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Synthesis and deposition of nanostructured SnS for semiconductor-sensitized solar cell

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Abstract

Structural, electrical, and optical properties of SnS nanoparticles and films deposited by ultrasound-assisted chemical bath were studied. The SnS was synthesized using tin chloride and thioacetamide as a tin and sulfur source, respectively. The obtained powder and films were characterized by using X-ray diffraction, field emission scanning electron microscopy, scanning electron microscopy, energy dispersive spectroscopy, particle size distribution analysis, and ultraviolet-visible spectroscopy. The synthesized SnS was crystalline in nature with an orthorhombic structure. To study the solar cell performance, the titanium dioxide photoanode was deposited on to the fluorine-doped tin oxide-coated glass (FTO) substrate. Further, the SnS was deposited on especially fabricated titanium dioxide film and the cell was made by using platinum-coated FTO as a counter electrode and a drop of polysulfide as an electrolyte.

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References

  1. Kulkarni AN, Arote SA, Pathan HM, Patil RS (2015) Room temperature synthesis of crystalline Sb2S3 for SnO2 photoanode-based solar cell application. Bull Mater Sci 38:493–498

    Article  CAS  Google Scholar 

  2. Guo W, Shen Y, Wu M, Wang L, Wang L, Ma T (2012) SnS-quantum dot solar cells using novel TiC counter electrode and organic redox couples. Chem Eur J 18:7862–7868

    Article  CAS  Google Scholar 

  3. Chang JA, Im SH, Lee YH, Kim H, Lim CS, Heo JH, Seok SI (2012) Panchromatic photon-harvesting by hole-conducting materials in inorganic−organic heterojunction sensitized-solar cell through the formation of nanostructured electron channels. Nano Lett 12:1863–1867

    Article  CAS  Google Scholar 

  4. Hodes G (2008) Comparison of dye- and semiconductor-sensitized porous nanocrystalline liquid junction solar cells. J Phys Chem C 112:17778–17787

    Article  CAS  Google Scholar 

  5. Nozik AJ (2010) Nanoscience and nanostructures for photovoltaics and solar fuels. Nano Lett 10:2735–2741

  6. Kulkarni AN, Arote SA, Pathan HM, Patil RS (2015) Time dependent synthesis of crystalline Bi2S3 and its application as a sensitizer in SnO2 based solar cells. Int J Mater Res 106:314–317

    Article  CAS  Google Scholar 

  7. Kulkarni AN, Prasad MBR, Pathan HM, Patil RS (2016) TiO2 photoanode sensitized with nanocrystalline Bi2S3: the effect of sensitization time and annealing on its photovoltaic performance. Appl Nanosci 6:567–574

    Article  CAS  Google Scholar 

  8. Prasad R, Pathan HM (2016) Effect of photoanode surface coverage by a sensitizer on the photovoltaic performance of titania based CdS quantum dot sensitized solar cells. Nanotechnology 27:145402

  9. Reddy NK, Devika M, Gopal ESR (2015) Review on tin (II) sulfide (SnS) material: synthesis, properties, and applications. Solid State Mater Sci 40:359–398

  10. Hickey SG, Waurisch C, Rellinghaus B, Eychmuller A (2008) Size and shape control of colloidally synthesized IV-VI nanoparticulate tin(II) sulfide. J Am Chem Soc 130(45):14978–14980

    Article  CAS  Google Scholar 

  11. El-Nahass MM, Zeyada HM, Aziz MS, El-Ghamaz NA (2002) Optical properties of thermally evaporated SnS thin films. Opt Mater 20:159–170

    Article  CAS  Google Scholar 

  12. Devika M, Reddy KN, Reddy SD, Ahsanulhaq Q, Ramesh K, Gopal ESR, Gunasekhar KR, Hahn YB (2008) Synthesis and characterization of nanocrystalline SnS films grown by thermal evaporation technique. J Electrochem Soc 155:130–135

  13. Panda SK, Gorai S, Chaudhuri S (2006) Shape selective solvothermal synthesis of SnS: role of ethylenediamine–water solvent system. Mater Sci Eng B 129:265–269

    Article  CAS  Google Scholar 

  14. Wang MX, Yue GH, Lin YD, Wen X, Peng DL, Geng ZR (2013) Synthesis, optical properties and photovoltaic application of the SnS quasi-one-dimensional nanostructures. Nano-Micro Lett 5:1–6

  15. Jia H, Cheng S, Wu X, Yang Y (2010) Effect of anneal temperature on electrical and optical properties of SnS:Ag thin films. Nat Sci 2:197–200

  16. Liu H, Liu Y, Wang Z, He P (2010) Facile synthesis of monodisperse, size-tunable SnS nanoparticles potentially for solar cell energy conversion. Nanotechnology 21:105707

  17. Lu J, Nan C, Li L, Peng Q, Li Y (2013) Flexible SnS nanobelts: facile synthesis, formation mechanism and application in Li-ion batteries. Nano Res 6:55–64

    Article  CAS  Google Scholar 

  18. Singh JP, Bedi RK (1991) Electrical properties of flash-evaporated Tin Selenide films. Thin Solid Films 199:9–12

    Article  CAS  Google Scholar 

  19. Xia J, Li X, Huang X, Mao N, Zhu N, Wang L, Xu H, Meng X (2016) Physical vapor deposition synthesis of two-dimensional orthorhombic SnS flakes with strong angle/temperature-dependent Raman responses. Nanoscale 8:2063–2070

