Abstract
As a sort of porous material with periodic network structure, metal–organic framework (MOF) is constructed with metal ions or clusters and organic ligands. Benefiting from the adjustable channel structure, abundant unsaturated metal sites and modifiable ligands, MOF has attracted more and more attention both from science and engineering perspectives in various fields. Although their intrinsic micropores endow size-selective capability and high surface area, etc., the narrow pores limit their applications toward diffusion-control and large size species involved processes. In recent years, the construction of mixed-metal MOFs and MOF films has captured widespread interest which extend the applications of conventional MOF-based materials. In this review, the advances in the design, synthesis, and functional applications of nanomaterials derived from MOF-based porous materials are summarized. Their structural characters toward applications of pollutant removal, including heavy metals, antibiotics, dyes, and some emerging pollutants from aqueous solutions, have been demonstrated with typical reports. The subsisting challenges as well as future perspectives in this research field are also indicated.
Graphical Abstract
Nanomaterials derived from MOFs for pollutants removal.
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References
Abdelhamid HN, Mathew AP (2022) Cellulose-metal organic frameworks (CelloMOFs) hybrid materials and their multifaceted applications: a review. Coord Chem Rev 451:214263. https://doi.org/10.1016/j.ccr.2021.214263
Abdelhamid HN, Georgouvelas D, Edlund U et al (2022) CelloZIFPaper: cellulose-ZIF hybrid paper for heavy metal removal and electrochemical sensing. Chem Eng J 446:136614. https://doi.org/10.1016/j.cej.2022.136614
Abdelmoaty AS, El-Wakeel ST, Fathy N et al (2022) High performance of UiO-66 metal-organic framework modified with melamine for uptaking of lead and cadmium from aqueous solutions. J Inorg Organomet Polym Mater 32:2557–2567. https://doi.org/10.1007/s10904-022-02326-9
Abednatanzi S, Gohari DP, Depauw H et al (2019) Mixed-metal metal-organic frameworks. Chem Soc Rev 48:2535–2565. https://doi.org/10.1039/C8CS00337H
Ahmadijokani F, Tajahmadi S, Bahi A et al (2021) Ethylenediamine-functionalized Zr-based MOF for efficient removal of heavy metal ions from water. Chemosphere 264:128466. https://doi.org/10.1016/j.chemosphere.2020.128466
Aijaz A, Xu Q (2014) Catalysis with metal nanoparticles immobilized within the pores of metal-organic frameworks. J Phys Chem Lett 5:1400–1411. https://doi.org/10.1021/jz5004044
Aijaz A, Karkamkar A, Choi YJ et al (2012) Immobilizing highly catalytically active Pt nanoparticles inside the pores of metal-organic framework: a double solvents approach. J Am Chem Soc 134:13926–13929. https://doi.org/10.1021/ja3043905
Aijaz A, Akita T, Tsumori N et al (2013) Metal-organic framework-immobilized polyhedral metal nanocrystals: reduction at solid-gas interface, metal segregation, core-shell structure, and high catalytic activity. J Am Chem Soc 135:16356–16359. https://doi.org/10.1021/ja4093055
Akha NZ, Salehi S, Anbia M (2022) Removal of arsenic by metal organic framework/chitosan/carbon nanocomposites: modeling, optimization, and adsorption studies. Int J Biol Macromol 208:794–808. https://doi.org/10.1016/j.ijbiomac.2022.03.161
Ali H, Khan E, Ilahi I (2019) Environmental chemistry and ecotoxicology of hazardous heavy metals: environmental persistence, toxicity, and bioaccumulation. J Chem 2019:6730305. https://doi.org/10.1155/2019/6730305
Al-Wafi R, Ahmed MK, Mansour SF (2020) Tuning the synthetic conditions of graphene oxide/magnetite/hydroxyapatite/cellulose acetate nanofibrous membranes for removing Cr(VI), Se(IV) and methylene blue from aqueous solutions. J Water Process Eng 38:101543. https://doi.org/10.1016/j.jwpe.2020.101543
Ameloot R, Gobechiya E, Uji-i H et al (2010) Direct patterning of oriented metal-organic framework crystals via control over crystallization kinetics in clear precursor solutions. Adv Mater 22:2685–2688. https://doi.org/10.1002/adma.200903867
An J, Geib SJ, Rosi NL (2010) High and selective CO2 uptake in a cobalt adeninate metal-organic framework exhibiting pyrimidine- and amino-decorated pores. J Am Chem Soc 132:38–39. https://doi.org/10.1021/ja909169x
Arya K, Kumar A, Mehra S et al (2023) Exploration and removal of multiple metal ions using mixed-linker-architected Zn-MOF in aqueous media. Sep Purif Technol 307:122551. https://doi.org/10.1016/j.seppur.2022.122551
Bae YS, Lee CY, Kim KC et al (2012) High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites. Angew Chem Int Ed 51:1857–1860. https://doi.org/10.1002/anie.201107534
Banerjee R, Phan A, Wang B et al (2008) High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science 319:939–943. https://doi.org/10.1126/science.1152516
Barthelet K, Marrot J, Riou D et al (2002) A breathing hybrid organic-inorganic solid with very large pores and high magnetic characteristics. Angew Chem Int Ed 41:281–284. https://doi.org/10.1002/1521-3773(20020118)41:2%3c281::AID-ANIE281%3e3.0.CO;2-Y
Batten SR, Champness NR, Chen XM et al (2013) Terminology of metal-organic frameworks and coordination polymers (IUPAC recommendations 2013). Pure Appl Chem 85:1715–1724. https://doi.org/10.1351/PAC-REC-12-11-20
Bell CM, Arendt MF, Gomez L et al (1994) Growth of lamellar Hofmann clathrate films by sequential ligand exchange reactions: assembling a coordination solid one layer at a time. J Am Chem Soc 116:8374–8375. https://doi.org/10.1021/ja00097a058
Betard A, Fischer RA (2012) Metal-organic framework thin films: from fundamentals to applications. Chem Rev 112:1055–1083. https://doi.org/10.1021/cr200167v
Bloch ED, Britt D, Lee C et al (2010) Metal insertion in a microporous metal-organic framework lined with 2, 2′-bipyridine. J Am Chem Soc 132:14382–14384. https://doi.org/10.1021/ja106935d
Brozek CK, Dincă M (2013) Ti3+-, V2+/3+-, Cr2+/3+-, Mn2+-, and Fe2+-substituted MOF-5 and redox reactivity in Cr- and Fe-MOF-5. J Am Chem Soc 135:12886–12891. https://doi.org/10.1021/ja4064475
Bruno R, Mon M, Escamilla P et al (2021) Bioinspired metal-organic frameworks in mixed matrix membranes for efficient static/dynamic removal of mercury from water. Adv Funct Mater 31:2008499. https://doi.org/10.1002/adfm.202008499
Cao S, Li B, Zhu R et al (2019) Design and synthesis of covalent organic frameworks towards energy and environment fields. Chem Eng J 355:602–623. https://doi.org/10.1016/j.cej.2018.08.184
Caskey SR, Matzger AJ (2008) Selective metal substitution for the preparation of heterobimetallic microporous coordination polymers. Inorg Chem 47:7942–7944. https://doi.org/10.1021/ic8007427
Cavka JH, Jakobsen S, Olsbye U et al (2008) A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J Am Chem Soc 130:13850–13851. https://doi.org/10.1021/ja8057953
Chen B, Xiang S, Qian G (2010) Metal-organic frameworks with functional pores for recognition of small molecules. Acc Chem Res 43:1115–1124. https://doi.org/10.1021/ar100023y
