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Synthesis, Characterization and X-Ray Structure of Bis(O-propyldithiocarbonato-κ2 S,S′)bis(4-cyanopyridine-κN)nickel(II)

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Abstract

The [Ni(S2COCH2CH2CH3)2(C6H4N2)2] adduct of 4-cyanopyridine with [Ni(S2COCH2CH2CH3)2] was synthesized and characterized by elemental analysis, magnetic susceptibility measurement, IR, electronic spectral data, Thermogravimetric analysis/DTA techniques and X-ray diffraction analysis. The Ni atom in the title complex is octahedrally coordinated within a trans-N2S4 donor set, with the Ni atom located on a centre of inversion. The title complex crystallizes in the monoclinic space group P2 1 /c with unit cell parameters a = 11.75(4), b = 11.62(3), c = 9.20(2) Å, β = 104.99(3)°. Crystal structure was solved by direct methods and refined by full matrix least squares procedures to a final R-value of 0.0294 for 1895 observed reflections. The packing of layers of molecules is stabilized by weak C–H···N and C–H···π interactions.

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Acknowledgments

One of the authors (Rajnikant) acknowledges the Department of Science & Technology for single crystal X-ray diffractometer sanctioned as a National Facility under research project No. SR/S2/CMP-47/2003. The authors are grateful to Instrumentation Centre, Indian Institute of Technology, Roorkee for magnetic and TGA studies.

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Authors and Affiliations

  1. Department of Chemistry, University of Jammu, Jammu Tawi, 180006, India

    Sanjay Kapoor & Renu Sachar

  2. X-ray Crystallography Laboratory, Post Graduate Department of Physics, University of Jammu, Jammu Tawi, 180006, India

    Kuldeep Singh, Vivek K. Gupta &  Rajnikant

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  1. Sanjay Kapoor
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  2. Renu Sachar
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  3. Kuldeep Singh
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  4. Vivek K. Gupta
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  5. Rajnikant
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Correspondence to Rajnikant.

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Kapoor, S., Sachar, R., Singh, K. et al. Synthesis, Characterization and X-Ray Structure of Bis(O-propyldithiocarbonato-κ2 S,S′)bis(4-cyanopyridine-κN)nickel(II). J Chem Crystallogr 42, 458–463 (2012). https://doi.org/10.1007/s10870-011-0269-2

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