Abstract
The Mg-xZn-yGa (x + y = 1 at.%) alloys are prepared by high strain rate rolling at 300 °C with the rolling strain rate of 9.1 s−1. The effects of the Zn/Ga ratio on microstructure, mechanical, damping and thermal properties of the as-rolled alloys are investigated by x-ray diffraction, tensile testing, dynamic mechanical analyzer and laser-flash method. The as-rolled alloy exhibits the dynamic recrystallization (DRX) volume fraction above 90%. The DRX volume fraction and the grain size increase with the lower Zn/Ga ratio. With the lower Zn/Ga ratio, the elongation and the damping capacity increase gradually. The Mg-1at.%Ga alloy exhibits the highest elongation (31.1%) and the biggest damping capacity, with Q−1 of 0.019 at the strain amplitude of 0.1%. However, the room temperature thermal conductivity decreases with the lower Zn/Ga ratio, and the Mg-1at.%Zn alloy exhibits the highest value (143 W/(m K)). The Mg-0.75at.%Zn-0.25at.%Ga alloy has the best comprehensive performance.
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References
B.L. Mordike and T. Ebert, Magnesium: Properties-Application-Potential, Mater. Sci. Eng. A, 2001, 302, p 37–45.
J.H. Jun, Damping Behavior of Mg-Zn-Al Casting Alloys, Mater. Sci. Eng. A, 2016, 665, p 86–89.
H. Wang, S.Q. Zhang, X.Z. Zou, F. Li and X.Q. Jiang, Magnesium Alloy Coated by Aluminum Process Characteristics and Application Prospects, J. Funct. Mater., 2011, 42, p 788–790.
Y.C. Lee, A.K. Dahle and D.H. Stjohn, The Role of SOLUTE in Grain Refinement of Magnesium, Metal. Mater. Trans. A, 2000, 31, p 2895–2906.
C. Wang, H.Y. Zhang, H.Y. Wang and G.J. Liu, Effect of Alloying Elements of Doping Atoms on the Generalized Stacking-fault Energies of Mg Alloys from First-Principles Calculations, Scr. Mater., 2013, 69, p 445–448.
W.S. Huang, J.H. Chen, H.G. Yan, W.J. Xia and W.B. Su, Effects of Ga Content on the Dynamic Recrystallization and Mechanical Properties of High Strain Rate Rolled Mg-Ga Alloy, Met. Mater. Int., 2019, 26, p 747–759.
L. Yu, H.G. Yan, J.H. Chen, W.J. Xia, B. Su and M. Song, Effects of Solid Solution Elements on Damping Capacities of Binary Magnesium Alloys, Mater. Sci. Eng. A, 2020, 772, p 138707.
H. Pan, F. Pan, R. Yang et al., Thermal and Electrical Conductivity of Binary Magnesium Alloys, J. Mater. Sci., 2014, 49, p 3107–3124.
S.Q. Zhu, H.G. Yan, J.H. Chen, Y.Z. Wu and J.Z. Liu, Effect of Twinning and Dynamic Recrystallization on the High Strain Rate Rolling Process, Scr. Mater., 2010, 63, p 985–988.
S.Q. Zhu, H.G. Yan, W.J. Xia, J.Z. Liu and J.F. Jiang, Influence of Different Deformation Processing on the AZ31 Magnesium Alloy Sheets, J. Mater. Sci., 2009, 44, p 3800–3806.
X.H. Feng, Y.P. Sun, Y.W. Lu, J.M. He and S.Y. Wan, Effect of the Rolling Rate on the Damping and Mechanical Properties of a ZK60 Magnesium Alloy, Mater, 2020, 13, p 2969.
L.P. Zhong, Y.J. Wang, H. Luo and C.S. Luo, Evolution of the Microstructure, Texture and Thermal Conductivity of As-Extruded ZM60 Magnesium Alloy in Pre-Compression, J. Alloys Compd., 2019, 775, p 707–713.
