Skip to main content

Advertisement

Log in

Use of statistical and GIS techniques to assess and predict concentrations of heavy metals in soils of Lahore City, Pakistan

  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

Soils from different land use areas in Lahore City, Pakistan, were analyzed for concentrations of heavy metals—cadmium (Cd), chromium (Cr), nickel (Ni), and lead (Pb). One hundred one samples were randomly collected from six land use areas categorized as park, commercial, agricultural, residential, urban, and industrial. Each sample was analyzed in the laboratory with the tri-acid digestion method. Metal concentrations in each sample were obtained with the use of an atomic absorption spectrophotometer. The statistical techniques of analysis of variance, correlation analysis, and cluster analysis were used to analyze all data. In addition, kriging, a geostatistical procedure supported by ArcGIS, was used to model and predict the spatial concentrations of the four heavy metals—Cd, Cr, Ni, and Pb. The results demonstrated significant correlation among the heavy metals in the urban and industrial areas. The dendogram, and the results associated with the cluster analysis, indicated that the agricultural, commercial, and park areas had high concentrations of Cr, Ni, and Pb. High concentrations of Cd and Ni were also observed in the residential and industrial areas, respectively. The maximum concentrations of both Cd and Pb exceeded world toxic limit values. The kriging method demonstrated increasing spatial diffusion of both Cd and Pb concentrations throughout and beyond the Lahore City area.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • Adriano, D. C. (2003). Trace elements in terrestrial environments: biogeochemistry, bioavailability and risks of metals (2nd ed.). New York: Springer.

    Google Scholar 

  • Ali, Z., Kazi, A. G., Malik, R. N., Naz, M., Khan, T., Hayat, Z., & Kazi, A. M. (2015). Heavy metal built-up in agricultural soils of Pakistan: sources, ecological consequences, and possible remediation measures. In I. Sherameti & A. Varma (Eds.), Heavy metal contamination of soils (pp. 23–42). Switzerland: Springer International. doi:10.1007/978-3-319-14526-6-2.

    Google Scholar 

  • Alloway, B. J. (1995). Heavy metals in soils. Glasgow: Blackie Academic and Professional. 368p.

    Book  Google Scholar 

  • Campbell, P. G. C. (2006). Cadmium-A priority pollutant. Environmental Chemistry, 3(6), 387–388.

    Article  CAS  Google Scholar 

  • CEM Corporation. (2012). Microwave accelerated reaction system. North Carolina: Matthews.

    Google Scholar 

  • Cheng, J., Shi, Z., & Zhu, Y. (2007). Assessment and mapping of environmental quality in agricultural soils of Zhejiang Province, China. Journal of Environmental Sciences, 19, 50–54.

    Article  CAS  Google Scholar 

  • De Vries, W., Romkens, P. F., & Schutze, G. (2007). Critical soil concentrations of cadmium, lead, and mercury in view of health effects on humans and animals. Reviews of Environmental Contamination and Toxicology, 191, 91–130.

    Google Scholar 

  • ESRI. (2002). ArcView 3.1 software. Redlands: Environmental Systems Research Institute (ESRI).

    Google Scholar 

  • ESRI. (2005). ArcGIS 9.1 software. Redlands: Environmental Systems Research Institute (ESRI).

    Google Scholar 

  • Ghauri, B., Lodhi, A., & Mansha, M. (2007). Development of baseline (air quality) data in Pakistan. Environmental Monitoring and Assessment, 127, 237–252.

    Article  CAS  Google Scholar 

  • Gjoka, F., Henningsen, P. F., Wegener, H. R., Salillari, I., & Beqiraj, A. (2011). Heavy metals in soils from Tirana (Albania). Environmental Monitoring and Assessment, 172(1–4), 517–527.

    Article  CAS  Google Scholar 

  • Godt, J., Scheidig, F., & Grosse-Siestrup, et al. (2006). The toxicity of cadmium and resulting hazards for human health. Journal of Occupational Medicine and Toxicology, 1, article 22.

  • GWRTAC. (1997). Remediation of metals-contaminated soils and groundwater. Technical Report TE-97-01. GWRTAC-E-Series. Pittsburgh: GWRTAC.

    Google Scholar 

  • Hani, A., & Pazira, E. (2011). Heavy metals assessment and identification of their sources in agricultural soils of Southern Tehran, Iran. Environmental Monitoring and Assessment, 176(1–4), 677–691.

