976.

    Google Scholar 

  4. Motherwell, W.D.S.GEOM, A Program for Geometrical Calculations; University Chemical Laboratory: Cambridge, England, 1976.

    Google Scholar 

  5. Beurskens, P.T.; Admiraal, G.; Beurskens, G.; Bosman, W.P.; Garcia-Granda, S.; Gould, R.O.; Smits, J.M.M.; Smykalla, C.The DIRDIF program system; Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1992.

    Google Scholar 

  6. Sheldrick, G.M.SHELXL-93. Program for the Refinement of Crystal Structures; Univ. of Goettingen, Germany, 1993.

    Google Scholar 

  7. Walker, N.; Stuart, D.Acta. Cryst. 1983,A39, 158.

    Google Scholar 

  8. International Tables for X-ray Crystallography, Vol. IV; Birmingham: Kynoch Press, 1974.

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Authors and Affiliations

  1. Crystallography Laboratory, University of Nijmegen, Toernooiveld, 6525 ED, Nijmegen, The Netherlands

    Gezina Beurskens, Paul T. Beurskens & J. M. M. Smits

  2. Department of Organic Chemistry, University of Nijmegen, Toernooiveld, 6525 ED, Nijmegen, The Netherlands

    C. F. Martens & R. J. M. Nolte

Authors
  1. Gezina Beurskens
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  2. C. F. Martens
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  3. R. J. M. Nolte
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  4. Paul T. Beurskens
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  5. J. M. M. Smits
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Beurskens, G., Martens, C.F., Nolte, R.J.M. et al. Crystal and molecular structure of tetrapyridyl-copper(II)-bis-nitrato-bis-pyridine. J Chem Crystallogr 25, 425–427 (1995). https://doi.org/10.1007/BF01665282

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  • DOI: https://doi.org/10.1007/BF01665282

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