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Absolute partial ionization cross sections for electron impact of R-carvone from threshold to 100 eV

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Abstract

Partial ionization cross section (PICS) measurements, of the cations created through electron ionization from threshold to 100 eV, have been taken for 78 cationic fragments of R-carvone, using a HIDEN quadrupole mass spectrometer (EPIC 300) with a mass resolution of 1 amu. These PICSs correspond to the cationic fragments with the highest intensity signal registered in our R-carvone mass spectrum reported in Lopes et al. (Int. J. Mass Spectrom. 456, 116395 (2020)) and, to the best of our knowledge, are being presented here for the first time to the scientific community. We also associate the profile observed in the PICSs with some ionic fragmentation mechanisms for R-carvone, based on the appearance energy (AE) values found in Lopes et al.

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Data Availability Statement

This manuscript has no associated data or the data will not be deposited. [Authors’ comment: All data is presented within the manuscript.]

References

  1. E. Alizadeh, L. Sanche, Chem. Rev. 112, 5578 (2012)

    Article  Google Scholar 

  2. B. Boudaïff, P. Cloutier, D. Hunting, M.A. Huels, L. Sanche, Science 287, 1658 (2000)

    Article  ADS  Google Scholar 

  3. A.G. Sanz, M.C. Fuss, A. Muñoz, F. Blanco, P. Limão-Vieira, M.J. Brunger, G. García, Int. J. Rad. Biol. 88, 71 (2012)

    Article  Google Scholar 

  4. R.D. White, W. Tattersall, G. Boyle, R.E. Robson, S. Dujko, Z.L. Petrovic, A. Bankovic, M.J. Brunger, J.P. Sullivan, S.J. Buckman, G. Garcia, Appl. Rad. Isot. 83, 77 (2014)

    Article  Google Scholar 

  5. M. L. da Rocha, L. E. G. Oliveira, C. C. M. Patrício Santos, D. P. de Sousa, R. N. de Almeida, D. A. M. Araújo J. Nat. Med. 67, 743 (2013)

  6. C.C.R. Carvalho, M.M.R. Fonseca, Food Chem. 95, 413 (2006)

    Article  Google Scholar 

  7. J.C. Gonçalves, F.S. Oliveira, R.B. Benedito, D.P. de Sousa, R.N. de Almeida, D.A. de Araújo, Biol. Pharm. Bull. 31, 1017 (2008)

    Article  Google Scholar 

  8. R.N. de Almeida, D.P. de Sousa, F.F.F. Nóbrega, F.S. Claudino, D.A. Araújo, J.R. Leite, R. Mattei, Neurosci. Lett. 443, 51 (2008)

    Article  Google Scholar 

  9. G. Buchbauer, W. Jäger, A. Gruber, H. Dietrich, Flavour Frag. J. 20(6), 686 (2005)

    Article  Google Scholar 

  10. B.B. Aggarwal, W. Yuan, S. Li, S.C. Gupta, Mol. Nutr. Food Res. 57, 1529 (2013)

    Article  Google Scholar 

  11. M.C.A. Lopes, W.A.D. Pires, R.A.A. Amorim, A.C.P. Fernandes, T.M. Casagrande, D.B. Jones, F. Blanco, G. García, M.J. Brunger, Int. J. Mass Spectrom. 456, 116395 (2020)

    Article  Google Scholar 

  12. G. von Bunau, G. Schade, K. Gollnick, Z. Anal. Chem. 227, 173 (1967)

    Article  Google Scholar 

  13. D.B. Jones, E. Ali, C.G. Ning, F.F. da Silva, O. Ingólfsson, M.C.A. Lopes, H.S. Chakraborty, D.H. Madison, M.J. Brunger, J. Chem. Phys. 151, 124306 (2019)

    Article  ADS  Google Scholar 

  14. R.A.A. Amorim, W.A.D. Pires, A.C.P. Fernandes, T.M. Casagrande, D.B. Jones, F. Blanco, G. García, M.J. Brunger, Int. J. Mass Spectrom. 464, 116556 (2021)

    Article  Google Scholar 

  15. G.A. Garcia, L. Nahon, I. Powis, Int. J. Mass Spectrom. 225, 261 (2003)

    Article  Google Scholar 

  16. R.B. de Castilho, C.V. Nunez, A.F. Lago, A.C.F. Santos, L.H. Coutinho, C.A. Lucas, S. Pilling, M.O. Silva-Moraes, G.G.B. de Souza, J. Electron Spectros. 192, 61 (2014)

