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A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition

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The crystal structure of manganese sulfate templated by 1,4-diaza-bicyclo[2.2.2]octane (abbreviated dabco), (C6H14N2)[Mn(H2O)6](SO4)2, was investigated using single crystal X-ray diffraction data. It crystallises in the monoclinic system (space group P21/c) with the following unit-cell parameters: a = 12.1392(2) Å, b = 12.3117(2) Å, c = 12.2765(2) Å, β = 104.607(1)°, V = 1775.47(5) Å3 and Z = 4. The structure has been solved using direct methods and refined by least-squares analysis [R 1 = 0.0381, wR 2 = 0.1082]. The crystal structure of the title compound is built from isolated [Mn(H2O)6]2+ octahedral cations, 1,4-diaza-bicyclo[2.2.2]octandiium cations (C6H14N2)2+ and sulfate anions (SO4)2− connected by a three-dimensional hydrogen-bond network. The thermal decomposition of the precursor, studied by thermogravimetry and temperature-dependent X-ray powder diffraction, proceeds through four stages giving rise to the mixture of Mn2O3and Mn3O4.

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Acknowledgment

Grateful thanks are expressed to Dr. T. Roisnel (Centre de Diffractométrie X, UMR CNRS 6226) and Mr. G. Marsolier for their assistance in single-crystal and powder X-ray diffraction data collection, respectively.

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Authors and Affiliations

  1. Sciences Chimiques de Rennes (CNRS, UMR 6226), Groupe Matériaux Inorganiques: Chimie Douce et Réactivité, Université de Rennes I, Avenue du Général Leclerc, 35042, Rennes CEDEX, France

    Walid Rekik & Thierry Bataille

  2. Laboratoire de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, BP 802, 3018 Sfax, Tunisie

    Walid Rekik, Houcine Naïli & Tahar Mhiri

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  1. Walid Rekik
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  2. Houcine Naïli
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  3. Tahar Mhiri
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  4. Thierry Bataille
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Corresponding author

Correspondence to Thierry Bataille.

Additional information

Supplementary Material CCDC 620298 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

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Rekik, W., Naïli, H., Mhiri, T. et al. A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition. J Chem Crystallogr 37, 147–155 (2007). https://doi.org/10.1007/s10870-006-9170-9

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  • DOI: https://doi.org/10.1007/s10870-006-9170-9

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