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O-Tolyl/benzyl dithiocarbonates of phosphorus(III) and (V): syntheses and characterization

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Abstract

O-Tolyl/benzyl dithiocarbonates, ROCS2Na (R = o-, m-, or p-CH3C6H4–, and –CH2C6H5), were synthesized and characterized. These new ligands reacted with PCl3/POCl3 in refluxing toluene which resulted in the formation of phosphorus(III) and phosphorus(V) tolyl/benzyl dithiocarbonates corresponding to [(ROCS2) n PCl3−n ] and [(ROCS2) n POCl3−n ] (R = o-, m-, or p-CH3C6H4–, and –CH2C6H5; n = 1, 2, 3). These pale yellow liquid compounds were characterized by IR, mass, and NMR (1H, 13C, and 31P) spectral studies, which suggest the dithiocarbonate ligands bind in a monodentate mode leading to P–S–C linkages in these derivatives.

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Acknowledgments

SKP gratefully acknowledges the financial assistance from the University Grants Commission, New Delhi. We are grateful to Sophisticated and Analytical Instrumentation Facility (SAIF), Chandigarh and Indian Institute of Integrative Medicine (IIIM), Jammu, for providing spectral facilities.

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Authors and Affiliations

  1. Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu, 180006, Jammu and Kashmir, India

    Bhawana Gupta, Nidhi Kalgotra, Savit Andotra & Sushil K. Pandey

Authors
  1. Bhawana Gupta
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  2. Nidhi Kalgotra
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  3. Savit Andotra
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  4. Sushil K. Pandey
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Correspondence to Sushil K. Pandey.

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Gupta, B., Kalgotra, N., Andotra, S. et al. O-Tolyl/benzyl dithiocarbonates of phosphorus(III) and (V): syntheses and characterization. Monatsh Chem 143, 1087–1095 (2012). https://doi.org/10.1007/s00706-011-0704-2

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