Chen L, Chen H, Li Y (2014a) One-pot synthesis of Pd@MOF composites without the addition of stabilizing agents. Chem Commun 50:14752–14755. https://doi.org/10.1039/C4CC06568A
Chen L, Chen H, Luque R et al (2014b) Metal-organic framework encapsulated Pd nanoparticles: towards advanced heterogeneous catalysts. Chem Sci 5:3708–3714. https://doi.org/10.1039/C4SC01847H
Chen L, Huang B, Qiu X et al (2016) Seed-mediated growth of MOF-encapsulated Pd@Ag core-shell nanoparticles: toward advanced room temperature nanocatalysts. Chem Sci 7:228–233. https://doi.org/10.1039/C5SC02925B
Chen L, Luque R, Li Y (2017) Controllable design of tunable nanostructures inside metal-organic frameworks. Chem Soc Rev 46:4614–4630. https://doi.org/10.1039/C6CS00537C
Chen X, Qian P, Zhang T et al (2018) Catalyst surfaces with tunable hydrophilicity and hydrophobicity: metal-organic frameworks toward controllable catalytic selectivity. Chem Commun 54:3936–3939. https://doi.org/10.1039/C8CC00318A
Chen J, Ouyang J, Chen W et al (2022) Fabrication and adsorption mechanism of chitosan/Zr-MOF (UiO-66) composite foams for efficient removal of ketoprofen from aqueous solution. Chem Eng J 431:134045. https://doi.org/10.1016/j.cej.2021.134045
Chen Z, Li Y, Cai Y et al (2023) Application of covalent organic frameworks and metal-organic frameworks nanomaterials in organic/inorganic pollutants removal from solutions through sorption-catalysis strategies. Carbon Res 2:8. https://doi.org/10.1007/s44246-023-00041-9
Cho HY, Yang DA, Kim J et al (2012) CO2 adsorption and catalytic application of Co-MOF-74 synthesized by microwave heating. Catal Today 185:35–40. https://doi.org/10.1016/j.cattod.2011.08.019
Choi KM, Jeong HM, Park JH et al (2014) Supercapacitors of nanocrystalline metal-organic frameworks. ACS Nano 8:7451–7457. https://doi.org/10.1021/nn5027092
Chui SSY, Lo SMF, Charmant JPH et al (1999) A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n. Science 283:1148–1150. https://doi.org/10.1126/science.283.5405.1148
Chun J, Kang S, Park N et al (2014) Metal-organic framework@microporous organic network: hydrophobic adsorbents with a crystalline inner porosity. J Am Chem Soc 136:6786–6789. https://doi.org/10.1021/ja500362w
Cobo S, Molnár G, Real JA et al (2006) Multilayer sequential assembly of thin films that display room-temperature spin crossover with hysteresis. Angew Chem 118:5918–5921. https://doi.org/10.1002/ange.200601885
Daradmare S, Xia M, Le VN et al (2021) Metal-organic frameworks/alginate composite beads as effective adsorbents for the removal of hexavalent chromium from aqueous solution. Chemosphere 270:129487. https://doi.org/10.1016/j.chemosphere.2020.129487
Das S, Kim H, Kim K (2009) Metathesis in single crystal: complete and reversible exchange of metal ions constituting the frameworks of metal-organic frameworks. J Am Chem Soc 131:3814–3815. https://doi.org/10.1021/ja808995d
Das MC, Xiang S, Zhang Z et al (2011) Functional mixed metal-organic frameworks with metalloligands. Angew Chem Int Ed 50:10510–10520. https://doi.org/10.1002/anie.201101534
Das MC, Guo Q, He Y et al (2012) Interplay of metalloligand and organic ligand to tune micropores within isostructural mixed-metal organic frameworks (M′MOFs) for their highly selective separation of chiral and achiral small molecules. J Am Chem Soc 134:8703–8710. https://doi.org/10.1021/ja302380x
Deng H, Grunder S, Cordova KE et al (2012) Large-pore apertures in a series of metal-organic frameworks. Science 336:1018–1023. https://doi.org/10.1126/science.1220131
Deng Z, Sun S, Li H et al (2021) Modification of coconut shell-based activated carbon and purification of wastewater. Adv Compos Hybrid Mater 4:65–73. https://doi.org/10.1007/s42114-021-00205-4
Deria P, Mondloch JE, Karagiaridi O et al (2014) Beyond post-synthesis modification: evolution of metal-organic frameworks via building block replacement. Chem Soc Rev 43:5896–5912. https://doi.org/10.1039/C4CS00067F
Dhara B, Nagarkar SS, Kumar J et al (2016) Increase in electrical conductivity of MOF to billion-fold upon filling the nanochannels with conducting polymer. J Phys Chem Lett 7:2945–2950. https://doi.org/10.1021/acs.jpclett.6b01236
Dietzel PDC, Besikiotis V, Blom R (2009) Application of metal-organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide. J Mater Chem 19:7362–7370. https://doi.org/10.1039/B911242A
Dong X, Li Y, Li D et al (2022) A new 3D 8-connected Cd(II) MOF as a potent photocatalyst for oxytetracycline antibiotic degradation. CrystEngComm 24:6933–6943. https://doi.org/10.1039/D2CE01121B
Eddaoudi M, Kim J, Rosi N et al (2002) Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science 295:469–472. https://doi.org/10.1126/science.1067208
Falcaro P, Hill AJ, Nairn KM et al (2011) A new method to position and functionalize metal-organic framework crystals. Nat Commun 2:237. https://doi.org/10.1038/ncomms1234
Fan G, Zhou J, Zheng X et al (2020) Fast photocatalytic inactivation of microcystis aeruginosa by metal-organic frameworks under visible light. Chemosphere 239:124721. https://doi.org/10.1016/j.chemosphere.2019.124721
Farha OK, Eryazici I, Jeong NC et al (2012) Metal-Organic framework materials with ultrahigh surface areas: is the sky the limit? J Am Chem Soc 134:15016–15021. https://doi.org/10.1021/ja3055639
Feng R, Jia YY, Li ZY et al (2018) Enhancing the stability and porosity of penetrated metal-organic frameworks through the insertion of coordination sites. Chem Sci 9:950–955. https://doi.org/10.1039/C7SC04192F
Férey G, Latroche M, Serre C et al (2003) Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C–C6H4-CO2) (M = Al3+, Cr3+), MIL-53. Chem Commun. https://doi.org/10.1039/B308903G
Férey G, Serre C, Mellot-Draznieks C et al (2004) A hybrid solid with giant pores prepared by a combination of targeted chemistry, simulation, and powder diffraction. Angew Chem Int Ed 43:6296–6301. https://doi.org/10.1002/anie.200460592
Férey G, Mellot-Draznieks C, Serre C et al (2005) A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309:2040–2042. https://doi.org/10.1126/science.1116275
Fracaroli AM, Siman P, Nagib DA et al (2016) Seven post-synthetic covalent reactions in tandem leading to enzyme-like complexity within metal-organic framework crystals. J Am Chem Soc 138:8352–8355. https://doi.org/10.1021/jacs.6b04204
Fu J, Das S, Xing G et al (2016) Fabrication of COF-MOF composite membranes and their highly selective separation of H2/CO2. J Am Chem Soc 138:7673–7680. https://doi.org/10.1021/jacs.6b03348
Fu L, Wang S, Lin G et al (2019) Post-modification of UiO-66-NH2 by resorcyl aldehyde for selective removal of Pb(II) in aqueous media. J Cleaner Prod 229:470–479. https://doi.org/10.1016/j.jclepro.2019.05.043
Fu K, Liu X, Lv C et al (2022) Superselective Hg(II) removal from water using a thiol-laced MOF-based sponge monolith: performance and mechanism. Environ Sci Technol 56:2677–2688. https://doi.org/10.1021/acs.est.1c07480
Furukawa H, Cordova KE, O’Keeffe M et al (2013) The chemistry and applications of metal-organic frameworks. Science 341:1230444. https://doi.org/10.1126/science.1230444
