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MIL-100(Fe) and its derivatives: from synthesis to application for wastewater decontamination

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Abstract

MIL-100(Fe), an environmental-friendly and water-stable metal–organic framework (MOF), has caught increasing research and application attention in the recent decade. Thanks to its mesoporous structure and eximious surface area, MIL-100(Fe) has been utilized as precursors for synthesizing various porous materials under high thermolysis temperature, which makes the derivatives of MIL-100(Fe) pretty promising candidates for the decontamination of wastewater. Herein, this review systematically summarizes the versatile synthetic methods and conditions for optimizing the properties of MIL-100(Fe) and its derivatives. Then, diverse environmental applications (i.e., adsorption, photocatalysis, and Fenton-like reaction) of MIL-100(Fe) and its derivatives and the corresponding removal mechanisms are detailed in the discussion. Finally, existing knowledge gaps related to fabrications and applications are discussed to close and promote the future development of MIL-100(Fe) and its derivatives toward environmental applications.

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Funding

This work was supported by the National Special Fund for Agro-scientific Research in the Public Interest of China (No. 201503108) and National Natural Science Foundation of China (No. 21771194).

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Authors and Affiliations

  1. Center for Environment and Water Resources, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, People’s Republic of China

    Ying Fang, Zhaoguang Yang, Haipu Li & Xinghao Liu

  2. Key Laboratory of Hunan Province for Water Environment and Agriculture Product Safety, Changsha, 410083, People’s Republic of China

    Ying Fang, Zhaoguang Yang, Haipu Li & Xinghao Liu

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  1. Ying Fang
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  2. Zhaoguang Yang
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Correspondence to Haipu Li.

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Fang, Y., Yang, Z., Li, H. et al. MIL-100(Fe) and its derivatives: from synthesis to application for wastewater decontamination. Environ Sci Pollut Res 27, 4703–4724 (2020). https://doi.org/10.1007/s11356-019-07318-w

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