Abstract
Free, gas-phase polycyclic aromatic hydrocarbons (PAHs) and related species are currently considered to play an important role in the interstellar/circumstellar medium as they are thought to significantly contribute to both Diffuse and Unidentified infrared interstellar bands. They are also considered fundamental blocks of the interstellar dust and several formation mechanisms were proposed with regard to their interstellar/circumstellar synthesis. In this paper we therefore present and discuss the results obtained from ab initio quantum scattering calculations of the response from neutral polar aromatic single-ring species to low-energies electron collisions. Our main purpose is here to provide new values for the rate constants for electron attachment to orthobenzyne and to phenyl molecules by discussing in detail the effects of the long-range dipole interaction in the framework of the Born perturbative approximation at the first order. We shall further discuss the specific behavior of the electrons’ diffusion by such molecules, especially in the low-energy range of the scattered particles’ energies as guided by their permanent dipole moments. We shall also provide accurate numerical fittings for both rates and give explicitly the fitting parameters for their possible use in evolutionary models.
Similar content being viewed by others
References
A.G.G.M. Tielens, The Physics and Chemistry of the Interstellar Medium (Cambridge University Press, 2005)
A.G.G.M. Tielens, EAS Pub. Ser. 46, 3 (2011)
F. Salama et al., ApJ 728, 154 (2011)
C.W. Bauschlicher et al., ApJS 189, 341 (2010)
T.P. Snow, V.M. Bierbaum, Annu. Rev. Anal. Chem. 1, 229 (2008)
J.P. Maier et al., ApJ 726, 41 (2011)
T. Oka, B.J. McCall, Science 331, 293 (2011)
J. Cernicharo et al., ApJ 546, L123 (2001)
P. Ehrenfreund, A.M. Sephton, Faraday Discuss. 133, 277 (2006)
A.G.G.M. Tielens, in Proc. of the IAU Symposium, edited by J. Cernicharo, R. Bachiller (Cambridge University Press, 2011), Vol. 280
S. Kwok, The origin and evolution of planetary nebulae, in Cambridge Astrophysics Series (Cambridge University Press, 2000)
S. Kwok, ApJ 198, 583 (1975)
K. Volk, G.Z. Xiong, S. Kwok, ApJ 530, 408 (2000)
L. Ziurys, Proc. Natl. Acad. Sci. 106, 12274 (2006)
E. Josselin, R. Bachiller, A&A 397, 659 (2003)
S. Kwok, Organic matter in the Universe (Wiley-VCH, 2012)
J.H. Black, in Proc. of the IAU Symposium, edited by J. Cernicharo, R. Bachiller (Cambridge University Press, 2011), Vol. 280
D.M. Hudgins, L.J. Allamandola, A&A 516, L41 (1999)
S. Kwok, K. Volk, P. Bernath, ApJ 554, L87 (2001)
M. Frenklach, E.D. Feigelson, ApJ 341, 372 (1989)
H. Wang, M. Frenklach, J. Phys. Chem. 98, 11465 (1994)
I. Chechneff, J.R. Barker, A.G.G.M. Tielens, ApJ 401, 269 (1992)
H. Wang, M. Frenklach, Combust. Flame 110, 173 (1997)
N.W. Moriarty, M. Frenklach, Proc. Combust. Inst. 28, 2563 (2000)
A. Comandini, K. Brezinsky, J. Phys. Chem. A 115, 5547 (2011)
E.R. Micelotta, A.P. Jones, A.G.G.M. Tielens, A&A 510, A36 (2010)
