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Factorial Kriging analysis and sources of heavy metals in soils of different land-use types in the Yangtze River Delta of Eastern China

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Abstract

The objectives of this study are to analyse the pollution status and spatial correlation of soil heavy metals and identify natural and anthropogenic sources of these heavy metals at different spatial scales. Two hundred and twenty-four soil samples (0–20 cm) were collected and analysed for eight heavy metals (Cd, Hg, As, Cu, Pb, Cr, Zn and Ni) in soils of different land-use types in the Yangtze River Delta of Eastern China. The multivariate methods and factorial Kriging analysis were used to achieve the research objectives. The results indicated that the human and natural effects of different land-use types on the contents of soil heavy metals were different. The Cd, Hg, Cu, Pb and Zn in soils of industrial area were affected by human activities, and the pollution level of these heavy metals in this area was moderate. The Pb in soils of traffic area was affected by human activities, and eight heavy metals in soils of residential area and farmland area were affected by natural factor. The ecological risk status of eight heavy metals in soils of the whole study area was light. The heavy metals in soils showed three spatial scales (nugget effect, short range and long range). At the nugget effect and short range scales, the Cd, Hg, Cu, Pb and Zn in soils were affected by human and natural factors. At three spatial scales, the As, Cr and Ni in soils were affected by soil parent materials.

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References

  • Bocchia S, Castrignanòb A, Fornarob F, Maggiore T (2000) Application of factorial kriging for mapping soil variation at field scale. Eur J Agron 13(4):295–308

    Article  Google Scholar 

  • Boquete MT, Aboal JR, Carballeira A, Fernández JA (2014) Effect of age on the heavy metal concentration in segments of Pseudoscleropodium purum and the biomonitoring of atmospheric deposition of metals. Atmos Environ 86:28–34

    Article  CAS  Google Scholar 

  • Chai Y, Guo J, Chai SL, Cai J, Xue LF, Zhang QW (2015) Source identification of eight heavy metals in grassland soils by multivariate analysis from the Baicheng–Songyuan area, Jilin Province, Northeast China. Chemosphere 134(9):67–75

    Article  CAS  Google Scholar 

  • Chang CY, Yu HY, Chen JJ, Li FB, Zhang HH, Liu CP (2014) Accumulation of heavy metals in leaf vegetables from agricultural soils and associated potential health risks in the Pearl River Delta, South China. Environ Monit Assess 186:1547–1560

    Article  CAS  Google Scholar 

  • CMEP (1995) Environmental quality standard for soils (GB 15618-1995). China Ministry of Environmental Protection, Beijing

  • Cui YJ, Zhu YG, Zhai RH, Chen DY, Huang YZ, Qiu Y, Liang JZ (2004) Transfer of metals from soil to vegetables in an area near a smelter in Nanning, China. Environ Int 30:785–791

    Article  CAS  Google Scholar 

  • Davis HT, Aelion CM, McDermott S, Lawson AB (2009) Identifying natural and anthropogenic sources of metals in urban and rural soils using GIS-based data, PCA, and spatial interpolation. Environ Pollut 157:2378–2385

    Article  CAS  Google Scholar 

  • Facchinelli A, Sacchi E, Mallen L (2001) Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environ Pollut 114:313–324

    Article  CAS  Google Scholar 

  • Fang HL, Liu GH, Kearney M (2005) Georelational analysis of soil type, soil salt content, landform, and land use in the Yellow River Delta, China. Environ Manage 35:72–83

    Article  Google Scholar 

  • Goovaerts p (1992) Factorial Kriging Analysis: a useful tool for wxploring the structure of multivariate spatial information. Sci Total Environ 43:597–619

    Google Scholar 

  • Gržtić I (2008) Potential health risk assessment for soil heavy metal contamination in the central zone of Belgrade (Serbia). J Serb Chem Soc 73:923–34

    Article  Google Scholar 

  • Gutiérrez-Ginés MJ, Pastor J, Hernández AJ (2012) Integrated approach to assessing the effects of soils polluted with heavy metals on a plant population. Ecotoxicology 21(7):1965–1978

