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Synthesis, characterization and antibacterial activities of two nickel(II) complexes with xanthate derivatives and N,N,N′,N′-tetramethylethylenediamine as ligands

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Abstract

Two Ni(II) xanthate complexes of composition [Ni(S2COR)2(tmeda)] (R=Me (1), Et (2); tmeda = N,N,N′,N′-tetramethylethylenediamine) have been synthesized and characterized by physicochemical and spectroscopic methods. Both the complexes are hexa-coordinate with an NiN2S4 core. Methylxanthate adopts an isobidentate coordination mode in complex 1 while ethylxanthate exhibits an anisobidentate binding mode in complex 2. Inter- and intramolecular hydrogen bonds are observed in the crystal structures of both complexes. The antibiotic properties of the complexes were investigated .

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Salahaddin University, Erbīl, Kurdistan Region, 44001, Iraq

    A M Qadir

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  1. A M Qadir
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Qadir, A.M. Synthesis, characterization and antibacterial activities of two nickel(II) complexes with xanthate derivatives and N,N,N′,N′-tetramethylethylenediamine as ligands. Transit Met Chem 42, 35–39 (2017). https://doi.org/10.1007/s11243-016-0103-y

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  • DOI: https://doi.org/10.1007/s11243-016-0103-y

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