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Synthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butane

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Abstract

Six new macrocyclic complexes were synthesized by reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane with various diamines. Then, their nickel(II) perchlorate complexes were synthesized by the template effect by reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane, Ni(ClO4)2 · 6H2O and various diamines. The metal-to-ligand ratio of NiII metal complexes was found to be 1:1. The compounds are coordinated to the central metal as tetradentate O2N2 ligands The NiII complexes are proposed to exhibit tetrahedral geometry. NiII metal complexes are 1:2 electrolytes as shown by their molar conductivities (ΛM) in DMF (dimethyl formamide) at 10−3 m. The structure of NiII metal complexes is proposed from elemental analysis, f.t.-i.r., u.v.-vis., magnetic susceptibility measurements, molar conductivity measurements and mass spectra.

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Authors and Affiliations

  1. Faculty of Education, Chemistry Department, Dicle University, Diyarbakir, 21280, Turkey

    Salih Ilhan & Hamdi Temel

  2. Faculty of Art and Science, Chemistry Department, Harran University, Sanliurfa, 63100, Turkey

    Ahmet Kilic & Esref Tas

Authors
  1. Salih Ilhan
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  2. Hamdi Temel
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  3. Ahmet Kilic
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  4. Esref Tas
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Correspondence to Salih Ilhan.

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Ilhan, S., Temel, H., Kilic, A. et al. Synthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butane. Transition Met Chem 32, 1012–1017 (2007). https://doi.org/10.1007/s11243-007-0260-0

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