H.C. Pan, F.S. Pan, X. Wang, J. Peng, J. She, C.Y. Zhao, Q.Y. Huang, K. Song and Z.Y. Gao, High Conductivity and High Strength Mg-Zn-Cu Alloy, Mater. Sci. Technol., 2014, 30, p 988–994.
S.Q. Zhu, H.G. Yan, J.H. Chen, Y.Z. Wu, B. Su, Y.G. Du and X.Z. Liao, Feasibility of High Strain-Rate Rolling of a Magnesium Alloy Across a Wide Temperature Range, Scripta. Mater., 2012, 67, p 404–407.
L. Zhao, H.G. Yan, J.H. Chen and B. Su, Effect of Zn Addition on Dynamic Recrystallization of High Strain Rate Rolled Al-Mg Sheets, Met. Mater. Int., 2021, 37, p 405–412.
H.E. Friedrich and B.L. Mordike, Magnesium Technology (Metallurgy, Design Date, Applications), Springer, Berlin, 2006, p 269–310
G.E. Totten and D.S. Mackenzie, Handbook of Aluminum Vol 1: Physical Metallurgy and Processes, Vol 1 Marcel Dekker, New York, 2003, p 84–85
J. Zou, J. Chen, H. Yan, W. Xia, B. Su, Y. Lei and Q. Wu, Effects of Sn Addition on Dynamic Recrystallization of Mg-5Zn-1Mn Alloy During High Strain Rate Deformation, Mater. Sci. Eng. A, 2018, 735, p 49–60.
K. Toyoda, H. Fujita, H. Sawatari and K. Yoshida, Effect of Stacking Fault Energy on Recrystallization in Cold-Worked FCC Crystals, Trans. Jpn. Inst. Metal., 1894, 25, p 339–347.
S.Q. Zhu, H.G. Yan, J.H. Chen, Y.Z. Wu, Y.G. Du and X.Z. Liao, Fabrication of Mg-Al-Zn-Mn Alloy Sheets with Homogeneous Fine-Grained Structures Using High Strain-Rate Rolling in a Wide Temperature Range, Mater. Sci. Eng. A, 2012, 22, p 765–772.
H.B. Liu, G.H. Qi, Y.T. Ma, H. Hao, F. Jia, S.H. Ji, H.Y. Zhang and X.G. Zhang, Microstructure and Mechanical Property of Mg-2.0Ga Alloys, Mater. Sci. Eng. A, 2009, 526, p 7–10.
J.A. Dean, Lange’s Handbook of Chemistry, 16th ed. McGraw-Hill, New York, 2005.
W.S. Huang, J.H. Chen, H.G. Yan, W.J. Xia and W.B. Su, Microstructure, Texture Modification and Mechanical Anisotropy of High Strain Rate Rolled Mg-Ga Alloy Sheets, J. Mater. Sci., 2020, 55, p 10242–10257.
F. Meng, J.M. Rosalie, A. Singh and K. Tsuchiya, Precipitation Behavior of an Ultra-Fine Grained Mg-Zn Alloy Processed by high-Pressure Torsion, J. Alloys Compd., 2015, 664, p 386–391.
A. Puskar, Internal Friction in Metallic Materials: A Handbook, Springer, Berlin, 2007, p 307–320
A. Granato and K. Lücke, Application of Dislocation Theory to Internal Friction Phenomena at High Frequencies, J. Appl. Phys., 1956, 27, p 583–593.
T. Ying, M.Y. Zheng, Z.T. Li and X.G. Qiao, Thermal Conductivity of As-Cast and As-Extruded Binary Mg-Al alloys, J. Alloys. Compd., 2014, 608, p 19–24.
Z. Li, X. Li, H. Yan et al., Achieving High Damping and Excellent Ductility of Al-Mg Alloy Sheet by the Coupling Effect of Mg Content and Fine Grain Structure, Mater. Charact., 2021, 174, p 110974.