Furukawa H, Müller U, Yaghi OM (2015) “Heterogeneity within order” in metal-organic frameworks. Angew Chem Int Ed 54:3417–3430. https://doi.org/10.1002/anie.201410252
Gamage NDH, McDonald KA, Matzger AJ (2016) MOF-5-polystyrene: direct production from monomer, improved hydrolytic stability, and unique guest adsorption. Angew Chem Int Ed 55:12099–12103. https://doi.org/10.1002/anie.201606926
Gascon J, Aguado S, Kapteijn F (2008) Manufacture of dense coatings of Cu3(BTC)2(HKUST-1) on α-alumina. Microporous Mesoporous Mater 113:132–138. https://doi.org/10.1016/j.micromeso.2007.11.014
Ge D, Qu G, Li X et al (2016) Novel transition bimetal-organic frameworks: recyclable catalyst for the oxidative coupling of primary amines to imines at mild conditions. New J Chem 40:5531–5536. https://doi.org/10.1039/C5NJ03544A
Giménez-Marqués M, Bellido E, Berthelot T et al (2018) GraftFast surface engineering to improve MOF nanoparticles furtiveness. Small 14:1801900. https://doi.org/10.1002/smll.201801900
Gonzalez MI, Bloch ED, Mason JA et al (2015) Single-crystal-to-single-crystal metalation of a metal-organic framework: a route toward structurally well-defined catalysts. Inorg Chem 54:2995–3005. https://doi.org/10.1021/acs.inorgchem.5b00096
Gu X, Lu ZH, Jiang HL et al (2011) Synergistic catalysis of metal-organic framework-immobilized Au-Pd nanoparticles in dehydrogenation of formic acid for chemical hydrogen storage. J Am Chem Soc 133:11822–11825. https://doi.org/10.1021/ja200122f
Gu H, Liu X, Wang S et al (2022) COF-based composites: extraordinary removal performance for heavy metals and radionuclides from aqueous solutions. Rev Environ Contam Toxicol 260:23. https://doi.org/10.1007/s44169-022-00018-6
Guerrero VV, Yoo Y, McCarthy MC et al (2010) HKUST-1 membranes on porous supports using secondary growth. J Mater Chem 20:3938–3943. https://doi.org/10.1039/B924536G
Guo H, Zhu G, Hewitt IJ et al (2009) “Twin copper source” growth of metal-organic framework membrane: Cu3(BTC)2 with high permeability and selectivity for recycling H2. J Am Chem Soc 131:1646–1647. https://doi.org/10.1021/ja8074874
Guo Z, Yang F, Yang R et al (2021) Preparation of novel ZnO-NP@Zn-MOF-74 composites for simultaneous removal of copper and tetracycline from aqueous solution. Sep Purif Technol 274:118949. https://doi.org/10.1016/j.seppur.2021.118949
Guo J, Xue X, Yu H et al (2022) Metal-organic frameworks based on infinite secondary building units: recent progress and future outlooks. J Mater Chem A 10:19320–19347. https://doi.org/10.1039/D2TA03159K
Guo J, Duan Y, Jia Y et al (2024) Biomimetic chiral hydrogen-bonded organic-inorganic frameworks. Nat Commun 15:139. https://doi.org/10.1038/s41467-023-43700-6
Halper SR, Cohen SM (2005) Heterometallic metal-organic frameworks based on tris(dipyrrinato) coordination complexes. Inorg Chem 44:486–488. https://doi.org/10.1021/ic048289z
Halper SR, Do L, Stork JR et al (2006) Topological control in heterometallic metal-organic frameworks by anion templating and metalloligand design. J Am Chem Soc 128:15255–15268. https://doi.org/10.1021/ja0645483
Hao M, Liu Y, Wu W et al (2023) Advanced porous adsorbents for radionuclides elimination. EnergyChem 5:100101. https://doi.org/10.1016/j.enchem.2023.100101
Hao M, Xie Y, Lei M et al (2024) Pore space partition synthetic strategy in imine-linked multivariate covalent organic frameworks. J Am Chem Soc 146:1904–1913. https://doi.org/10.1021/jacs.3c08160
He J, Yu J, Zhang Y et al (2005) Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks. Inorg Chem 44:9279–9282. https://doi.org/10.1021/ic051143v
He L, Liu Y, Liu J et al (2013) Core-shell noble-metal@metal-organic-framework nanoparticles with highly selective sensing property. Angew Chem Int Ed 52:3741–3745. https://doi.org/10.1002/anie.201209903
Hu Y, Dong X, Nan J et al (2011) Metal-organic framework membranes fabricated via reactive seeding. Chem Commun 47:737–739. https://doi.org/10.1039/C0CC03927F
Huang G, Yang Q, Xu Q et al (2016a) Polydimethylsiloxane coating for a palladium/MOF composite: highly improved catalytic performance by surface hydrophobization. Angew Chem 128:7505–7509. https://doi.org/10.1002/ange.201600497
Huang L, He M, Chen B et al (2016b) A mercapto functionalized magnetic Zr-MOF by solvent-assisted ligand exchange for Hg2+ removal from water. J Mater Chem A 4:5159–5166. https://doi.org/10.1039/c6ta00343e
Huang YB, Liang J, Wang XS et al (2017) Multifunctional metal-organic framework catalysts: synergistic catalysis and tandem reactions. Chem Soc Rev 46:126–157. https://doi.org/10.1039/C6CS00250A
Huang N, Drake H, Li J et al (2018) Flexible and hierarchical metal-organic framework composites for high-performance catalysis. Angew Chem Int Ed 57:8916–8920. https://doi.org/10.1002/anie.201803096
Huang Z, Zhao M, Wang C et al (2020) Preparation of a novel Zn(II)-imidazole framework as an efficient and regenerative adsorbent for Pb, Hg, and As ion removal from water. ACS Appl Mater Interfaces 12:41294–41302. https://doi.org/10.1021/acsami.0c10298
Ji C, Ren Y, Yu H et al (2022) Highly efficient and selective Hg(II) removal from water by thiol-functionalized MOF-808: kinetic and mechanism study. Chem Eng J 430:132960. https://doi.org/10.1016/j.cej.2021.132960
Jiang HL, Akita T, Ishida T et al (2011) Synergistic catalysis of Au@Ag core-shell nanoparticles stabilized on metal-organic framework. J Am Chem Soc 133:1304–1306. https://doi.org/10.1021/ja1099006
Jing C, Zhang Y, Zheng J et al (2022) In-situ constructing visible light CdS/Cd-MOF photocatalyst with enhanced photodegradation of methylene blue. Particuology 69:111–122. https://doi.org/10.1016/j.partic.2021.11.013
Julien PA, Mottillo C, Friščić T (2017) Metal-organic frameworks meet scalable and sustainable synthesis. Green Chem 19:2729–2747. https://doi.org/10.1039/C7GC01078H
Kalaj M, Denny MS Jr, Bentz KC et al (2019) Nylon-MOF composites through postsynthetic polymerization. Angew Chem 131:2358–2362. https://doi.org/10.1002/ange.201812655
Katsoulidis AP, Park KS, Antypov D et al (2014) Guest-adaptable and water-stable peptide-based porous materials by imidazolate side chain control. Angew Chem Int Ed 53:193–198. https://doi.org/10.1002/anie.201307074
Ke F, Qiu LG, Yuan YP et al (2011) Thiol-functionalization of metal-organic framework by a facile coordination-based postsynthetic strategy and enhanced removal of Hg2+ from water. J Hazard 196:36–43. https://doi.org/10.1016/j.jhazmat.2011.08.069
Khaletskaya K, Reboul J, Meilikhov M et al (2013) Integration of porous coordination polymers and gold nanorods into core-shell mesoscopic composites toward light-induced molecular release. J Am Chem Soc 135:10998–11005. https://doi.org/10.1021/ja403108x
Kidanemariam A, Park J (2021) Metal-organic framework based on Co and 4,4′-dimethylenebiphenyl diphosphonic acid as an efficient methylene blue adsorbent. J Ind Eng Chem 104:61–72. https://doi.org/10.1016/j.jiec.2021.08.010