    Article  CAS  Google Scholar 

  • IARC (2006). IARC Monographs on the evaluation of carcinogenic risks to humans. Vol. 87. Inorganic and organic lead compounds. International Agency for Research on Cancer.

  • IARC (2012). A review of human carcinogens: metals, arsenic, fibres and dusts. Vol. 100C. International Agency for Research on Cancer: Monographs on the Evaluation of Carcinogenic Risks to Humans.

  • Ikenaka, Y., Nakayama, S. M. M., Muzandu, K., Choongo, K., Teraoka, H., Mizuno, N., & Ishizuka, M. (2010). Heavy metal contamination of soil and sediment in Zambia. African Journal of Environmental Science and Technology, 4(11), 729–739.

    CAS  Google Scholar 

  • Iram, S., Ahmad, I., Javed, B., Yaqoob, S., Akhtar, K., Kazmi, M., & Rand Zaman, B. (2009). Fungal tolerance to heavy metals. Pakistan Journal of Botany, 41(5), 2583–2594.

    Google Scholar 

  • Kabata-Pendias, A., & Pendias, H. (2001). Trace metals in soils and plants (2nd ed.). Boca Raton: CRC.

    Google Scholar 

  • Khan, A., Javid, S., Muhmood, A., Mjeed, T., Niaz, A., Majeed, A., et al. (2013). Heavy metal status of soil and vegetables grown on peri-urban area of Lahore district. Soil and Environment, 32(1), 49–54.

  • Khan, S., Cao, Q., Zheng, Y. M., Huang, Y. Z., & Zhu, Y. G. (2008). Health risks of heavy metals in contaminated soils and food crops irrigated with wastewater in Beijing, China. Environmental Pollution, 152(3), 686–692.

    Article  CAS  Google Scholar 

  • Khan, S., Rehman, S., Khan, A. Z., Khan, M. A., & Shah, M. T. (2010). Soil and vegetables enrichment with heavy metals from geological sources in Gilgit, northern Pakistan. Ecotoxicology and Environmental Safety, 73(7), 1820–1827.

    Article  CAS  Google Scholar 

  • Kuang, C., Neumann, T., Norra, S., & Stüben, D. (2004). Land use-related chemical composition of street sediments in Beijing. Environmental Science and Pollution Research, 11(2), 73–83.

    Article  CAS  Google Scholar 

  • Lacatusu, R. (2000). Appraising levels of soil contamination and pollution with heavy metals. European Soil Bureau Research Report Number 4, Section 5(7): 393–403. The European Soil Bureau, Joint Research Centre.

  • Lakhan, V. C., Cabana, K., & LaValle, P. D. (2002). Heavy metal concentrations in surficial sediments from accreting and eroding areas along the coast of Guyana. Environmental Geology, 42, 73–80.

    Article  CAS  Google Scholar 

  • Lee, C. S., Li, X., Shi, W., Cheung, S. C., & Thornton, I. (2006). Metal contamination in urban, suburban, and country park soils of Hong Kong: a study based on GIS and multivariate statistics. Science of the Total Environment, 356, 45–61.

    Article  CAS  Google Scholar 

  • Liu, X., Wu, J., & Xu, J. (2006). Characterizing the risk assessment of heavy metals and sampling uncertainty analysis in paddy field by geostatistics and GIS. Environmental Pollution, 141, 257–264.

    Article  CAS  Google Scholar 

  • Malik, R. N., Jadoon, W. A., & Husain, S. (2010). Metal contamination of surface soils of industrial city Sialkot, Pakistan: a multivariate and GIS approach. Environmental Geochemistry and Health, 32(3), 179–191.

    Article  CAS  Google Scholar 

  • Manahan, S. E. (2003). Toxicological chemistry and biochemistry (3rd ed.). London: CRC Press.

    Google Scholar 

  • Manta, D. S., Angelone, M., Bellanca, A., Neri, R., & Sprovieri, M. (2002). Heavy metals in urban soils: a case study from the city of Palermo (Sicily), Italy. Science of the Total Environment, 300, 229–243.

    Article  CAS  Google Scholar 

  • Markus, J. A., & Mcbratney, A. B. (1996). An urban soil study: heavy metals in Glebe, Australia. Soil Research, 34, 453–465.