    Article  Google Scholar 

  • Ha H, Olson JR, Bian L, Rogerson PA (2014) Analysis of heavy metal sources in soil using Kriging interpolation on principal components. Environ Sci Technol 48(9):4999–5007

    Article  CAS  Google Scholar 

  • Hakanson L (1980) An ecological risk index for aquatic pollution control. A sedimentological approach. Water Res 14(8):975–1001

    Article  Google Scholar 

  • Harley T, Davis C, Marjorie A, Suzanne MD, Lawson AB (2009) Identifying natural and anthropogenic sources of metals in urban and rural soils using GIS-based data, PCA, and spatial interpolation. Environ Pollut 157(8-9):2378–2385

    Article  Google Scholar 

  • Hu YA, Cheng HF (2013) Application of stochastic models in identification and apportionment of heavy metal pollution sources in the surface soils of a large-scale region. Environ Sci Technol 47(8):3752–3760

    Article  CAS  Google Scholar 

  • Imrie CE, Korre A, Munoz-Melendez G, Thornton I, Durucan S (2008) Application of factorial Kriging analysis to the FOREGS European topsoil geochemistry database. Sci Total Environ 393(1):96–110

    Article  CAS  Google Scholar 

  • Korre A (1999) Statistical and spatial assessment of soil heavy metal contamination in areas of poorly recorded, complex sources of pollution Part 1: factor analysis for contamination assessment. Stoch Env Res Risk A 13:260–287

    Article  Google Scholar 

  • Lai HY, Hseu ZY, Chen TC, Chen BC, Guo HY, Chen ZS (2010) Health risk-based assessment and management of heavy metals-contaminated soil sites in Taiwan. Int J Environ Res Pub Health 7:3595–3614

    Article  CAS  Google Scholar 

  • Lee CS, Li XD, Shi WZ, Cheung SC, Thornton I (2006) Metal contamination in urban, suburban, and country park soils of Hong Kong: a study based on GIS and multivariate statistics. Sci Total Environ 356:45–61

    Article  CAS  Google Scholar 

  • Li XY, Liu LJ, Wang YG et al (2013) Heavy metal contamination of urban soil in an old industrial city in Northeast China. Geoderma 192:50–58

    Article  CAS  Google Scholar 

  • Lu AX, Wang JH, Qin XY, Wang KY, Han P, Zhang SZ (2012) Multivariate and geostatistical analyses of the spatial distribution and origin of heavy metals in the agricultural soils in Shunyi, Beijing, China. Sci Total Environ 425:66–74

    Article  CAS  Google Scholar 

  • Luo XS, Xue Y, Wang YL, Cang L, Xu B, Ding J (2015) Source identification and apportionment of heavy metals in urban soil profiles. Chemosphere 127:152–157

    Article  CAS  Google Scholar 

  • Niu L, Yang F, Xu C, Yang H, Liu W (2013) Status of metal accumulation in farmland soils across China: from distribution to risk assessment. Environ Pollut 176:55–62

    Article  CAS  Google Scholar 

  • Olumuyiwa OO, Simiso D, Omotayo RA, Mathew MN (2014) Assessing the enrichment of heavy metals in surface soil and plant (Digitaria eriantha) around coal-fired power plants in South Africa. Environ Sci Pollut Res 21(6):4686–4696

    Article  Google Scholar 

  • Reimann C, Filzmoser P, Fabian K, Hron K, Birke M, Demetriades A, Dinelli E, Ladenberger A (2012) The concept of compositional data analysis in practice—total major element concentrations in agricultural and grazing land soils of Europe. Sci Total Environ 426:196–210

    Article  CAS  Google Scholar 

  • Rodriguez Martin JA, Ramos-Miras JJ, Boluda R, Gil C (2013) Spatial relations of heavy metals in arable and greenhouse soils of a Mediterranean environment region (Spain). Geoderma 200–201:180–188

    Article  Google Scholar 

  • Santschi PH, Allison MA, Asbill S, Perlet AB (1999) Sediment transport and Hg recovery in Lavaca Bay, as evaluated from radionuclide and Hg distributions. Environ Sci Technol 33:378–391