Kim D, Coskun A (2017) Template-directed approach towards the realization of ordered heterogeneity in bimetallic metal-organic frameworks. Angew Chem Int Ed 56:5071–5076. https://doi.org/10.1002/anie.201702501
Kim M, Cahill JF, Fei H et al (2012) Postsynthetic ligand and cation exchange in robust metal-organic frameworks. J Am Chem Soc 134:18082–18088. https://doi.org/10.1021/ja3079219
Kim CR, Uemura T, Kitagawa S (2016) Inorganic nanoparticles in porous coordination polymers. Chem Soc Rev 45:3828–3845. https://doi.org/10.1039/C5CS00940E
Kim N, Cha B, Yea Y et al (2022) Effective sequestration of tetracycline and ciprofloxacin from aqueous solutions by Al-based metal organic framework and reduced graphene oxide immobilized alginate biosorbents. Chem Eng J 450:138068. https://doi.org/10.1016/j.cej.2022.138068
Kitagawa S, Kitaura R, Noro SI (2004) Functional porous coordination polymers. Angew Chem Int Ed 43:2334–2375. https://doi.org/10.1002/anie.200300610
Kitao T, Zhang Y, Kitagawa S et al (2017) Hybridization of MOFs and polymers. Chem Soc Rev 46:3108–3133. https://doi.org/10.1039/C7CS00041C
Klein N, Senkovska I, Gedrich K et al (2009) A mesoporous metal-organic framework. Angew Chem Int Ed 48:9954–9957. https://doi.org/10.1002/anie.200904599
Kong XJ, Ren YP, Long LS et al (2008) Influence of reaction conditions on the channel shape of 3d–4f heterometallic metal-organic framework. CrystEngComm 10:1309–1314. https://doi.org/10.1039/B804966A
Kumar A, Amit K, Cabral-Pinto MMS et al (2020) Lead toxicity: health hazards, influence on food chain, and sustainable remediation approaches. Int J Environ Res Public Health. https://doi.org/10.3390/ijerph17072179
Kuo CH, Tang Y, Chou LY et al (2012) Yolk-shell nanocrystal@ZIF-8 nanostructures for gas-phase heterogeneous catalysis with selectivity control. J Am Chem Soc 134:14345–14348. https://doi.org/10.1021/ja306869j
Lalonde M, Bury W, Karagiaridi O et al (2013) Transmetalation: routes to metal exchange within metal-organic frameworks. J Mater Chem A 1:5453–5468. https://doi.org/10.1039/C3TA10784A
Lammert M, Glißmann C, Stock N (2017) Tuning the stability of bimetallic Ce(IV)/Zr(IV)-based MOFs with UiO-66 and MOF-808 structures. Dalton Trans 46:2425–2429. https://doi.org/10.1039/C7DT00259A
Lau CH, Babarao R, Hill MR (2013) A route to drastic increase of CO2 uptake in Zr metal organic framework UiO-66. Chem Commun 49:3634–3636. https://doi.org/10.1039/c3cc40470f
Le Ouay B, Watanabe C, Mochizuki S et al (2018) Selective sorting of polymers with different terminal groups using metal-organic frameworks. Nat Commun 9:3635. https://doi.org/10.1038/s41467-018-06099-z
Lee JS, Vlaisavljevich B, Britt DK et al (2015) Understanding small-molecule interactions in metal-organic frameworks: coupling experiment with theory. Adv Mater 27:5785–5796. https://doi.org/10.1002/adma.201500966
Li S, Huo F (2015) Metal-organic framework composites: from fundamentals to applications. Nanoscale 7:7482–7501. https://doi.org/10.1039/c5nr00518c
Li Y, Yang RT (2006) Significantly enhanced hydrogen storage in metal-organic frameworks via spillover. J Am Chem Soc 128:726–727. https://doi.org/10.1021/ja056831s
Li Z, Zeng HC (2013) Surface and bulk integrations of single-layered Au or Ag nanoparticles onto designated crystal planes 110 or 100 of ZIF-8. Chem Mater 25:1761–1768. https://doi.org/10.1021/cm400260g
Li B, Xie Y, Huang J et al (1999) Synthesis by a solvothermal route and characterization of CuInSe2 nanowhiskers and nanoparticles. Adv Mater 11:1456–1459. https://doi.org/10.1002/(SICI)1521-4095(199912)11:17%3c1456::AID-ADMA1456%3e3.0.CO;2-3
Li YS, Bux H, Feldhoff A et al (2010) Controllable synthesis of metal-organic frameworks: from MOF nanorods to oriented MOF membranes. Adv Mater 22:3322–3326. https://doi.org/10.1002/adma.201000857
Li WJ, Liu J, Sun ZH et al (2016a) Integration of metal-organic frameworks into an electrochemical dielectric thin film for electronic applications. Nat Commun 7:11830. https://doi.org/10.1038/ncomms11830
Li Z, Xiao JD, Jiang HL (2016b) Encapsulating a Co(II) molecular photocatalyst in metal-organic framework for visible-light-driven H2 production: boosting catalytic efficiency via spatial charge separation. ACS Catal 6:5359–5365. https://doi.org/10.1021/acscatal.6b01293
Li L, Xu Y, Zhong D et al (2020a) CTAB-surface-functionalized magnetic MOF@MOF composite adsorbent for Cr(VI) efficient removal from aqueous solution. Colloids Surf A 586:124255. https://doi.org/10.1016/j.colsurfa.2019.124255
Li WT, Shi W, Hu ZJ (2020b) Fabrication of magnetic Fe3O4@metal organic framework@covalent organic framework composite and its selective separation of trace copper. Appl Surf Sci 530:147254. https://doi.org/10.1016/j.apsusc.2020.147254
Li L, Yang L, Zou R et al (2021) Facile and scalable preparation of ZIF-67 decorated cotton fibers as recoverable and efficient adsorbents for removal of malachite green. J Leather Sci Eng 3:28. https://doi.org/10.1186/s42825-021-00069-w
Li Z, Yao B, Cheng C et al (2023) Versatile structural engineering of metal-organic frameworks enabling switchable catalytic selectivity. Adv Mater. https://doi.org/10.1002/adma.202308427
Li F, Duan Y, Li J et al (2024a) Recent advances of chiral metal-organic frameworks in analytic chemistry. TrAC Trends Anal Chem 170:117471. https://doi.org/10.1016/j.trac.2023.117471
Li Y, Wang S, Wang X (2024b) Highly selective removal of U(VI) from aqueous solutions by porous nanomaterials. EcoEnergy. https://doi.org/10.1002/ece2.35
Lin Q, Bu X, Kong A et al (2015) New heterometallic zirconium metalloporphyrin frameworks and their heteroatom-activated high-surface-area carbon derivatives. J Am Chem Soc 137:2235–2238. https://doi.org/10.1021/jacs.5b00076
Liu Y, Tang Z (2013) Multifunctional nanoparticle@MOF core-shell nanostructures. Adv Mater 25:5819–5825. https://doi.org/10.1002/adma.201302781
Liu H, Chang L, Bai C et al (2016a) Controllable encapsulation of “clean” metal clusters within MOFs through kinetic modulation: towards advanced heterogeneous nanocatalysts. Angew Chem Int Ed 55:5019–5023. https://doi.org/10.1002/anie.201511009
Liu Q, Cong H, Deng H (2016b) Deciphering the spatial arrangement of metals and correlation to reactivity in multivariate metal-organic frameworks. J Am Chem Soc 138:13822–13825. https://doi.org/10.1021/jacs.6b08724
Liu A, Wang CC, Wang CZ et al (2018a) Selective adsorption activities toward organic dyes and antibacterial performance of silver-based coordination polymers. J Colloid Interface Sci 512:730–739. https://doi.org/10.1016/j.jcis.2017.10.099
Liu A, Wang CZ, Chu C et al (2018b) Adsorption performance toward organic pollutants, odour control and anti-microbial activities of one Ag-based coordination polymer. J Environ Chem Eng 6:4961–4969. https://doi.org/10.1016/j.jece.2018.07.035
Liu YQ, Song CG, Ding G et al (2022) High-performance functional Fe-MOF for removing aflatoxin B1 and other organic pollutants. Adv Mater Interfaces 9:2196–7350. https://doi.org/10.1002/admi.202102480
