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Synthesis, Characterization, Crystal Structure, and Hirshfeld Surface Analysis of Zinc, Cadmium, and Mercury Diphosphine Complexes; Precursors for Oxide Nanoparticles

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Abstract

In this article, complexes of Zinc(II), Cadmium(II), and Mercury(II) with Xantphos were synthesized and the molecular structure of two new complexes of [Cd(Xantphos)I2] and [Hg(Xantphos)I2] was determined by single-crystal X-ray crystallography. The hirshfeld surface analyses showed different types of intermolecular interactions in these diphosphines complexes. Moreover, the thermal decomposition of complexes was investigated using the thermogravimetric analysis, which approved the calcination of complexes had led to the formation of corresponding metal oxide nanoparticles. The crystallinity and morphology of final metal oxide nanoparticles characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and IR spectroscopy.

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Acknowledgements

The authors gratefully acknowledge the financial support from Iran National Science Foundation (INSF).

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Authors and Affiliations

  1. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Mehrnaz Aliahmadi & Ali Nemati Kharat

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  1. Mehrnaz Aliahmadi
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  2. Ali Nemati Kharat
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Correspondence to Ali Nemati Kharat.

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Aliahmadi, M., Nemati Kharat, A. Synthesis, Characterization, Crystal Structure, and Hirshfeld Surface Analysis of Zinc, Cadmium, and Mercury Diphosphine Complexes; Precursors for Oxide Nanoparticles. J Inorg Organomet Polym 31, 2594–2605 (2021). https://doi.org/10.1007/s10904-021-01948-9

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  • DOI: https://doi.org/10.1007/s10904-021-01948-9

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