Abstract
To investigate the Sn effects on the oxidation and oxide characteristics of Zr-xSn (x=02.0wt%) binary alloys, autoclave tests were performed in pure water and LiOH solutions containing 2.2 and 70 ppm Li. Corrosion behavior of the Zr-xSn binary alloys was found to be highly dependent on the Sn content and test environment. Corrosion resistance of the Zr-xSn alloys decreased with increasing Sn content in pure water, but increased with increasing Sn content in the LiOH solution. In pure water, a high Sn content accelerated transformation of the oxide microstructure from a columnar grain to an equiaxed grain and the oxide crystal structure from tetragonal to monoclinic. However, this trend was not maintained in the LiOH solution because Li-penetration into the oxide played a more important role than Sn in the transformation of the oxide properties. It is suggested that high Sn content tends to retard Li-penetration into the oxide in LiOH solution.
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References
G. P. Sabol, G. R. Kilp, M. G. Balfour, and E. Roberts,ASTM STP 1023, 227 (1989).
A. V. Nikulina, Y. K. Bibilashvili, P. P. Markelov, and M. M. Peregu,ASTM STP 1295, 785 (1996).
T. Isobe and Y. Matsuo,ASTM STP 1132, 346 (1991).
B. Wadman, Z. Lai, H. O. Andren, A. L. Nystrom, P. Rudling, and H. Pettersson,ASTM STP 1132, 579 (1994).
J. P. Mardon, D. Charquet, and J. Senevat,ASTM STP 1354, 15 (2000).
S. Suzuki, K. Murakami, and T. Takahashi,Proceedings of the 1994 International Topical Meeting on LWR Fuel Performance, p. 352, ANS, La Grange Park, IL (1994).
H. Anada,Proceedings of the 2000 Int. topical meeting on LWR fuel performance, p. 200, ANS, La Grange Park, IL (2000).
M. Eucken, P. T. Finden, S. T. Pritsching, and H. G. Wedinger,ASTM STP 1023, 113 (1989).
A. V. Nikulina, Y. K. Bibilashvili, P. P. Markelov, and M. M. Peregu,ASTM STP 1295, 785 (1996).
M. Harada,ASTM STP 1132, 368 (1991).
K. Takeda and H. Anada,ASTM STP 1354, 592 (2000).
F. Garzarolli, Y. Broy, and R. A. Busch,ASTM STP 1295, 850 (1996).
E. Hillner and J. S. Chirigos, WADP-TM-307 (1962).
Y. H. Jeong, J. H. Back, and S. J. Kim, J. Nucl. Mater.270, 322 (1999).
F. Garzarolli and S. Pohlmeyer,Proceedings of Technical Committee Meeting on Fundamental Aspects of Corrosion of Zirconium Base Alloys in Water Reactor Environments, p. 65, IAEA, Portland, OR (1989).
D. Pecheur, J. Godleweski, P. Billot, and J. Thomazet,ASTM STP 1295, 94 (1996).
O. Gebhardt and A. Hermann, Electrochimica Acta41, 1181 (1996).
ASTM-G2: Standard Test Method for Corrosion Testing of Products of Zirconium, Hafnium and Their Alloys in Water at 680 °F or in Steam at 750 °F.
Ch. Valot and D. Ciosmak,Oxidation of Metals 48, 337 (1997).
D. Charquet, R. Haln, E. Ortlieb, and J. P. Gros,ASTM STP,1023, 405 (1989).
J. Y. Park Y. H. Jeong, and Y. H. Jung,Met. Mater. Int. 7, 447 (2001).
J. Godlewski,ASTM STP 1132, 663 (1994).
H. Anada and K. Takeda,ASTM STP 1295, 35 (1996).
H. Anada, B. J. Herb, K. Nomoto, S. Hagi, R. A. Graham, and T. Kuroda,ASTM STP 1295, 74 (1996).
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Jeong, Y.H., Kim, JH. & Kim, Hg. Effects of Sn on the oxidation and oxide characteristics of Zr alloys in water and a LiOH solution. Met. Mater. Int. 10, 453–459 (2004). https://doi.org/10.1007/BF03027348
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DOI: https://doi.org/10.1007/BF03027348