H. Suzuki, Segregation of Solute Atoms to Stacking Faults, J. Phys. Soc., 1962, 17, p 322–325.
G.D. Fan, M.Y. Zheng, X.S. Hu, C. Xu, K. Wu and I.S. Golovin, Improved mechanical Property and Internal Friction of Pure Mg Processed by ECAP, Mater. Sci. Eng. A, 2012, 556, p 588–594.
K. Sugimoto, K. Matsui, T. Okamoto and K. Kishitake, Effect of Crystal Orientation on Amplitude-Dependent Damping in Magnesium, Mater. Trans. Jim., 1975, 16, p 647–655.
J. Yuan, K. Zhang, T. Li, X. Li, Y. Li, M. Ma, P. Luo, G. Luo and Y. Hao, Anisotropy of Thermal Conductivity and Mechanical Properties in Mg-5Zn-1Mn Alloy, Mater. Des., 2012, 40, p 257–261.
H.C. Pan, F.S. Pan, J. Peng, A. Tang, J. Gou, L. Wu and H.W. Dong, High-Conductivity Binary Mg-Zn Sheet Processed by Cold Rolling and Subsequent Aging, J. Alloys Compd., 2013, 578, p 439–500.
J. Peng, L.P. Zhong, Y.J. Wang, Y. Lu and F.S. Pan, Effect of Extrusion Temperature on the Microstructure and Thermal Conductivity of Mg-2.0Zn-1.0Mn-0.2Ce alloys, Mater. Des., 2015, 87, p 914–919.
B. Noble and T. Pike, Deviations from Matthiessen’s Rule in Some Magnesium-Based Alloys, J. Phys. F. Metal. Phys., 2000, 11, p 587.
L. Zhong, J. Peng, M. Li, Y. Wang, Y. Lu and F. Pan, Microstructure and Thermal Conductivity of As-Cast and As-Extruded Binary Mg-Mn Alloy, J. Alloys Compd., 2016, 661, p 402–410.
H.C. Pan, F.S. Pan, X. Wang, J. Peng, A. Tang, J. She and J. Gou, Correlation on the Electrical and Thermal Conductivity for Binary Mg-Al and Mg-Zn Alloy, Int. J. Thermophys., 2013, 34, p 1336–1346.
Y. Miyajima, S.Y. Komatsu, M. Mitsuhara, S. Hata, H. Nakashima and N. Tsuji, Change in Electrical Resistivity of Commercial Purity Aluminum Severely Plastic Deformed, Philos. Mag., 2010, 90, p 4475–4488.
C.Y. Su, D.J. Li and A.A. Luo, Effect of Solute Atoms and Second Phases on the Thermal Conductivity of Mg-RE Alloys: A Quantitative Study, J. Alloys Compd., 2018, 747, p 431–437.
X. Tong, G.Q. You, Y.H. Ding, H.S. Xue, Y.C. Wang and W. Guo, Effect of Grain Size on Low-Temperature Electrical Resistivity and Thermal Conductivity of Pure Magnesium, Mater. Lett., 2018, 229, p 261–264.
T. Ying, H. Chi, M.Y. Zheng, Z.T. Li and C. Uher, Low-Temperature Electrical Resistivity and Thermal Conductivity of Binary Magnesium Alloys, Acta. Mater., 2014, 80, p 28–295.
A. Rudajevovoa and P. Lukac, Thermal Properties of Reinforced QE22 Magnesium alloy, Phys. Stat. Sol. A, 1999, 457, p 175.
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The authors are grateful for the support of the Natural Science Foundation Project of China (51871093).
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JH Investigation, Date curation, Writing-original Draft; JC Writing-Review and Editing, Funding acquisition; HY Conceptualization, Methodology; WX Formal analysis, Project administration; BS Validation; PP Validation; MZ Validation; JH Validation
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He, J., Chen, J., Yan, H. et al. Effect of Zn/Ga Ratio on Damping and Thermal Behaviors of Fine-Grained Mg-Zn-Ga Sheets. J. of Materi Eng and Perform 31, 5201–5211 (2022). https://doi.org/10.1007/s11665-022-06605-x
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DOI: https://doi.org/10.1007/s11665-022-06605-x