D.S.N. Parker, F. Zhang, Y.S. Kim, R.I. Kaiser, A. Landera, V.V. Kislov, A.M. Mebel, A.G.G.M. Tielens, Proc. Natl. Acad. Sci. 109, 53 (2012)
E.R. Micelotta, A.P. Jones, A.G.G.M. Tielens, A&A 510, A37 (2010)
E.R. Micelotta, A.P. Jones, A.G.G.M. Tielens, A&A 526, A52 (2011)
I. Cherchneff, EAS Pub. Ser. 46, 177 (2011)
F. Carelli, F. Sebastianelli, I. Baccarelli, F.A. Gianturco, ApJ 712, 445 (2010)
F. Carelli, F. Sebastianelli, M. Satta, F.A. Gianturco, Mon. Not. Roy. Astron. Soc. 415, 425 (2011)
R.F. Gunion, M.K. Gilles, M.L. Polak, W.C. Lineberger, Int. J. Mass Spectrom. Ion Proc. 117, 601 (1992)
P.G. Wenthold, R.R. Squires, W.C. Lineberger, J. Am. Chem. Soc. 120, 5279 (1998)
R.J. McMahon et al., ApJ 590, L61 (2003)
E. Kraka, D. Cremer, Chem. Phys. Lett. 216, 333 (1993)
S. Lepp, A. Dalgarno, ApJ 324, 553 (1988)
V. Wakelam, E. Herbst, ApJ 680, 371 (2008)
E.L.O. Bakes, A.G.G.M. Tielens, ApJ 499, 258 (1998)
M. Hammond, A. Pathak, A. Candian, P.J. Sarre, EAS Pub. Ser. 46, 373 (2011)
F. Carelli, M. Satta, F.A. Gianturco, Eur. Phys. J. D 67, 230 (2013)
N.J. Demarais, Z. Yang, O. Martinez Jr., N. Wehres, T.P. Snow, V.M. Bierbaum, ApJ 746, 32 (2012)
R.R. Lucchese, F.A. Gianturco, Int. Rev. Phys. Chem. 15, 429 (1996)
F.A. Gianturco, P. Paioletti, in Novel aspect of electron-molecule collisions, edited by K.H. Becker (World Scientific, 1998)
N. Sanna, F.A. Gianturco, in Photon and Electron Collisions with Atoms and Molecules, edited by P.G. Burke, C.J. Joachain (Plenum, New York, 1997)
S.L. Altman, A.P. Cracknell, Rev. Mod. Phys. 37, 19 (1965)
R.R. Lucchese et al., ‘ePolyScat’ program, version E2 (1993)
S. Hara, J. Phys. Soc. Jpn 22, 710 (1967)
N. Sanna, F.A. Gianturco, Comput. Phys. Commun. 114, 142 (1998)
S. Altshuler, Phys. Rev. 107, 114 (1957)
D.W. Norcross, N.T. Padial, Phys. Rev. A 25, 226 (1982)
F.A. Gianturco, A. Jain, Phys. Rep. 143, 348 (1986)
M.J. Frisch et al., Gaussian 03 (Gaussian Inc., Wallingford, CT, 2004)
R.N. Zare, Angular Momentum: Understanding Spatial Aspects in Chemistry and Physics (Wiley, 1986)
K. Takayanagi, J. Phys. Jpn 21, 507 (1966)
Y. Okamoto, K. Onda, Y. Itikawa, J. Phys. B 26, 745 (1993)
A. Faure, V. Kokoouline, C.H. Greene, J. Tennyson, J. Phys. B 39, 4261 (2006)
F. Carelli, T. Grassi, F.A. Gianturco, A&A 549, A103 (2013)
S. Irrera, F.A. Gianturco, New J. Phys. 7, 1 (2005)
F. Carelli, T. Grassi, M. Satta, F.A. Gianturco, ApJ 774, 97 (2013)
E. Herbst, Nature 289, 656 (1981)
Author information
Authors and Affiliations
Corresponding author
Additional information
Contribution to the Topical Issue “Astrochemical Processes and Evolutionary Modelling for Stars and Planetary Systems”, edited by Serena Viti, Franco A. Gianturco and Nigel Mason.
Rights and permissions
About this article
Cite this article
Carelli, F., Gianturco, F.A. Electron angular distributions and attachment rates in o-Benzyne and Phenyl aromatic molecules: the effect of the permanent dipoles. Eur. Phys. J. D 67, 268 (2013). https://doi.org/10.1140/epjd/e2013-40434-5
Received:
Revised:
Published:
DOI: https://doi.org/10.1140/epjd/e2013-40434-5