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Synthesis and Characterization of New Zinc(II) Coordination Polymer with a Flexible Hetro-coordination Ligand via In Situ Reaction as a New Precursor for Zinc(II) Oxide Nano-sphere Particles

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Abstract

A new coordination polymer, [Zn3(tza)3(H2O)3] n (1) which H2tza = 1H-tetrazolate-5-acetic acid has been synthesized and characterized by IR spectroscopy, elemental analysis X-ray crystallography. The single-crystal X-ray data of compound 1 show existence of three different ZnII ion with different coordination spheres, hexagonal, pyramidal and pentagonal. This coordination polymer used as a precursor for preparation of zinc(II) oxide nano-particles. Nano-particles were characterized by powder X-ray powder diffraction and the its morphology characterized by scanning electron microscope.

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Acknowledgments

Support of this investigation by Tarbiat Modares University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Islamic Republic of Iran

    Mohammad Sadegh Yazdan Parast & Ali Morsali

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  1. Mohammad Sadegh Yazdan Parast
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  2. Ali Morsali
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Correspondence to Ali Morsali.

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Parast, M.S.Y., Morsali, A. Synthesis and Characterization of New Zinc(II) Coordination Polymer with a Flexible Hetro-coordination Ligand via In Situ Reaction as a New Precursor for Zinc(II) Oxide Nano-sphere Particles. J Inorg Organomet Polym 22, 998–1002 (2012). https://doi.org/10.1007/s10904-012-9691-y

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  • DOI: https://doi.org/10.1007/s10904-012-9691-y

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