Skip to main content
SpringerLink
Log in

Spectroscopic, Structural and Thermal Properties of Three New Metal Nitrates Templated by DABCO: (C6H14N2)[MII(H2O)6](NO3)4 with MII: Mn, Ni and Zn

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Three new metal nitrates templated by 1,4-diazabicyclo[2.2.2]octane (DABCO) were successfully synthesized by slow evaporation method from aqueous solutions. Single crystals were characterized by X-ray diffraction technique which shows that all compounds crystallize in the monoclinic system, space group P21/c, with the following formula: (C6H14N2)[MII(H2O)6](NO3)4 with MII: Mn (Z = 8), Ni and Zn (Z = 4). The crystal structures of the three materials can be described as mixed organic and inorganic free entities linked together via N–H⋯O and OW–H⋯O hydrogen bonds. Although the three compounds present the same formula and adopt the same crystal system and space group they show different atomic arrangement and two structure types are distinguished. Indeed, the arrangement of the different entities along cationic and anionic layers makes the structure of the manganese compound different with respect to the two others which are isostructural. The thermal decomposition of the precursors proceeds through several steps. The first one consists in the dehydration which takes place in two stages and leads to intermediate anhydrous phases while the second corresponds to the total degradation ending with the formation of the metal oxides M2+O.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. G.R. Desiraju, Angew. Chem Int. Ed. Engl. 34, 2311 (1995)

    Article  CAS  Google Scholar 

  2. G.R. Desiraju, Chem. Commun. 28, 1475 (1997)

    Article  Google Scholar 

  3. J.M. Lehn, Supramolecular Chemistry (VCH, Weinheim, 1995)

    Book  Google Scholar 

  4. E.C. Constable, Chem. Commun. 3, 1073 (1997)

    Article  Google Scholar 

  5. M. AzizulHaque, R.G. Chaudhary, L.J. Paliwal, Inorg. Chim. Acta 462, 298 (2017)

    Article  CAS  Google Scholar 

  6. G.F. Swiegers, T.J. Malefetse, Coord. Chem. Rev. 225, 91 (2002)

    Article  CAS  Google Scholar 

  7. R.G. Chaudhary, P. Ali, N.V. Gandhare, J.A. Tanna, H.D. Juneja, Arab. J. Chem. 12, 1070 (2019)

    Article  CAS  Google Scholar 

  8. M.R. Bermejo, A.M. Gonzalez-Noya, R. Pedrido, M.J. Romero, M. Vazquez, Angew. Chem. Int. Ed. 44, 4182 (2005)

    Article  CAS  Google Scholar 

  9. R.G. Chaudhary, H.D. Juneja, M.P. Gharpure, J. Chin. Adv. Mater. Soc. 1, 121 (2013)

    Article  CAS  Google Scholar 

  10. M. Andruh, Chem. Commun. 47, 3025 (2011)

    Article  CAS  Google Scholar 

  11. R.L. Paul, Z.R. Bell, J.C. Jeffery, J.A. McCleverty, M.D. Ward, Proc. Natl. Acad. Sci. USA 99, 4883 (2002)

    Article  CAS  PubMed  Google Scholar 

  12. L.P. Zhang, M. Du, W.J. Lu, T.C.W. Mak, Inorg. Chem. Commun. 8, 623 (2005)

    Article  CAS  Google Scholar 

  13. M.R. Bermejo, M. Fondo, A.M. Gonzalez, O.L. Hoyos, A. Sousa, C.A. McAuliffe, W. Hussain, R. Pritchard, V.M. Novotorsev, J. Chem. Soc. Dalton Trans. 6, 2211 (1999)

