Skip to main content
SpringerLink
Log in

Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO −2 )2]

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)2] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-H⋯O interactions; no aromatic π-π stacking occurs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. Kaim and B. Schwederski, Bioinorganic chemistry: Inorganic Elements in the Chemistry of Life, Wiley, New York (1994).

    Google Scholar 

  2. M. C. Linder and M. Hazegh-Azam, Am. J. Clin. Nutr., 63, 797S–811S (1996).

    CAS  Google Scholar 

  3. N. W. Solomons, J. Am. Coll. Nutr., 4, 83–105 (1985).

    CAS  Google Scholar 

  4. E. Frieden, Clin. Physiol. Biochem., 4, 11–19 (1985).

    Google Scholar 

  5. U. Weser, C. Richter, A. Wendel, and M. Younes, Bioinorg. Chem., 8, 225–236 (1978).

    Google Scholar 

  6. F. Saczewski, E. Dziemidowicz-Borys, P. J. Bednarski, R. Grunert, M. Gdaniec, and P. Tabin, J. Inorg. Biochem., 100, 1389–1398 (2006).

    CAS  Google Scholar 

  7. A. L. Abuhijleh and C. Woods, Inorg. Chem. Commun., 5, 269–273 (2002).

    Google Scholar 

  8. T. Wang and Z. Guo, Curr. Med. Chem., 13, 525–537 (2006).

    CAS  Google Scholar 

  9. J. E. Weder, C. T. Dillon, T. W. Hambley, B. J. Kennedy, P. A. Lay, J. R. Biffin, H. L. Regtop, and N. M. Davies, Coord. Chem. Rev., 232, 95–126 (2002).

    CAS  Google Scholar 

  10. M. Devereux, D. O’Shea, M. Kellet, M. McCann, M. Walsh, D. Egan, C. Deegan, K. Kedziora, G. Rosair, and H. Muller-Bunz,, J. Inorg. Biochem., 101, 881–892 (2007).

    CAS  Google Scholar 

  11. M. Devereux, D. O’Shea, M. O’Connor, H. Grehan, G. Connor, M. McCann, G. Rosair, F. Lyng, A. Kellett, M. McCann, M. Walsh, D. Egan, and B. Thati, Polyhedron, 26, 4073–4084 (2007).

    Article  CAS  Google Scholar 

  12. C. Marzano, M. Pellei, F. Tisato, and C. Santini, Anti-Cancer Agents Med. Chem., 9, 185–211 (2009).

    CAS  Google Scholar 

  13. V. Rajendiran, R. Karthik, M. Palaniandavar, H. Stoeckli-Evans, V. S. Periasamy, M. A. Akbarsha, B. S. Srinag, and H. Krishnamurthy, Inorg. Chem., 46, 8208–8221 (2007).

    CAS  Google Scholar 

  14. A. Spassky and D. S. Sigman, Biochemistry, 24, 8050–8056 (1985).

    Article  CAS  Google Scholar 

  15. A. Kellett, M. O’Connor, M. M. McCann, M. McNamara, P. Lynch, G. Rosair, V. McKee, B. Creaven, M. Walsh, S. McClean, A. Foltyn, D. O’Shea, O. Howe, and M. Devereux, Dalton. Trans., 40, 1024–1027 (2011)

    CAS  Google Scholar 

  16. A. Prisecaru, M. Devereux, N. Barron, M. McCann, J. Colleran, A. Casey, V. McKee, and A. Kellett, Chem. Commun., 48, 6906–6908 (2012).

    CAS  Google Scholar 

  17. S. Roy, S. Saha, R. Majumdar, R. R. Dighe, and A. R. Chakravarty, Polyhedron, 29, 2787–2794 (2010).

    Article  CAS  Google Scholar 

  18. E. Gao, Q. Shi, L. Liu, M. Zhu, C. Shi, and W. Zhang, Chin. J. Chem., 27, 2341–2366 (2009).

    CAS  Google Scholar 

  19. P. Haribabu, Y. P. Patil, K. H. Reddy, and M. Nethaji, Transition Met. Chem., 36, 867–874 (2011).

    CAS  Google Scholar 

  20. A. Garcia-Raso, J. J. Fiol, B. Adrover, V. Moreno, I. Mata, E. Espinosa, and E. Molins, J. Inorg. Biochem., 95, 77–86 (2003).

