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Electrochemical performance of polymer blend electrolytes based on chitosan: dextran: impedance, dielectric properties, and energy storage study

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Abstract

A facile and efficient methodology was implemented in preparation of plasticized polymer electrolyte with polymer blend of chitosan and dextran from leuconostocmesenteroides impregnated with magnesium acetate using solution cast technique. A number of electrochemical techniques were applied in the characterization of the blend polymer electrolyte, such as cyclic voltammetry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), and transference number measurement (TNM). Field emission scanning electron microscopy (FESEM) is used in morphological investigation of impact of plasticizer on films. The X-ray diffraction (XRD) patterns of the plasticized doped samples have shown a significant enhancement in their amorphous nature compared to the pure sample. From the CV, the capacitive behavior of the polymer blend electrolyte was proved. The decomposition potential of the polymer blend electrolyte is determined to be 1.5 V using LSV. The ion transference number (tion) was calculated and found to be 0.979, confirming dominancy of ion conduction in the polymer blend electrolyte system. It is found that ionic conductivity can be enhanced via adding glycerol as plasticizer, which supported the obtained results from both FESEM and XRD studies. To evaluate the EDLC assembly, the specific capacitance was measured as 25.377 F/g using CV curve, with energy and power densities of 7.59 Wh/kg and 520.8 W/kg, respectively.

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Acknowledgements

The authors gratefully acknowledge the financial support for this study from the Ministry of Higher Education and Scientific Research-Kurdish National Research Council (KNRC), Kurdistan Regional Government/Iraq, and University of Malaya. The financial support from the University of Sulaimani, Prince Sultan University, and Komar University of Science and Technology are greatly appreciated.

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Authors and Affiliations

  1. Department of Physics, College of Education, University of Sulaimani, Old Campus, Kurdistan Regional Government, Sulaimani, Iraq

    Rebar T. Abdulwahid

  2. Advanced Polymeric Materials Research Lab., Department of Physics, College of Science, University of Sulaimani, Qlyasan Street, Kurdistan Regional Government, Sulaimani, Iraq

    Rebar T. Abdulwahid, Shujahadeen B. Aziz, M. A. Brza & Ranjdar M. Abdullah

  3. Department of Civil Engineering, College of Engineering, Komar University of Science and Technology, Kurdistan Regional Government, Sulaimani, 46001, Iraq

    Shujahadeen B. Aziz

  4. Department of Manufacturing and Materials Engineering, Faculty of Engineering, International Islamic University of Malaysia, Gombak, Kuala Lumpur, Malaysia

    M. A. Brza

  5. Centre for Foundation Studies in Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

    M. F. Z. Kadir

  6. Department of Chemistry, College of Education, University of Sulaimani, Old Campus, Kurdistan Regional Government, Sulaimani, Iraq

    Wrya O. Karim

  7. Institute for Advanced Studies, University of Malaya, 50603, Kuala Lumpur, Malaysia

    H. M. Hamsan

  8. Chemical Engineering Section, Universiti Kuala Lumpur, Malaysian Institute of Chemical & Bioengineering Technology (UniKL MICET), Alor Gajah 78000, Malacca, Malaysia

    Ahmad S. F. M. Asnawi

  9. Department of Mathematics and General Sciences, Prince Sultan University, P. O. Box 66833, Riyadh, 11586, Saudi Arabia

    Muaffaq M. Nofal

  10. General Science Department, Prince Sultan University, Woman Campus, P. O. Box 66833, Riyadh, 11586, Saudi Arabia

    Elham M. A. Dannoun

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  1. Rebar T. Abdulwahid
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Abdulwahid, R.T., Aziz, S.B., Brza, M.A. et al. Electrochemical performance of polymer blend electrolytes based on chitosan: dextran: impedance, dielectric properties, and energy storage study. J Mater Sci: Mater Electron 32, 14846–14862 (2021). https://doi.org/10.1007/s10854-021-06038-7

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