    Article  CAS  Google Scholar 

  • McGrath, S. P. (1995). Chromium and nickel. In B. J. Alloway (Ed.), Heavy metals in soils (2nd ed., pp. 152–178). London: Blackie Academic & Professional.

    Chapter  Google Scholar 

  • Micó, C., Recatalá, L., Peris, M., & Sánchez, J. (2006). Assessing heavy metal sources in agricultural soils of a European Mediterranean area by multivariate analysis. Chemosphere, 65, 863–872.

    Article  Google Scholar 

  • Miguel, E., Llamas, J. F., Chacón, E., Berg, T., Larssen, S., Røyset, O., & Vadset, M. (1997). Origin and patterns of distribution of trace elements in street dust: unleaded petrol and urban lead. Atmospheric Environment, 31(17), 2733–2740.

    Article  Google Scholar 

  • Mudgal, V., Madaan, N., Mudgal, A., Singh, R., & Mishra, S. (2010). Effect of toxic metals on human health. Open Nutraceuticals Journal, 3, 94–99.

    CAS  Google Scholar 

  • NSC. (2009). Lead poisoning. Itasca: National Safety Council. http://www.nsc.org/news_resources/Resources/Documents/Lead_Poisoning.pdf.

    Google Scholar 

  • Parizanganeh, A., Lakhan, V. C., Jalalian, H., & Ahmad, S. R. (2008). Contamination of nearshore surficial sediments from the Iranian coast of the Caspian Sea. Soil and Sediment Contamination: An International Journal, 17(1), 19–28.

    Article  CAS  Google Scholar 

  • Peris, M., Recatalá, L., Micó, C., Sánchez, R., & Sánchez, J. (2008). Increasing the knowledge of heavy metal contents and sources in agricultural soils of the European Mediterranean Region. Water, Air, & Soil Pollution, 192(1–4), 25–37.

    Article  CAS  Google Scholar 

  • Perveen, S., Samad, A., Nazif, W., & Shah, S. (2012). Impact of sewage water on vegetables quality with respect to heavy metals in Peshawar, Pakistan. Pakistan Journal of Botany, 44(6), 1923–1931.

    Google Scholar 

  • Qiao, M., Cai, C., Huang, Y., Liu, Y., Lin, A., & Zheng, Y. (2011). Characterization of soil heavy metal contamination and potential health risk in metropolitan region of northern China. Environmental Monitoring and Assessment, 172(1–4), 353–365.

    Article  CAS  Google Scholar 

  • Rattigan, O. V., Mirza, M. I., Ghauri, B. M., Khan, A. R., Swami, K., Yang, K., et al. (2002). Aerosol sulfate and trace elements in urban fog. Energy and Fuels, 16, 640–646.

    Article  CAS  Google Scholar 

  • Saif, M. S., Midrar-Ul-Haq, & Memon, K. S. (2005). Heavy metals contamination through industrial effluent to irrigation water and soil in Korangi area of Karachi (Pakistan). International Journal of Agriculture and Biology, 7, 646–648.

    CAS  Google Scholar 

  • Shah, M. H., & Shaheen, N. (2007). Statistical analysis of atmospheric trace metals and particulate fractions in Islamabad, Pakistan. Journal of Hazardous Materials, 147(3), 759–767.

    Article  CAS  Google Scholar 

  • Shah, M. H., Shaheen, N., Jaffar, M., & Saqib, M. (2004). Distribution of lead in relation to size of airborne particulate matter in Islamabad, Pakistan. Journal of Environmental Management, 70(2), 95–100.

    Article  Google Scholar 

  • Shi, J. C., Wang, H. Z., Xu, J. M., Wu, J. J., Liu, X. M., Zhu, H. P., & Yu, C. (2007). Spatial distribution of heavy metals in soils: a case study of Changxing, China. Environmental Geology, 52, 1–10.

    Article  CAS  Google Scholar 

  • Shimadzu Corporation. Technical report. Atomic Spectroscopy. Tokyo, Japan: Shimadzu Corporation.

  • Sial, R. A., Chaudhary, M. F., Abbas, S. T., Latif, M. I., & Khan, A. G. (2006). Quality of effluents from Hattar Industrial Estate. Journal of Zhejiang University. Science. B, 7(12), 974–980.

    Article  CAS  Google Scholar 

  • StataCorp. (2011). Stata statistical software: release 12. College Station: StataCorp. LP.

    Google Scholar 

  • StatSoft Inc. (2010). Statistica version 10. Tulsa: StatSoft Inc.