Liu X, Li Y, Tan C et al (2023) Highly selective extraction of U(VI) from solutions by metal organic framework-based nanomaterials through sorption, photochemistry and electrochemistry strategies. Langmuir 39:18696–18712. https://doi.org/10.1021/acs.langmuir.3c02739
Liu Q, Zhao Y, Wang J et al (2024) Application of single-atom-based photocatalysts in environmental pollutant removal and renewable energy production. Cri Rev Environ Sci Technol 54(12):909–930. https://doi.org/10.1080/10643389.2023.2284646
Loiseau T, Lecroq L, Volkringer C et al (2006) Mil-96, a porous aluminum trimesate 3D structure constructed from a hexagonal network of 18-membered rings and μ3-oxo-centered trinuclear units. J Am Chem Soc 128:10223–10230. https://doi.org/10.1021/ja0621086
Ma H, Yang Y, Yin F et al (2022) Integration of thermoresponsive MIL-121 into alginate beads for efficient heavy metal ion removal. J Cleaner Prod 333:130229. https://doi.org/10.1016/j.jclepro.2021.130229
Makiura R, Motoyama S, Umemura Y et al (2010) Surface nano-architecture of a metal-organic framework. Nat Mater 9:565–571. https://doi.org/10.1038/nmat2769
Masoomi MY, Stylianou KC, Morsali A et al (2014) Selective CO2 capture in metal-organic frameworks with azine-functionalized pores generated by mechanosynthesis. Cryst Growth Des 14:2092–2096. https://doi.org/10.1021/cg500033b
Masoomi MY, Bagheri M, Morsali A (2017) Porosity and dye adsorption enhancement by ultrasonic synthesized Cd(II) based metal-organic framework. Ultrason Sonochem 37:244–250. https://doi.org/10.1016/j.ultsonch.2017.01.018
Mayer S, Keglevich A, Sepsey Für C et al (2020) Results in chemistry of natural organic compounds. synthesis of new anticancer vinca alkaloids and flavone alkaloids. Chemistry 2:714–726. https://doi.org/10.3390/chemistry2030046
McCarthy MC, Varela-Guerrero V, Barnett GV et al (2010) Synthesis of zeolitic imidazolate framework films and membranes with controlled microstructures. Langmuir 26:14636–14641. https://doi.org/10.1021/la102409e
Mellot-Draznieks C, Serre C, Surblé S et al (2005) Very large swelling in hybrid frameworks: a combined computational and powder diffraction study. J Am Chem Soc 127:16273–16278. https://doi.org/10.1021/ja054900x
Mendt M, Jee B, Stock N et al (2010) Structural phase transitions and thermal hysteresis in the metal-organic framework compound MIL-53 as studied by electron spin resonance spectroscopy. J Phys Chem C 114:19443–19451. https://doi.org/10.1021/jp107487g
Mohammadi N, Mousazadeh B, Hamoule T (2021) Synthesis and characterization of NH2-SiO2@Cu-MOF as a high-performance adsorbent for Pb ion removal from water environment. Environ Dev Sustain 23:1688–1705. https://doi.org/10.1007/s10668-020-00646-9
Mohan B, Kumar S, Virender, et al (2022) Analogize of metal-organic frameworks (MOFs) adsorbents functional sites for Hg2+ ions removal. 2D Mater 297:121471
Monahan C, Nag R, Morris D et al (2021) Antibiotic residues in the aquatic environment-current perspective and risk considerations. J Environ Sci Health A 56:733–751. https://doi.org/10.1080/10934529.2021.1923311
Moon HR, Lim DW, Suh MP (2013) Fabrication of metal nanoparticles in metal-organic frameworks. Chem Soc Rev 42:1807–1824. https://doi.org/10.1039/c2cs35320b
Murphy DL, Malachowski MR, Campana CF et al (2005) A chiral, heterometallic metal-organic framework derived from a tris(chelate) coordination complex. Chem Commun. https://doi.org/10.1039/B510915A
Nguyen NTT, Lo TNH, Kim J et al (2016) Mixed-metal zeolitic imidazolate frameworks and their selective capture of wet carbon dioxide over methane. Inorg Chem 55:6201–6207. https://doi.org/10.1021/acs.inorgchem.6b00814
Nijem N, Kong L, Zhao Y et al (2011) Spectroscopic evidence for the influence of the benzene sites on tightly bound H2 in metal-organic frameworks with unsaturated metal centers: MOF-74-cobalt. J Am Chem Soc 133:4782–4784. https://doi.org/10.1021/ja2010863
O’Keeffe M, Yaghi OM (2012) Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem Rev 112:675–702. https://doi.org/10.1021/cr200205j
Pastore VJ, Cook TR, Rzayev J (2018) Polymer-MOF hybrid composites with high porosity and stability through surface-selective ligand exchange. Chem Mater 30:8639–8649. https://doi.org/10.1021/acs.chemmater.8b03881
Peng Y, Zhao M, Chen B et al (2018) Hybridization of MOFs and COFs: a new strategy for construction of MOF@COF core-shell hybrid materials. Adv Mater 30:1705454. https://doi.org/10.1002/adma.201705454
Pham T, Forrest KA, McLaughlin K et al (2014) Capturing the H2-metal interaction in Mg-MOF-74 using classical polarization. J Phys Chem C 118:22683–22690. https://doi.org/10.1021/jp508249c
Pu M, Ye D, Wan J et al (2022) Zinc-based metal-organic framework nanofibers membrane ZIF-65/PAN as efficient peroxymonosulfate activator to degrade aqueous ciprofloxacin. Sep Purif Technol 299:121716. https://doi.org/10.1016/j.seppur.2022.121716
Quiros J, Boltes K, Aguado S et al (2015) Antimicrobial metal-organic frameworks incorporated into electrospun fibers. Chem Eng J 262:189–197. https://doi.org/10.1016/j.cej.2014.09.104
Ranjan R, Tsapatsis M (2009) Microporous metal organic framework membrane on porous support using the seeded growth method. Chem Mater 21:4920–4924. https://doi.org/10.1021/cm902032y
Rao C, Zhou L, Pan Y et al (2022) The extra-large calixarene-based MOFs-derived hierarchical composites for photocatalysis of dye: facile syntheses and contribution of carbon species. J Alloys Compd 897:163178. https://doi.org/10.1016/j.jallcom.2021.163178
Rego RM, Sriram G, Ajeya KV et al (2021) Cerium based UiO-66 MOF as a multipollutant adsorbent for universal water purification. J Hazard 416:125941. https://doi.org/10.1016/j.jhazmat.2021.125941
Remy T, Peter SA, Van der Perre S et al (2013) Selective dynamic CO2 separations on Mg-MOF-74 at low pressures: a detailed comparison with 13X. J Phys Chem C 117:9301–9310. https://doi.org/10.1021/jp401923v
Ren Y, Cheng X, Yang S et al (2013) A chiral mixed metal-organic framework based on a Ni(saldpen) metalloligand: synthesis, characterization and catalytic performances. Dalton Trans 42:9930–9937. https://doi.org/10.1039/C3DT50664A
Rösler C, Fischer RA (2015) Metal-organic frameworks as hosts for nanoparticles. CrystEngComm 17:199–217. https://doi.org/10.1039/C4CE01251H
Rowsell JLC, Millward AR, Park KS et al (2004) Hydrogen sorption in functionalized metal-organic frameworks. J Am Chem Soc 126:5666–5667. https://doi.org/10.1021/ja049408c
Ruan W, Wu H, Qi Y et al (2023) Removal of Hg2+ in wastewater by grafting nitrogen/sulfur-containing molecule onto Uio-66-NH2: from synthesis to adsorption studies. Environ Sci Pollut Res 30:15464–15479. https://doi.org/10.1007/s11356-022-23255-7
Saad DR, Alismaeel ZT, Abbar AH (2020) Cobalt removal from simulated wastewaters using a novel flow-by fixed bed bio-electrochemical reactor. Chem Eng Process 156:108097. https://doi.org/10.1016/j.cep.2020.108097
Sabo M, Henschel A, Fröde H et al (2007) Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic properties. J Mater Chem 17:3827–3832. https://doi.org/10.1039/B706432B