    Article  Google Scholar 

  14. M. Abid Derbel, M. François, H. Naïli, W. Rekik, Monatshefte für Chemie 150, 1793 (2019)

    Article  CAS  Google Scholar 

  15. W. Rekik, H. Naili, T. Mhiri, T. Bataille, Acta Cryst. E 61, m629 (2005)

    Article  CAS  Google Scholar 

  16. M.A. El-Gahami, E.M. Abdalla, J. Inorg. Organomet. Polym. 13, 41 (2003)

    Article  CAS  Google Scholar 

  17. H. Tlili, S. Walha, S. Elleuch, B. Fares Ali, H. Naili, J. Mol. Struct. 1152, 303 (2018)

    Article  CAS  Google Scholar 

  18. E. Soyer, F. Yilmaz, V.T. Yilmaz, O. Buyukgungor, W.T.A. Harrison, J. Inorg. Organomet. Polym. 20, 320 (2010)

    Article  CAS  Google Scholar 

  19. W. Rekik, H. Naïli, T. Mhiri, T. Bataille, Mater. Res. Bull. 43, 2709 (2008)

    Article  CAS  Google Scholar 

  20. P. Sen, D. Akagunduz, A. Sheibani Aghdam, F. Çakmak Cebeci, T. Nyokong, T. Catal, J. Inorg. Organomet. Polym. (2019). https://doi.org/10.1007/s10904-019-01286-x

    Article  Google Scholar 

  21. M.M. Chowdhry, D.M.P. Mingos, A.J.P. White, D.J. Williams, Chem. Commun. 97, 899 (1996)

    Article  Google Scholar 

  22. M. Tadokoro, H. Kanno, T. Kitajima, H. Shimada-Umemoto, N. Nakanishi, K. Isobe, K. Nakasuji, Proc. Natl. Acad. Sci. USA 99, 4950 (2002)

    Article  CAS  PubMed  Google Scholar 

  23. M. Tadokoro, T. Shiomi, K. Isobe, K. Nakasuji, Inorg. Chem. 40, 5476 (2001)

    Article  CAS  PubMed  Google Scholar 

  24. L. Öhrström, K. Larsson, S. Borg, S.T. Norberg, Chem. Eur. J. 7, 4805 (2001)

    Article  PubMed  Google Scholar 

  25. D. Braga, J. Chem. Soc. Dalton Trans. 801, 3705 (2000)

    Article  Google Scholar 

  26. A.D. Burrows, Struc. Bond. 108, 55 (2004)

    Article  CAS  Google Scholar 

  27. I. Dance, in Supermolecular Inorganic Chemistry. The Crystal as Supermolecular Entity, ed. by G.R. Desiraju (Wiley, New York, 1996)

    Google Scholar 

  28. O.M. Yaghi, Nature 423, 707 (2003)

    Article  CAS  Google Scholar 

  29. O. Kammoun, N. Loulou, W. Rekik, H. Naïli, T. Mhiri, T. Bataille, Chem. Crystallogr. 42, 103 (2012)

    Article  CAS  Google Scholar 

  30. N. Loulou Nkhili, W. Rekik, H. Naïli, T. Mhiri, T. Bataille, Chem. Crystallogr. 41, 1680 (2011)

    Article  CAS  Google Scholar 

  31. N. Loulou Nkhili, W. Rekik, H. Naïli, T. Mhiri, T. Bataille, Arab. J. Chem. 10, S2509 (2017)

    Article  CAS  Google Scholar 

  32. N. Loulou Nkhili, W. Rekik, T. Mhiri, K.T. Mahmudov, M.N. Kopylovich, H. Naïli, Inorg. Chem. Acta. 412, 27 (2014)

    Article  CAS  Google Scholar 

  33. B. Baghernejad, Europ. J. Chem. 1(1), 54 (2010)

    Article  CAS  Google Scholar 

  34. M. Maneiro, W.F. Ruettinger, E. Bourles, G.L. McLendon, G.C. Dismukes, Proc. Natl. Acad. Sci. USA 100, 3707 (2003)

    Article  CAS  PubMed  Google Scholar 

  35. J. McEvoy, G. Brudvig, Chem. Rev. 106, 4455 (2006)

    Article  CAS  PubMed  Google Scholar 

  36. D. Ben Hassan, W. Rekik, A. Otero de la Roza, F. Ben Mefteh, T. Roisnel, T. Bataille, H. Naïli, Polyhedron 119, 238 (2016)