    Article  CAS  Google Scholar 

  20. Nora A, Gomez G, Salome M, Arcieniega D, Lorena L, Tovar G, Luis C, Gonzalez T, Sanchez E (2014) Ionic liquid-assisted sonochemical synthesis of SnS nanostructures. J Alloys Compd 588:638–643

    Article  Google Scholar 

  21. Gedi S, Reddy VRM, Park C, Chan-Wook J, Reddy R (2015) Comprehensive optical studies on SnS layers synthesized by chemical bath deposition. Opt Mater 42:468–475

    Article  CAS  Google Scholar 

  22. Ninan GG, Kartha CS, Vijayakumar KP (2016) On the preparation of n-type SnS:Cu using chemical spray pyrolysis for photovoltaic application: effect of annealing. Sol Energy Mater Sol Cells 157:229–233

    Article  CAS  Google Scholar 

  23. Schneikart A, Schimper H, Klein A, Jaegermann W (2013) Efficiency limitations of thermally evaporated thin-film SnS solar cells. J Phys D Appl Phys 46:305109

  24. Reddy KTR, Reddy NK, Miles RW (2006) Photovoltaic properties of SnS based solar cells. Sol Energy Mater Sol Cells 90:3041–3046

    Article  Google Scholar 

  25. Park HH, Heasley R, Steinmann VS, Jaramillo R, Hartman K, Chakraborty R, Sinsermsuksakul P, Chua D, Buonassisi, Gordon RG (2015) Co-optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells. Prog Photovolt Res Appl 23:901–908

  26. Sinsermsuksakul P, Hartman K, Kim SB, Sun HJ, Park HH, Chakraborty R, Buonassisi T, Gordon RG (2013) Enhancing the efficiency of SnS solar cells via band-offset engineering with a zinc oxysulfide buffer layer. Appl Phys Lett 102:053901

    Article  Google Scholar 

  27. Deepa KG, Nagaraju J (2014) Development of SnS quantum dot solar cells by SILAR method. Mater Sci Semicond Process 27:649–653

  28. Sayyed SAAR, Beedri NI, Kadam VS, Pathan HM (2016) Rose Bengal sensitized bilayered photoanode of nano-crystalline TiO2–CeO2 for dye-sensitized solar cell application. Bull Mater Sci 39:1381–1387

    Article  CAS  Google Scholar 

  29. Prasad MBR, Kadam V, Joo OS, Pathan HM (2017) Improving the photovoltaic parameters in Quantum dot sensitized solar cells through employment of chemically deposited compact titania blocking layer. Mater Chem Phys 194:165–171

  30. Tamboli PS, Prasad MBR, Kadam VS, Vhatkar RS, Pathan HM, Mahajan SS (2017) α-MoO3-C composite as counter electrode for quantum dot sensitized solar cells. Sol Energy Mater Sol Cells 161:96–101

  31. Yadav AT, Magar PP, Kadam VS, Jagtap CV, Pawar CS (2016) Chemically deposited nickel oxide as counter electrode for dye sensitized solar cell. J Mater Sci Mater Electron 27:12297–12301

    Article  CAS  Google Scholar 

  32. Ghosh B, Das M, Banerjee P, Das S (2008) Fabrication and optical properties of SnS thin films by SILAR method. Appl Surf Sci 254:6436–6440

    Article  CAS  Google Scholar 

  33. Matsunami N, Kakiuchida H, Sataka M, Okayasu S (2013) XRD characterization of AIN thin films prepared by reactive RF-sputter deposition. Adv Mater Phys Chem 3:101–107

    Article  Google Scholar 

  34. Kale SS, Mane RS, Pathan HM, Shaikh AV, Joo OS, Han SH (2007) Preparation and characterization of ZnTe thin films by SILAR method. Appl Surf Sci 253:4335–4337

  35. Malik MA, O’Brien P, Revaprasadu N (1999) A novel route for the preparation of CuSe and CuInSe2 nanoparticles. Adv Mater 11:1441–1444

    Article  CAS  Google Scholar 

  36. Pankove JI (1970) Optical processes in semiconductors. Dover Publications Inc, New York

    Google Scholar 

  37. Mathew M, Jayakrishnan R, Kumar PMR, Kartha CS, Vijayakumar KP, Kashiwaba Y, Abe T (2006) Anomalous behavior of silver doped indium sulfide thin films. J Appl Phys 100:33504

    Article  Google Scholar 

  38. Xu Y, Al-Salim N, Bumby CW, Tilley RD (2009) Synthesis of SnS quantum dots. J Am Chem Soc 131:15990–15991

    Article  CAS  Google Scholar 

  39. Sajeesh TH, Poornima N, Kartha CS, Vijayakumar KP (2010) Unveiling the defect levels in SnS thin films for photovoltaic applications using photoluminescence technique. Phys Status Solidi A 207:1934–1939

    Article  CAS  Google Scholar 

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Acknowledgements

Dr. P. V. Adhyapak thanks the Indian Space Research Organization (ISRO), Bengaluru, for financial support and Dr. I. S. Mulla thanks the Council of Scientific & Industrial Research (CSIR), New Delhi, for Emeritus Scientist scheme. Dr. H. M. Pathan is thankful to the Departmental Research Development Program (DRDP), Savitribai Phule Pune University (SPPU), Pune, for their partial fanatical support.

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Hortikar, S.S., Kadam, V.S., Rathi, A.B. et al. Synthesis and deposition of nanostructured SnS for semiconductor-sensitized solar cell. J Solid State Electrochem 21, 2707–2712 (2017). https://doi.org/10.1007/s10008-017-3642-z

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  • DOI: https://doi.org/10.1007/s10008-017-3642-z

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