Safarifard V, Morsali A (2015) Applications of ultrasound to the synthesis of nanoscale metal-organic coordination polymers. Coord Chem Rev 292:1–14. https://doi.org/10.1016/j.ccr.2015.02.014
Sajjadi S, Khataee A, Darvishi Cheshmeh Soltani R et al (2018) Implementation of magnetic Fe3O4@ZIF-8 nanocomposite to activate sodium percarbonate for highly effective degradation of organic compound in aqueous solution. J Ind Eng Chem 68:406–415. https://doi.org/10.1016/j.jiec.2018.08.016
Schoedel A, Scherb C, Bein T (2010) Oriented nanoscale films of metal-organic frameworks by room-temperature gel-layer synthesis. Angew Chem 122:7383–7386. https://doi.org/10.1002/anie.201001684
Schoedel A, Wojtas L, Kelley SP et al (2011) Network diversity through decoration of trigonal-prismatic nodes: two-step crystal engineering of cationic metal-organic materials. Angew Chem Int Ed 50:11421–11424. https://doi.org/10.1002/anie.201104688
Schoedel A, Cairns AJ, Belmabkhout Y et al (2013) The asc trinodal platform: two-step assembly of triangular, tetrahedral, and trigonal-prismatic molecular building blocks. Angew Chem Int Ed 52:2902–2905. https://doi.org/10.1002/anie.201206042
Seo JS, Whang D, Lee H et al (2000) A homochiral metal-organic porous material for enantioselective separation and catalysis. Nature 404:982–986. https://doi.org/10.1038/35010088
Serre C, Millange F, Thouvenot C et al (2002a) Very large breathing effect in the first nanoporous chromium(III)-based solids: MIL-53 or CrIII(OH)·{O2C-C6H4-CO2}·{HO2C-C6H4-CO2H}x·H2Oy. J Am Chem Soc 124:13519–13526. https://doi.org/10.1021/ja0276974
Serre C, Taulelle F, Férey G (2002b) Synthesis and characterization of new lamellar templated titanium(IV) phosphates with perforated layers: MIL-28n or Ti3O2X2(HPO4)x(PO4)y·(N2CnH2n+2)z·(H2O)2(n=2, 3; x=0,2; y=4, 2; z=3, 2; X=F, OH). Chem Mater 14:998–1003. https://doi.org/10.1021/cm011058v
Serre C, Pelle F, Gardant N et al (2004) Synthesis and sharacterization of MIL-79 and MIL-80: two new luminescent open-framework rare-earth dicarboxylates with unusual 1D inorganic subnetworks. Chem Mater 16:1177–1182. https://doi.org/10.1021/cm035045o
Shamim MA, Zia H, Zeeshan M et al (2022) Metal organic frameworks (MOFs) as a cutting-edge tool for the selective detection and rapid removal of heavy metal ions from water: recent progress. J Environ Chem Eng 10:106991. https://doi.org/10.1016/j.jece.2021.106991
Shayegan H, Ali GAM, Safarifard V (2020a) Amide-functionalized metal-organic framework for high efficiency and fast removal of Pb(II) from aqueous solution. J Inorg Organomet Polym Mater 30:3170–3178. https://doi.org/10.1007/s10904-020-01474-0
Shayegan H, Ali GAM, Safarifard V (2020b) Recent progress in the removal of heavy metal ions from water using metal-organic frameworks. ChemistrySelect 5:124–146. https://doi.org/10.1002/slct.201904107
Shekhah O, Wang H, Zacher D et al (2009) Growth mechanism of metal-organic frameworks: insights into the nucleation by employing a step-by-step route. Angew Chem Int Ed 48:5038–5041. https://doi.org/10.1002/anie.200900378
Silva P, Vilela SMF, Tomé JPC et al (2015) Multifunctional metal-organic frameworks: from academia to industrial applications. Chem Soc Rev 44:6774–6803. https://doi.org/10.1039/C5CS00307E
Singh N, Srivastava I, Dwivedi J et al (2021) Ultrafast removal of ppb levels of Hg(II) and volatile Hg(0) using post modified metal organic framework. Chemosphere 270:129490. https://doi.org/10.1016/j.chemosphere.2020.129490
Smith SJ, Ladewig BP, Hill AJ et al (2015) Post-synthetic Ti exchanged UiO-66 metal-organic frameworks that deliver exceptional gas permeability in mixed matrix membranes. Sci Rep 5:7823. https://doi.org/10.1038/srep07823
Song X, Kim TK, Kim H et al (2012) Post-synthetic modifications of framework metal ions in isostructural metal-organic frameworks: core-shell heterostructures via selective transmetalations. Chem Mater 24:3065–3073. https://doi.org/10.1021/cm301605w
Spokoyny AM, Kim D, Sumrein A et al (2009) Infinite coordination polymer nano- and microparticle structures. Chem Soc Rev 38:1218–1227. https://doi.org/10.1039/b807085g
Stassen I, Styles M, Grenci G et al (2016) Chemical vapour deposition of zeolitic imidazolate framework thin films. Nat Mater 15:304–310. https://doi.org/10.1038/NMAT4509
Stock N, Biswas S (2012) Synthesis of metal-organic frameworks (MOFs): routes to various mof topologies, morphologies, and composites. Chem Rev 112:933–969. https://doi.org/10.1021/cr200304e
Stork JR, Thoi VS, Cohen SM (2007) Rare examples of transition-metal-main-group metal heterometallic metal-organic frameworks from gallium and indium dipyrrinato complexes and silver salts: synthesis and framework variability. Inorg Chem 46:11213–11223. https://doi.org/10.1021/ic7016159
Subramaniyam V, Thangadurai TD, Lee YI (2022) Zirconium based metal-organic framework for the adsorption of Cu(II) ions in real water samples. Clean Eng Technol 9:100526. https://doi.org/10.1016/j.clet.2022.100526
Sun D, Liu W, Qiu M et al (2015a) Introduction of a mediator for enhancing photocatalytic performance via post-synthetic metal exchange in metal-organic frameworks (MOFs). Chem Commun 51:2056–2059. https://doi.org/10.1039/C4CC09407G
Sun D, Sun F, Deng X et al (2015b) Mixed-metal strategy on metal-organic frameworks (MOFs) for functionalities expansion: Co substitution induces aerobic oxidation of cyclohexene over inactive Ni-MOF-74. Inorg Chem 54:8639–8643. https://doi.org/10.1021/acs.inorgchem.5b01278
Sun Z, Zhang Y, Guo S et al (2022) Confining FeNi nanoparticles in biomass-derived carbon for effectively photo-Fenton catalytic reaction for polluted water treatment. Adv Compos Hybrid Mater 5:1566–1581. https://doi.org/10.1007/s42114-022-00477-4
Surblé S, Millange F, Serre C et al (2006) Synthesis of MIL-102, a chromium carboxylate metal-organic framework, with gas sorption analysis. J Am Chem Soc 128:14889–14896. https://doi.org/10.1021/ja064343u
Tan K, Zuluaga S, Gong Q et al (2015) Competitive coadsorption of CO2 with H2O, NH3, SO2, NO, NO2, N2, O2, and CH4 in M-MOF-74 (M = Mg Co, Ni): the role of hydrogen bonding. Chem Mater 27:2203–2217. https://doi.org/10.1021/acs.chemmater.5b00315
Trousselet F, Archereau A, Boutin A et al (2016) Heterometallic metal-organic frameworks of MOF-5 and UiO-66 families: insight from computational chemistry. J Phys Chem C 120:24885–24894. https://doi.org/10.1021/acs.jpcc.6b08594
Troyano J, Carné-Sánchez A, Pérez-Carvajal J et al (2018) A self-folding polymer film based on swelling metal-organic frameworks. Angew Chem 130:15646–15650. https://doi.org/10.1002/anie.201808433
Tsuruoka T, Furukawa S, Takashima Y et al (2009) Nanoporous nanorods fabricated by coordination modulation and oriented attachment growth. Angew Chem 121:4833–4837. https://doi.org/10.1002/anie.200901177
Verma P, Xu X, Truhlar DG (2013) Adsorption on Fe-MOF-74 for C1–C3 hydrocarbon separation. J Phys Chem C 117:12648–12660. https://doi.org/10.1021/jp402884h
Virmani E, Rotter JM et al (2018) On-surface synthesis of highly oriented thin metal-organic framework films through vapor-assisted conversion. J Am Chem Soc 140:4812–4819. https://doi.org/10.1021/jacs.7b08174