    Article  CAS  Google Scholar 

  • Schröder W, Pesch R, Hertel A, Schoenrock S, Harmens H, Mills G, Ilyin I (2013) Correlation between atmospheric deposition of Cd, Hg and Pb and their concentrations in mosses specified for ecological land classes covering Europe. Atmos Pollut Res 4:267–274

    Article  Google Scholar 

  • Shan YS, Tysklind M, Hao FH, Ouyang W, Chen SY, Lin CY (2013) Identification of sources of heavy metals in agricultural soils using multivariate analysis and GIS. J Soils Sediments 13(4):720–729

    Article  CAS  Google Scholar 

  • Shine JP, Ika RV, Ford TE (1995) Multivariate statistical examination of spatial and temporal patterns of heavy metal contamination in New Bedform Harbor marine sediment. Environ Sci Technol 29:1781–1788

    Article  CAS  Google Scholar 

  • Sun CY, Liu JS, Wang Y, Sun LQ, Yu HW (2013) Multivariate and geostatistical analyses of the spatial distribution and sources of heavy metals in agricultural soil in Dehui, Northeast China. Chemosphere 92:517–523

    Article  CAS  Google Scholar 

  • Szolnoki ZS, Farsang A, Puskás I (2013) Cumulative impacts of human activities on urban garden soils: origin and accumulation of metals. Environ Pollut 177:106–115

    Article  CAS  Google Scholar 

  • Wang XQ, He MC, Xie J, Xi JH, Lu XF (2010) Heavy metal pollution of the world largest antimony mine-affected agricultural soils in Hunan province (China). J Soils Sediments 10:827–837

    Article  CAS  Google Scholar 

  • Wei B, Yang L (2010) A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China. Microchem 94:99–107

    Article  CAS  Google Scholar 

  • Webster R, Oliver MA (2001) Geostatistics for environmental scientists, Statistics in Practice. John Wiley & Sons, New York

    Google Scholar 

  • Wold S, Esbensen K, Geladi P (1987) Principal component analysis. Chemometr Intell Lab 2(1):37–52

    Article  CAS  Google Scholar 

  • You DM (2014) Monitoring and spatial estimation of contents of soil heavy metals (Doctor degree paper). China Agricultural University, Beijing, China

    Google Scholar 

  • Zhang JJ, Wang Y, Liu JS, Liu Q, Zhou QH (2016) Multivariate and geostatistical analyses of the sources and spatial distribution of heavy metals in agricultural soil in Gongzhuling, Northeast China. J Soils Sediments 16(2):634–644

    Article  CAS  Google Scholar 

  • Zheng N, Wang QC, Zhang XW, Zheng DM, Zhang ZS, Zhang SQ (2007) Population health risk due to dietary intake of heavy metals in the industrial area of Huludao city, China. Sci Total Environ 387:96–104

    Article  CAS  Google Scholar 

  • Zhong XL, Zhou SL, Zhao QG, Li JT, Liao QL (2007) Coregionalization, Spatial correlation and spatial factor analysis of soil available heavy metals in a typical region of the Yangze River Delta. Environmental Science 28:2758–2765

    CAS  Google Scholar 

  • Zhou J, Feng K, Pei ZP, Meng F, Sun J (2016) Multivariate analysis combined with GIS to source identification of heavy metals in soils around an abandoned industrial area, Eastern China. Ecotoxicology 25(2):380–388

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This study was supported by the Special Fund from Ministry of Environmental Protection for Soil Pollution Control and Remediation Project (Grant No. SL32106427) and Yangzhou City Environmental Protection Fund (Grant No. YZHB3210035). The authors thank the China University of Mining and Technology for providing spatial analysis, and thank the anonymous reviewers for their helpful comments.

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Correspondence to Ke Feng.

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Responsible editor: Zhihong Xu

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Zhou, J., Feng, K., Li, Y. et al. Factorial Kriging analysis and sources of heavy metals in soils of different land-use types in the Yangtze River Delta of Eastern China. Environ Sci Pollut Res 23, 14957–14967 (2016). https://doi.org/10.1007/s11356-016-6619-z

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