    Article  CAS  Google Scholar 

  37. D. Ben Hassan, W. Rekik, F. Ben Mefteh, H. Naïli, Therm. Anal. Calorim. 127, 1553 (2016)

    Article  CAS  Google Scholar 

  38. Bruker-Nonius. SAINT version 7.23A. Bruker AXS Inc. Madison (2005).

  39. G.M. Sheldrick, SADABS Bruker AXS Inc. (Madison, Wisconsin, 2002)

    Google Scholar 

  40. A. Altomare, M.C. Burla, M. Camalli, G. Cascarano, C. Giacovazzo, A. Guagliardi, A.G.G. Moliterni, G. Polidori, R. Spagna, J. Appl. Cryst. 32, 115 (1999)

    Article  CAS  Google Scholar 

  41. G.M. Sheldrick, Acta Crystallogr. 64, 112 (2008)

    Article  CAS  Google Scholar 

  42. L.J. Farrugia, J App Crystallogr. 32, 837 (1999)

    Article  CAS  Google Scholar 

  43. R.G. Chaudhary, H.D. Juneja, R. Pagadala, N.V. Gandhare, M.P. Gharpure, J. Saudi Chem. Soc. 19, 442 (2016)

    Article  Google Scholar 

  44. C.C. Addison, B.M. Gatehouse, J. Chem. Soc. 13, 613 (1960)

    Article  Google Scholar 

  45. B.M. Gatehouse, S.E. Livingstone, R.S. Nyholm, J. Chem. Soc. 3965, 4222 (1957)

    Article  Google Scholar 

  46. H. Temel, S. Ilhan, M. Sekerci, R. Ziyadanogŭlları, Spectrosc. Lett. 35, 219 (2002)

    Article  CAS  Google Scholar 

  47. S. Ilhan, H. Temel, A. Kılıc, E. Tas, Transition Met. Chem. 32, 1012 (2007)

    Article  CAS  Google Scholar 

  48. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds Part B, 5th edn. (Wiley, New York, 2000)

    Google Scholar 

  49. N. Prabavathi, A. Nilufer, V. Krishnakumar, Spectrochim Acta Part A 121, 483 (2014)

    Article  CAS  Google Scholar 

  50. E. Tasal, M. Kumalar, Spectrochim. Acta 96, 548 (2012)

    Article  CAS  Google Scholar 

  51. P.A. Kollman, L.C. Allen, Chem. Rev. 72, 283 (1972)

    Article  CAS  Google Scholar 

  52. W. Rekik, H. Naïli, T. Mhiri, T. Bataille, J. Chem. Crystal. 37(2), 147 (2007)

    Article  CAS  Google Scholar 

  53. W. Rekik, H. Naïli, T. Bataille, T. Mhiri, J. Organometal. Chem. 691, 4725 (2006)

    Article  CAS  Google Scholar 

  54. R.G. Chaudhary, H.D. Juneja, M.P. Gharpure, J Therm Anal Calorim. 112, 637 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Grateful thanks are expressed to T. Roisnel (Centre de Diffractométrie X, Institut des Sciences Chimiques de Rennes (ISCR), UMR 6226 CNRS-Université de Rennes 1) and T. Gargouri (Unité de services communs et de Recherche; diffractomètre RX 4 cercles; Faculté des Sciences de Sfax) for the assistance in single-crystal X-ray diffraction data collection.

Author information

Authors and Affiliations

  1. Laboratoire Physico-Chimie de L’État Solide, Département de Chimie, Faculté Des Sciences de Sfax, Université de Sfax, BP 1171, 3000, Sfax, Tunisia

    Dhouha Ben Hassan, Houcine Naïli & Walid Rekik

Authors
  1. Dhouha Ben Hassan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Houcine Naïli
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Walid Rekik
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Houcine Naïli.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 19 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ben Hassan, D., Naïli, H. & Rekik, W. Spectroscopic, Structural and Thermal Properties of Three New Metal Nitrates Templated by DABCO: (C6H14N2)[MII(H2O)6](NO3)4 with MII: Mn, Ni and Zn. J Inorg Organomet Polym 30, 2480–2488 (2020). https://doi.org/10.1007/s10904-020-01495-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-020-01495-9

Keywords

Search

Navigation