    CAS  Google Scholar 

  21. L. P. Battaglia and A. B. Corradi, Acta Crystallogr., B33, 3886 (1977).

    CAS  Google Scholar 

  22. C.-T. Yang and J. J. Vittal, Inorg. Chim. Acta, 344, 65–76 (2003).

    CAS  Google Scholar 

  23. Y.-Q. Zheng, Z.-P. Kong, and J.-L. Lin, J. Coord. Chem., 55, 1233–1240 (2002).

    CAS  Google Scholar 

  24. Y.-Q. Zheng, J. Sun, and J.-L. Lin, J. Mol. Struct., 650, 49–56 (2003).

    CAS  Google Scholar 

  25. J. Moncol, K. Jomova, and M. Porubska, Acta Crystallogr., C68, m85–m89 (2012).

    Google Scholar 

  26. C.-H. Ye, H.-L. Sun, X.-Y. Wang, R.-L. Huang, J.-R. Li, and S. Gao, J. Chem. Crystallogr., 35, 381–384 (2005).

    CAS  Google Scholar 

  27. W.-X. Huang, B.-B. Liu, and J.-L. Lin, Acta Crystallogr., E66, m488/m489 (2010).

    Google Scholar 

  28. W. Xu, J. L. Lin, H. Z. Xie, and M. Zhang, Acta Crystallogr., E64, m1496 (2008).

    Google Scholar 

  29. F. Chen, X. H. Li, H. P. Xiao, and M. L. Hu, Acta Crystallogr., E60, m708–m710 (2004).

    Google Scholar 

  30. P. Kitiphaisalnont, S. Siripaisarnpipat, and N. Chaichit, Acta Crystallogr., E65, m1284 (2009).

    Google Scholar 

  31. M. Zheng, Y. Q. Zheng, and B. S. Zhang, J. Coord. Chem., 64, 3419–3431 (2011).

    CAS  Google Scholar 

  32. S. Youngme, A. Cheansirisomboon, C. Danvirutai, C. Pakawatchai, and N. Chaichit, Inorg. Chem. Commun., 11, 57–62 (2008).

    CAS  Google Scholar 

  33. A.-Q. Ma, M.-X. Yu, and L.-G. Zhu, Z. Kristallogr. — New Cryst. Struct., 219, 63/64 (2004).

    Google Scholar 

  34. R. Carballo, B. M. Covelo, E. M. Vazquez-Lopez, A. Castineiras, and J. Niclos, Z. Naturforsch., 58b, 151–154 (2003).

    Google Scholar 

  35. X.-F. Chen, P. Cheng, X. Liu, B. Zhao, D.-Z. Liao, S. P. Yan, and Z.-H. Jiang, Inorg. Chem, 40, 2652–2659 (2001).

    CAS  Google Scholar 

  36. L. Li, D. Liao, Z. Jiang, and S. Yan, Polyhedron, 19, 2529–2532 (2000).

    CAS  Google Scholar 

  37. Y. Rodriguez-Martin, C. Ruiz-Perez, J. Sanchiz, F. Lloret, and M. Julve, Inorg. Chim. Acta, 318, 159–165 (2001).

    CAS  Google Scholar 

  38. M. Padmanabhan, S. M. Kumary, X. Huang, and J. Li, Inorg. Chim. Acta, 358, 3537–3544 (2005).

    CAS  Google Scholar 

  39. Y. Q. Zheng, D. Y. Cheng, J. L. Lin, Z. F. Li, and X. W. Wang, Eur. J. Inorg. Chem., 28, 4453–4461 (2008).

    Google Scholar 

  40. M. Iqbal, I. Ahmad, S. Ali, N. Muhammad, S. Ahmed, and M. Sohail, Polyhedron, 50, 524–531 (2013).

    Article  CAS  Google Scholar 

  41. Bruker. APEX2 and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA (2007).

  42. G. M. Sheldrick, Acta Crystallogr., A64, 112–122 (2008).

    Google Scholar 

  43. G. B. Deacon and R. J. Philips, Coord. Chem. Rev., 33, 227–250 (1980).

    CAS  Google Scholar 

  44. M. Benslimane, Y. K. Redjel, H. Meraziga, and J.-C. Daran, Acta Crystallogr., E69, m277 (2013).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan

    S. S. Batool & S. Ahmad

  2. Department of Chemistry, Government College University, Lahore, Pakistan

    I. U. Khan &  Ejaz

  3. Department of Chemistry, University of Aberdeen, Aberdeen, Scotland

    W. T. A. Harrison

Authors
  1. S. S. Batool
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Ahmad
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. U. Khan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ejaz
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. W. T. A. Harrison
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. S. Batool.

Additional information

Original Russian Text © 2015 S. S. Batool, S. Ahmad, I. U. Khan, Ejaz, W. T. A. Harrison.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 2, pp. 405–409, March–April, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Batool, S.S., Ahmad, S., Khan, I.U. et al. Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO −2 )2]. J Struct Chem 56, 387–391 (2015). https://doi.org/10.1134/S0022476615020286

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476615020286

Keywords

Search

Navigation