    Article  Google Scholar 

  17. P. McGeady, D.L. Wansley, D.A. Logan, J. Nat. Prod. 65, 953 (2002)

    Article  Google Scholar 

  18. W.A.D. Pires, K.L. Nixon, S. Ghosh, R.F.C. Neves, H.V. Duque, R.A.A. Amorim, D.B. Jones, F. Blanco, G. Garcia, M.J. Brunger, M.C.A. Lopes, Int. J. Mass Spectrom. 422, 32 (2017)

    Article  Google Scholar 

  19. W.A.D. Pires, K.L. Nixon, S. Ghosh, R.A.A. Amorim, R.F.C. Neves, H.V. Duque, D.G.M. da Silva, D.B. Jones, M.J. Brunger, M.C.A. Lopes, Int. J. Mass Spectrom. 430, 158 (2018)

    Article  Google Scholar 

  20. M.C.A. Lopes, W.A.D. Pires, K.L. Nixon, R.A.A. Amorim, D.G.M. Silva, A.C.P. Fernandes, S. Ghosh, D.B. Jones, L. Campbell, R.F.C. Neves, H.V. Duque, G. García, F. Blanco, M.J. Brunger, Eur. Phys. J. D 74, 88 (2020)

    Article  ADS  Google Scholar 

  21. K.L. Nixon, W.A.D. Pires, R.F.C. Neves, H.V. Duque, D.B. Jones, M.J. Brunger, M.C.A. Lopes, Int. J. Mass Spectrom. 404, 48 (2016)

    Article  Google Scholar 

  22. D.B. Jones, M. Yamazaki, N. Watanabe, M. Takahashi, Phys. Rev. A 87, 022714 (2013)

    Article  ADS  Google Scholar 

  23. B. G. Lindsay, M. A. Mangan. in “Photon and Electron Interactions with Atoms, Molecules and Ions”, ed. Y Itikawa, Landolt-Börstein, Volume 17C, chapter 5, Springer-Verlag, Berlin/Heidelberg (2003)

  24. NIST Chemistry WebBook, NIST Standard Reference Database, 69th ed. National Institute of Standards and Technology, Gaithersburg, MD 20899 (2001) http://webbook.nist.gov

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Acknowledgements

This paper is dedicated to the many contributions that Professor Vince McKoy made to the electron scattering community during his long and distinguished career. Vale Vince, you will be missed. This work was supported by the Brazilian Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG) and FINEP. M.C.A.L. acknowledges financial support from CNPq, while W.A.D.P., A.C.P.F. and R.A.A.A. acknowledge their fellowships from CAPES and FAPEMIG. Some financial assistance from the Australian Research Council through grant # DP180101655 is also noted. Finally, G. García thanks the Spanish Ministerio de Ciencia, Innovación y Universidades for the project grants FIS 2016 -80440 and the CSIC project LINKA20085.

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Authors and Affiliations

  1. Departamento de Física, Universidade Federal de Juiz de Fora, Juiz de Fora, MG, 36936-900, Brazil

    R. A. A. Amorim, W. A. D. Pires, A. C. P. Fernandes, T. M. Casagrande & M. C. A. Lopes

  2. College of Science and Engineering, Flinders University, GPO Box 2100, Adelaide, SA, 5001, Australia

    D. B. Jones & M. J. Brunger

  3. Departamento de Estructura de la Materia, Física Térmica y Electrónica e IPARCOS, Universidad Complutense de Madrid, 28040, Madrid, Spain

    F. Blanco

  4. Instituto de Física Fundamental, Consejo Superior de Investigaciones Cientiìficas (CSIC), Serrano 113-bis, 28006, Madrid, Spain

    G. García

  5. Dept of Actuarial Science and Applied Statistics, Faculty of Business and Management, UCSI University, Kuala Lumpur, 56000, Malaysia

    M. J. Brunger

Authors
  1. R. A. A. Amorim
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  2. W. A. D. Pires
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  3. A. C. P. Fernandes
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  4. T. M. Casagrande
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  5. D. B. Jones
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  7. G. García
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  8. M. J. Brunger
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  9. M. C. A. Lopes
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All authors have contributed equally to the paper.

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Correspondence to M. C. A. Lopes.

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Amorim, R.A.A., Pires, W.A.D., Fernandes, A.C.P. et al. Absolute partial ionization cross sections for electron impact of R-carvone from threshold to 100 eV. Eur. Phys. J. D 75, 217 (2021). https://doi.org/10.1140/epjd/s10053-021-00225-1

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