    Google Scholar 

  • Šxkrbić, B., & Đurišić-Mladenović, N. (2013). Distribution of heavy elements in urban and rural surface soils: the Novi Sad city and the surrounding settlements, Serbia. Environmental Monitoring and Assessment, 185(1), 457–471.

    Article  Google Scholar 

  • Tahmasbian, I., Nasrazadani, A., Shoja, H., & Sinegani, A. A. S. (2013). The effects of human activities and different land-use on trace element pollution in urban topsoil of Isfahan (Iran). Environmental Earth Science, 71, 1551–1560.

    Article  Google Scholar 

  • Tariq, S. R., Shah, M. H., Shaheen, N., Jaffar, M., & Khalique, A. (2008). Statistical source identification of metals in groundwater exposed to industrial contamination. Environmental Monitoring and Assessment, 138(1–3), 159–165.

    Article  CAS  Google Scholar 

  • Ullah, R., Malik, R. N., & Qadir, A. (2009). Assessment of groundwater contamination in an industrial city, Sialkot, Pakistan. African Journal of Environmental Science and Technology, 3, 429–446.

    CAS  Google Scholar 

  • Ullah, Z., Khan, H., Waseem, A., Mahmood, Q., & Farooq, U. (2013). Water quality assessment of the River Kabul at Peshawar, Pakistan: industrial and urban wastewater impacts. Journal of Water Chemistry and Technology, 35, 170–176.

    Article  Google Scholar 

  • United States Environmental Protection Agency. (1996). Method 3052: Microwave assisted acid digestion of siliceous and organically based matrices. Washington, D.C.: Environmental Protection Agency.

    Google Scholar 

  • United States Environmental Protection Agency. (2007). Treatment technologies for site cleanup: annual status report. 12th Edition. Technical Report EPA-542-R-07-012. Solid waste and emergency response (5203P). Washington, D.C: Environmental Protection Agency.

    Google Scholar 

  • von Schneidemesser, E., Stone, E. A., Quraishi, T. A., Shafer, M. M., & Schauer, J. J. (2010). Toxic metals in the atmosphere in Lahore, Pakistan. Science of the Total Environment, 408, 1640–1648.

    Article  Google Scholar 

  • Wang, X. S., & Qin, Y. (2006). Spatial distribution of metals in urban topsoils of Xuzhou (China): controlling factors and environmental implications. Environmental Geology, 49, 905–914.

    Article  CAS  Google Scholar 

  • Wasseem, A., Arshad, J., Iqbal, F., Sajjad, A., Mehmood, Z., & Murtaza, G. (2014). Pollution status of Pakistan: a retrospective review on heavy metal contamination of water, soil, and vegetables. BioMed Research International. Article ID 813206. doi:10.1155/2014/813206.

  • Wuana, R.A., & Okieimen, F.E. (2011). Heavy metals in contaminated soils: a review of sources, chemistry, risks and best available strategies for remediation. International Scholarly Research Network. ISRN Ecology. Article ID 402647. doi:10.5402/2011/402647.

  • Zhang, C. S. (2006). Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland. Environmental Pollution, 142(3), 501–511.

    Article  CAS  Google Scholar 

  • Zhang, C., Wu, L., Luo, Y., Zhang, H., & Christie, P. (2008). Identifying sources of soil inorganic pollutants on a regional scale using a multivariate statistical approach: role of pollutant migration and soil physicochemical properties. Environmental Pollution, 151, 470–476.

    Article  CAS  Google Scholar 

  • Zhang, M. K., Liu, Z. Y., & Wang, H. (2010). Use of single extraction methods to predict bioavailability of heavy metals in polluted soils to rice. Communications in Soil Science and Plant Analysis, 41(7), 820–831.

    Article  CAS  Google Scholar 

  • Zheng, Y. M., Chen, T. B., & He, J. Z. (2008). Multivariate geostatistical analysis of heavy metal in topsoils from Beijing, China. Journal of Soils and Sediments, 8(1), 51–58.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. Chris Lakhan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Alam, N., Ahmad, S.R., Qadir, A. et al. Use of statistical and GIS techniques to assess and predict concentrations of heavy metals in soils of Lahore City, Pakistan. Environ Monit Assess 187, 636 (2015). https://doi.org/10.1007/s10661-015-4855-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10661-015-4855-1

Keywords

Navigation