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Boosting reversible charging of Li-ion batteries at low temperatures by a synergy of propylene carbonate-based electrolyte and defective graphite

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Abstract

Propylene carbonate (PC)-based electrolytes have exhibited significant advantages in boosting the low-temperature discharging of graphite-based Li-ion batteries. However, it is still unclear whether they can improve the charging property and suppress lithium plating. Studying this topic is challenging due to the problem of electrochemical compatibility. To overcome this issue, we introduced graphite with phase defects. The results show that the pouch-type full batteries using PC-based electrolyte exhibit steady performance over 500 cycles and can be reversibly charged over 30 times at −20 °C with an average Coulombic efficiency of 99.95%, while the corresponding value for the conventional ethylene carbonate (EC)-based electrolyte sample is only 31.20%. This indicates that the use of PC-based electrolyte significantly suppresses lithium plating during low-temperature charging. We further demonstrate that the improved performance is mainly attributed to the unique solvation structure, where more \({\rm{PF}}_6^ -\) anions participate in solvation, leading to the formation of a stable F-rich solid state electrolyte interface on the graphite surface and a lower reduction tendency of Li+ ions. This work inspires new ideas for the design of PC-based electrolytes for low-temperature charging and fast-charging batteries.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 22279071, 22279070, 52073161, and U21A20170), the Ministry of Science and Technology of the People’s Republic of China (Nos. 2019YFA0705703 and 2019YFE0100200), and Postdoctoral Research Foundation of China (No. 2021M701873).

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Authors and Affiliations

  1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084, China

    Yingqiang Wu, Jiao Zhang, Jinli Liu, Li Sheng, Bo Zhang, Li Wang, Hong Xu & Xiangming He

  2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (CAS), Changchun, 130022, China

    Jiao Zhang & Limin Wang

  3. China National Quality Supervision and Inspection Center for Industrial Explosive Materials, Nanjing University of Science and Technology, Nanjing, 210094, China

    Jinli Liu

  4. School of Materials Science and Engineering, Materials Genome Institute, Shanghai University, Shanghai, 200444, China

    Siqi Shi

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  1. Yingqiang Wu
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Correspondence to Li Sheng, Siqi Shi or Xiangming He.

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Boosting reversible charging of Li-ion batteries at low temperatures by a synergy of propylene carbonate-based electrolyte and defective graphite

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Wu, Y., Zhang, J., Liu, J. et al. Boosting reversible charging of Li-ion batteries at low temperatures by a synergy of propylene carbonate-based electrolyte and defective graphite. Nano Res. 17, 1491–1499 (2024). https://doi.org/10.1007/s12274-023-5968-4

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