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Hydrothermal Synthesis and Structural Characterization of a New Hybrid Zinc Borate, [Zn(dap)2][B4O6(OH)2]

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Abstract

A new zinc borate [Zn(dap)2][B4O6(OH)2] (1, dap = 1,3-diaminopropane) has been hydrothermally synthesized and structurally characterized by IR, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffractions. It crystallized in the monoclinic P21/c space group, a = 7.0050(4) Å, b = 7.8160(2) Å, c = 18.4470(5) Å, β = 94.571(3) Å, V = 1006.78(7) Å3, Z = 4, R 1 = 0.0342, wR 2 = 0.0835. Compound 1 displays a novel two-dimensional inorganic–organic hybrid zinc borate layer constructed from the assembly of [B4O6(OH)2]2− clusters, ZnO2N2 tetrahedra and organic dap molecules. The occurrence of infinite Zn–amine–Zn chains in the structure is uncommon and noteworthy in borate materials.

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Acknowledgements

This work was supported by the Natural Science Foundation of China (20901043, 21571111), Beijing National Laboratory for Molecular Sciences (BNLMS), China Postdoctoral Science Foundation (2016M592130), Postdoctoral Scientific Research Foundation of Qingdao (2016009) and the Taishan Scholar Program (ts201511027).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Collaborative Innovation Center for Marine Biomass Fiber Materials and Textiles, Qingdao University, Shandong, 266071, China

    Li Wei, Ai-Huan Sun, Zhen-Zhen Xue, Jie Pan, Guo-Ming Wang & Zong-Hua Wang

  2. Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China

    Ying-Xia Wang

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  1. Li Wei
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  2. Ai-Huan Sun
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  3. Zhen-Zhen Xue
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Correspondence to Guo-Ming Wang.

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Wei, L., Sun, AH., Xue, ZZ. et al. Hydrothermal Synthesis and Structural Characterization of a New Hybrid Zinc Borate, [Zn(dap)2][B4O6(OH)2]. J Clust Sci 28, 1453–1462 (2017). https://doi.org/10.1007/s10876-017-1158-4

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  • DOI: https://doi.org/10.1007/s10876-017-1158-4

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