Volosskiy B, Niwa K, Chen Y et al (2015) Metal-organic framework templated synthesis of ultrathin, well-aligned metallic nanowires. ACS Nano 9:3044–3049. https://doi.org/10.1021/nn5072446
Waller PJ, Gándara F, Yaghi OM (2015) Chemistry of covalent organic frameworks. Acc Chem Res 48:3053–3063. https://doi.org/10.1021/acs.accounts.5b00369
Wang Y, Bredenkötter B, Rieger B et al (2007) Two-dimensional metal-organic frameworks (MOFs) constructed from heterotrinuclear coordination units and 4,4′-biphenyldicarboxylate ligands. Dalton Trans. https://doi.org/10.1039/B609733B
Wang B, Côté AP, Furukawa H (2008) Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs. Nature 453:207–211. https://doi.org/10.1038/nature06900
Wang C, DeKrafft KE, Lin W (2012) Pt nanoparticles@ photoactive metal-organic frameworks: efficient hydrogen evolution via synergistic photoexcitation and electron injection. J Am Chem Soc 134:7211–7214. https://doi.org/10.1021/ja300539p
Wang LJ, Deng H, Furukawa H et al (2014) Synthesis and characterization of metal-organic framework-74 containing 2, 4, 6, 8, and 10 different metals. Inorg Chem 53:5881–5883. https://doi.org/10.1021/ic500434a
Wang S, Fan Y, Teng J et al (2016) Nanoreactor based on macroporous single crystals of metal-organic framework. Small 12:5702–5709. https://doi.org/10.1002/smll.201601873
Wang RF, Deng LG, Li K et al (2020) Fabrication and characterization of sugarcane bagasse-calcium carbonate composite for the efficient removal of crystal violet dye from wastewater. Ceram Int 46:27484–27492. https://doi.org/10.1016/j.ceramint.2020.07.237
Wang GQ, Huang JF, Huang XF et al (2021a) A hydrolytically stable cage-based metal-organic framework containing two types of building blocks for the adsorption of iodine and dyes. Inorg Chem Front 8:1083–1092. https://doi.org/10.1039/D0QI01257B
Wang R, Deng L, Fan X et al (2021b) Removal of heavy metal ion cobalt (II) from wastewater via adsorption method using microcrystalline cellulose-magnesium hydroxide. Int J Biol Macromol 189:607–617. https://doi.org/10.1016/j.ijbiomac.2021.08.156
Wang H, Yu T, Li Y (2022a) Self-sustained bioelectrical reduction system assisted iron-manganese doped metal-organic framework membrane for the treatment of electroplating wastewater. J Cleaner Prod 331:129972. https://doi.org/10.1016/j.jclepro.2021.129972
Wang RD, He L, Zhu RR et al (2022b) Highly efficient and selective capture Pb(II) through a novel metal-organic framework containing bifunctional groups. J Hazard 427:127852. https://doi.org/10.1016/j.jhazmat.2021.127852
Wang W, Liu D, Cheng H et al (2022c) Structural design and broadband radar absorbing performance of multi-layer patch using carbon black. Adv Compos Hybrid Mater 5:3137–3145. https://doi.org/10.1007/s42114-021-00399-7
Wang X, Zhao B, Xu Z et al (2022d) Synthesized layer-by-layer self-assembly of a novel resin-based MOF for Cu(II) removal. New J Chem 46:19542–19554. https://doi.org/10.1039/d2nj04264a
Wang J, Zhou Y, Liu X et al (2024) Design and application of metal-organic framework membranes for gas and liquid separations. Sep Purif Technol 329:125178. https://doi.org/10.1016/j.seppur.2023.125178
Wei Y, Luo W, Zhuang Z et al (2021) Fabrication of ternary MXene/MnO2/polyaniline nanostructure with good electrochemical performances. Adv Compos Hybrid Mater 4:1082–1091. https://doi.org/10.1007/s42114-021-00323-z
White RJ, Luque R, Budarin VL et al (2009) Supported metal nanoparticles on porous materials. Methods and applications. Chem Soc Rev 38:481–494. https://doi.org/10.1039/B802654H
Wu G, Huang J, Zang Y et al (2017) Porous field-effect transistors based on a semiconductive metal-organic framework. J Am Chem Soc 139:1360–1363. https://doi.org/10.1021/jacs.6b08511
Xia J, Gao Y, Yu G (2021) Tetracycline removal from aqueous solution using zirconium-based metal-organic frameworks (Zr-MOFs) with different pore size and topology: adsorption isotherm, kinetic and mechanism studies. J Colloid Interface Sci 590:495–505. https://doi.org/10.1016/j.jcis.2021.01.046
Xiao DJ, Oktawiec J, Milner PJ et al (2016a) Pore environment effects on catalytic cyclohexane oxidation in expanded Fe2(dobdc) analogues. J Am Chem Soc 138:14371–14379. https://doi.org/10.1021/jacs.6b08417
Xiao JD, Shang Q, Xiong Y et al (2016b) Boosting photocatalytic hydrogen production of a metal-organic framework decorated with platinum nanoparticles: the platinum location matters. Angew Chem Int Ed 55:9389–9393. https://doi.org/10.1002/anie.201603990
Xie MH, Yang XL, Zou C et al (2011) A SnIV-porphyrin-based metal-organic framework for the selective photo-oxygenation of phenol and sulfides. Inorg Chem 50:5318–5320. https://doi.org/10.1021/ic200295h
Xie Y, Rong Q, Mao F et al (2024a) Engineering the pore environment of antiparallel stacked covalent organic frameworks for dynamic capture of iodine pollutants. Nat Commun 15:2671. https://doi.org/10.1038/s41467-024-46942-0
Xie Y, Rong Q, Wen C et al (2024b) Covalent organic framework with predesigned single-ion traps for highly efficient palladium recovery from wastes. CCS Chem. https://doi.org/10.31635/ccschem.023.202303404
Xu R, Jian M, Ji Q et al (2020) 2D water-stable zinc-benzimidazole framework nanosheets for ultrafast and selective removal of heavy metals. Chem Eng J 382:122658. https://doi.org/10.1016/j.cej.2019.122658
Yaghi OM, Li H (1995) Hydrothermal synthesis of a metal-organic framework containing large rectangular channels. J Am Chem Soc 117:10401–10402. https://doi.org/10.1021/ja00146a033
Yang Q, Zhao Q, Ren S et al (2016) Fabrication of core-shell Fe3O4@MIL-100(Fe) magnetic microspheres for the removal of Cr(VI) in aqueous solution. J Solid State Chem 244:25–30. https://doi.org/10.1016/j.jssc.2016.09.010
Yang Q, Xu Q, Jiang HL (2017) Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis. Chem Soc Rev 46:4774–4808. https://doi.org/10.1039/C6CS00724D
Yang Q, Ren S, Zhao Q et al (2018) Selective separation of methyl orange from water using magnetic ZIF-67 composites. Chem Eng J 333:49–57. https://doi.org/10.1016/j.cej.2017.09.099
Yang X, Liu X, Liu Y et al (2023) Optimizing iodine capture performance by metal−organic framework containing with bipyridine units. Front Chem Sci Eng 17:395–403. https://doi.org/10.1007/s11705-022-2218-3
Yao H, Wang F, Chong H et al (2023) A curcumin-modified coordination polymers with ROS scavenging and macrophage phenotype regulating properties for efficient ulcerative colitis treatment. Adv Sci 10:2300601. https://doi.org/10.1002/advs.202300601
Yin Z, Qiu D, Zhang M (2021) Molecular level study of cadmium adsorption on dithiocarbamate modified chitosan. Environ Pollut 271:116322. https://doi.org/10.1016/j.envpol.2020.116322
Yoo Y, Jeong HK (2010) Heteroepitaxial growth of isoreticular metal-organic frameworks and their hybrid films. Cryst Growth Des 10:1283–1288. https://doi.org/10.1021/cg9013027
You B, Jiang N, Sheng M et al (2015) Bimetal-organic framework self-adjusted synthesis of support-free nonprecious electrocatalysts for efficient oxygen reduction. ACS Catal 5:7068–7076. https://doi.org/10.1021/acscatal.5b02325
Yu CX, Wang KZ, Li XJ et al (2020) Highly efficient and facile removal of Pb2+ from water by using a negatively charged azoxy-functionalized metal-organic framework. Cryst Growth Des 20:5251–5260. https://doi.org/10.1021/acs.cgd.0c00437
Yue Y, Fulvio PF, Dai S (2015) Hierarchical metal-organic framework hybrids: perturbation-assisted nanofusion synthesis. Acc Chem Res 48:3044–3052. https://doi.org/10.1021/acs.accounts.5b00349
Yusenko K, Meilikhov M, Zacher D et al (2010) Step-by-step growth of highly oriented and continuous seeding layers of [Cu2(ndc)2(dabco)] on bare oxide and nitride substrates. CrystEngComm 12:2086–2090. https://doi.org/10.1039/B927212G
Zacher D, Baunemann A, Hermes S et al (2007) Deposition of microcrystalline [Cu3(btc)2] and [Zn2(bdc)2(dabco)] at alumina and silica surfaces modified with patterned self assembled organic monolayers: evidence of surface selective and oriented growth. J Mater Chem 17:2785–2792. https://doi.org/10.1039/B703098C
Zacher D, Yusenko K, Bétard A et al (2011) Liquid-phase epitaxy of multicomponent layer-based porous coordination polymer thin films of [M(L)(P)0.5] type: importance of deposition sequence on the oriented growth. Chem Eur J 17:1448–1455. https://doi.org/10.1002/chem.201002381
Zhai QG, Bu X, Mao C et al (2016) Systematic and dramatic tuning on gas sorption performance in heterometallic metal-organic frameworks. J Am Chem Soc 138:2524–2527. https://doi.org/10.1021/jacs.5b13491
Zhan WW, Kuang Q, Zhou JZ et al (2013) Semiconductor@metal-organic framework core-shell heterostructures: a case of ZnO@ZIF-8 nanorods with selective photoelectrochemical Response. J Am Chem Soc 135:1926–1933. https://doi.org/10.1021/ja311085e
Zhang Y, Chen B, Fronczek FR et al (2008) A nanoporous Ag-Fe mixed-metal-organic framework exhibiting single-crystal-to-single-crystal transformations upon guest exchange. Inorg Chem 47:4433–4435. https://doi.org/10.1021/ic800183v
Zhang Z, Chen Y, Xu X et al (2014) Well-defined metal-organic framework hollow nanocages. Angew Chem Int Ed 53:429–433. https://doi.org/10.1002/anie.201308589
Zhang Y, Xie Z, Wang Z et al (2016) Unveiling the adsorption mechanism of zeolitic imidazolate framework-8 with high efficiency for removal of copper ions from aqueous solutions. Dalton Trans 45:12653–12660. https://doi.org/10.1039/c6dt01827k
Zhang FM, Sheng JL, Yang ZD et al (2018) Rational design of MOF/COF hybrid materials for photocatalytic H2 evolution in the presence of sacrificial electron donors. Angew Chem Int Ed 57:12106–12110. https://doi.org/10.1002/anie.201806862
Zhang X, Yang X, Rong Q et al (2024) Enrichment and separation of radionuclides by organic polymer materials: a review. ACS ES&T Eng 4:250–268. https://doi.org/10.1021/acsestengg.3c00543
Zhao M, Deng K, He L et al (2014) Core-shell palladium nanoparticle@metal-organic frameworks as multifunctional catalysts for cascade reactions. J Am Chem Soc 136:1738–1741. https://doi.org/10.1021/ja411468e
Zhao S, Wang Y, Dong J et al (2016) Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution. Nat Energy 1:16184. https://doi.org/10.1038/nenergy.2016.184
Zhao X, Zhao H, Dai W et al (2018) A metal-organic framework with large 1-D channels and rich -OH sites for high-efficiency chloramphenicol removal from water. J Colloid Interface Sci 526:28–34. https://doi.org/10.1016/j.jcis.2018.04.095
Zhao R, Ma T, Zhao S et al (2020) Uniform and stable immobilization of metal-organic frameworks into chitosan matrix for enhanced tetracycline removal from water. Chem Eng J 382:122893. https://doi.org/10.1016/j.cej.2019.122893
Zhao J, Dang Z, Muddassir M et al (2023) A new Cd(II)-based coordination polymer for efficient photocatalytic removal of organic dyes. Molecules. https://doi.org/10.3390/molecules28196848
Zheng M, Chen J, Zhang L et al (2022) Metal organic frameworks as efficient adsorbents for drugs from wastewater. Mater Today Commun 31:103514. https://doi.org/10.1016/j.mtcomm.2022.103514
Zhou XP, Xu Z, Zeller M et al (2009) Reversible uptake of HgCl2 in a porous coordination polymer based on the dual functions of carboxylate and thioether. Chem Commun. https://doi.org/10.1039/B910265E
Zhou W, Liang W, Li D et al (2016) Dual-color encoded DNAzyme nanostructures for multiplexed detection of intracellular metal ions in living cells. Biosens Bioelectron 85:573–579. https://doi.org/10.1016/j.bios.2016.05.058
Zhou Y, Fang F, Lv Q et al (2022) Simultaneous removal of tetracycline and norfloxacin from water by iron-trimesic metal-organic frameworks. J Environ Chem Eng 10:107403. https://doi.org/10.1016/j.jece.2022.107403
Zhou Y, Wang J, Zhao Y et al (2023) Selective capture and separation of xenon and krypton using metal organic frameworks: a review. Front Chem Sci Eng 17:1895–1912. https://doi.org/10.1007/s11705-023-2355-3
Zhu QL, Xu Q (2016) Immobilization of ultrafine metal nanoparticles to high-surface-area materials and their catalytic applications. Chem 1:220–245. https://doi.org/10.1016/j.chempr.2016.07.005
Zhu QL, Li J, Xu Q (2013) Immobilizing metal nanoparticles to metal-organic frameworks with size and location control for optimizing catalytic performance. J Am Chem Soc 135:10210–10213. https://doi.org/10.1021/ja403330m
Zhu H, Yuan J, Tan X et al (2019) Efficient removal of Pb2+ by Tb-MOFs: identifying the adsorption mechanism through experimental and theoretical investigations. Environ Sci-Nano 6:261–272. https://doi.org/10.1039/c8en01066h
Zhuang Z, Wang W, Wei Y et al (2021) Preparation of polyaniline nanorods/manganese dioxide nanoflowers core/shell nanostructure and investigation of electrochemical performances. Adv Compos Hybrid Mater 4:938–945. https://doi.org/10.1007/s42114-021-00225-0
Zlotea C, Campesi R, Cuevas F et al (2010) Pd nanoparticles embedded into a metal-organic framework: synthesis, structural characteristics, and hydrogen sorption properties. J Am Chem Soc 132:2991–2997. https://doi.org/10.1021/ja9084995
Zou X, Zhu G, Zhang F et al (2010) Facile fabrication of metal-organic framework films promoted by colloidal seeds on various substrates. CrystEngComm 12:352–354. https://doi.org/10.1039/B912470E
Acknowledgements
The work was supported by the National Natural Science Foundation of China (U2267224); Beijing Outstanding Young Scientist Program and the Opening Project of Key Laboratory of Microelectronic Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences.
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Funding was provided by National Natural Science Foundation of China (Grant No. U2267224).
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Qu, Z., Leng, R., Wang, S. et al. Nanomaterials Derived from Metal–Organic Frameworks and Their Applications for Pollutants Removal. Reviews Env.Contamination (formerly:Residue Reviews) 262, 12 (2024). https://doi.org/10.1007/s44169-024-00064-2
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DOI: https://doi.org/10.1007/s44169-024-00064-2